This volume presents a personal selection of papers by Herschbach which have influenced the development of chemical physics. The papers include major works on the molecular dynamics of reactive collisions, celebrated by the 1986 Nobel Prize in Chemistry. The papers are accompanied by instructive comments and afterthoughts by the author which outline subsequent and anticipated applications of the ideas, methods and discoveries. Beyond its use as a reference book, students and senior investigators alike should gain from this volume a vision of both the foundations and the frontiers of chemical physics.
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Sprache
Verlagsort
Zielgruppe
Für höhere Schule und Studium
Für Beruf und Forschung
Maße
ISBN-13
978-981-02-1797-6 (9789810217976)
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Schweitzer Klassifikation
Disposal of Energy Among Translation, Rotation and Vibration of Product Molecules; Preferred Angles of Product Emission in Reactions and in Photodissociation; Collisional Angular Momentum and its Orientation in Space; Variation of Reaction Yield and Other Attributes with Impact Energy, Closeness of Collision, Rotational Orientation or Vibrational Excitation of the Target Molecule; Collisional Excitation of Electronic States and Ionization; Crossing of Covalent and Ionic Potential Curves; Extremely Inelastic Energy Transfer in "Ballistic" Collisions; Conversion of Vibrational to Electronic Excitation Fostered by Reaction; Rebound and Stripping Mechanisms for Direct Bond Exchange Reactions; Formation and Decay of Persistent or Osculating Collision Complexes; Facile Four- and Six-Centre Reactions; Exchange of van der Waals Bonds.