Designed to allow students to move from theoretical concepts to concrete applications, this text discusses topics such as gas, solution and solid state kinetics as well as the different methods employed to investigate rates and types of reaction.
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Verlagsort
Verlagsgruppe
McGraw-Hill Education - Europe
Zielgruppe
Für höhere Schule und Studium
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Gewicht
ISBN-13
978-0-07-114831-3 (9780071148313)
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Schweitzer Klassifikation
Some fundamental ideas of kinetics; rates of reactions; dependence on concentration; cautions on treating kinetics data; effects of temperature; mechanisms of reactions; catalysis; kinetics of more complex systems; second-order case, first-order in two components; other reaction order; parallel first-order reactions; series first-order reactions; reversible reactions; autocatalysis; effect of temperature; techniques and methods; calculating rate constants; method of half-lives; initial rates; flooding; logarithmic method; effects of pressure; flow techniques; tracer methods; kinetic isptope effects; reactions in the gas phase; collision theory; the potential energy surface; transitional state theory; unimolecular decomposition of gases; free radical and chain mechanisms; adsorption; catalysis; reactions in solutions; the nature of liquids; solvent polarity effects on rates; ideal solutions; ideal solution and cohesion energies; effects of solvent cohesion energy on rates; solvation and its effects on rates; effects of ionic strength;linear free-energy relationships; compensation effect; some correlations of rate with solubility parameter; enzyme catalysis; enzyme action; kinetics of reactions catalyzed by enzymes; inhibition of enzyme action; enzyme activation by metal ions; regulatory enzymes; kinetics of reactions in the solid state; general considerations; factors affecting reaction rates in solids; rate laws; the Prout-Tompkins equation; rate laws based on nucleation; kinetic studies; nonisothermal methods in kinetics; TGA and DSCA methods; kinetic analysis by the Coats and Redfern method; the Reich and Stivala method; a method based on three data pairs; a differential method; a comprehensive nonisothermal kinetic method; the general rate law and comprehensive method.
