Experimental Physical Chemistry

I. TREATMENT OF EXPERIMENTAL DATA: ERRORS AND ERROR ANALYSIS.

II. TEMPERATURE, PRESSURE, AND VOLTAGE MEASUREMENTS.

III. COMPUTERS IN THE PHYSICAL CHEMISTRY LABORATORY.

IV. THERMODYNAMICS OF GASES.

1. Thermodynamics of a Gas Phase Reaction: Reversible Dissociation of N2O4.
2. Heat Capacity Ratio (Cp/CV) of Gases.
3. Real Gases, Part I: The Joule-Thomson Coefficient.
4. Real Gases, Part II: The Second Virial Coefficient.
V. THERMOCHEMISTRY.

5. Bomb Calorimetry: Heat of Formation of Naphthalene or Sucrose.
6. Bomb Calorimetry: The Resonance Energy of Benzene.
VI. THERMODYNAMICS OF SOLUTIONS: ELECTROCHEMISTRY.

7. The Entropy of Mixing.
8. Thermodynamics of an Electrochemical Cell, Part I: Energy, Enthalpy, and Entropy of Reaction.
9. Thermodynamics of an Electrochemical Cell, Part II: Standard Cell Potential and Activity Coefficients.
VII. THERMODYNAMICS OF PHASE EQUILIBRIUM AND SOLUTION PROPERTIES.

10. Mutual Solubilities of Liquids in a Binary, Two-Phase System.
11. The Vapor Pressure and Heat of Vaporization of Liquids.
12. Liquid-Vapor Coexistence Curve of CO2 or SF6 Near the Critical Point.
13. Solid-Liquid Equilibrium in a Binary System.
14. Liquid-Vapor Equilibrium in a Binary System.
15. Henry's Law Constant Determined by Headspace Gas Chromatography.
16. Surface Tension Properties of Liquids.
VIII. TRANSPORT PROPERTIES AND CHEMICAL KINETICS.

17. Viscosity of Liquids. Part I: Low Viscosities.
18. Viscosity of Liquids. Part II: High Viscosities.
19. Measurement of the Diffusion Coefficient in Solution.
20. Collision Diameters From Gas Viscocities Using the Evacuation Method.
21. The Kinetics of a Homogeneous Reaction in Solution.
22. Kinetics of a Diffusion-Controlled Reaction.
23. The Kinetics of a Reversible, First-Order, Consecutive Reaction. The Reduction of Cr (VI) by Glutathione.
24. The Kinetics of an Enzyme-Catalyzed Reaction.
25. Kinetics and Thermodynamics of a Heterogeneous Gas Phase Reaction: The Reversible Dissociation of Ammonium Carbamate.
26. Kinetics of a Heterogeneous Reaction: The Oxidation of Magnesium by Hydrochloric Acid.
27. Laser Kinetics Part I: Luminescence Quenching of the Uranyl Ion by the Chloride Ion.
28. Laser Kinetics Part II: The Photochromism of Mercury (II) Dithizonate.
29. Laser Kinetics Part III: Viscosity Effects on Luminescence Quenching Rate Constants.
IX. COLLOIDAL SYSTEMS: MICELLES.

30. The Determination of the Critical Micelle Concentration.
31. The Determination of the Mean Aggregation Number of a Micellar System.
X. POLYMERS.

32. Molecular Weight and Monomer Linkage Properties of Poly (vinyl alcohol).
33. The Thermodynamic Properties of Elastomers.
XI. PHOTOPHYSICS AND MOLECULAR SPECTROSCOPY.

34. Excited State Properties of 2-Naphthol, Part I: Acidity Constant.
35. Excited State Properties of 2-Naphthol, Part II: Deprotonation/Protonation Rate Constants.
36. The Enthalpy and Entropy of Excimer Formation.
37. The Rotational-Vibrational Spectrum of HCl.
38. The Vibrational Spectrum of SO2.