Filled with detail not often found in coverage of the chemistry involved with transition metals, this clearly written resource encourages enhanced interest in the study of organometallic chemistry. Among a wealth of topics it covers the 18 Valence Electron Rule, unique reactions in organometallic chemistry, bioorganometallic chemistry, relevant ligands, bonding, structures, and a variety of other reactions, processes, and applications essential to understanding this highly complex field. The text includes figures, equations, and a large number of problems and exercises at the end of each chapter.
Rezensionen / Stimmen
"The book is rife with interesting little tidbits and anecdotes about discoveries, practical uses of complexes, and case studies. Separate stand-alone chapters on metal clusters, ferrocene: structure, bonding, and reactions, and organometallic polymers are, as far as I can tell, unique to this text and may be of interest to instructors who practice in these fields."
-David A. Vicic, Organometallics 2011, 30, 196-198
Sprache
Verlagsort
Verlagsgruppe
Zielgruppe
Für höhere Schule und Studium
Chemistry students.
Maße
Höhe: 254 mm
Breite: 178 mm
Gewicht
ISBN-13
978-1-4398-4968-2 (9781439849682)
Copyright in bibliographic data and cover images is held by Nielsen Book Services Limited or by the publishers or by their respective licensors: all rights reserved.
Schweitzer Klassifikation
Prof. B D Gupta is professor at the chemistry department of IIT Kanpur. After completing his MS (Hons) from Punjab University Chandigarh and Ph.D from Flinders University, Australia, he worked as a post-doctoral researcher at the University College, London. After a one year teaching stint at Roorkee University (now IIT Roorkee), he joined IIT Kanpur where he has been teaching undergraduate, graduate and postgraduate students for over 30 years. He has taught undergraduate classes for many years at various universities in the USA and Japan. His research interests are in the area of organometallic chemistry of cobalt compounds. He has published more than 90 research papers in international journals of repute.
Prof. Anil J Elias is professor at the chemistry department of IIT Delhi. He holds a doctorate in inorganic chemistry from IIT Madras and has gained further experience as an Alexander von Humboldt fellow in Germany and later at the fluorine research laboratories of the University of Idaho, USA. He has been teaching undergraduate, graduate and postgraduate students at IIT Kanpur and IIT Delhi for over 16 years. His research interests are in the area of organometallic and main group chemistry. He has published more than 50 research papers including review articles in reputed international journals.
Autor*in
Department of Chemistry, IIT, Kanpur, India
Department of Chemistry, IIT, Delhi, India
Introduction
The 18 valence electron rule
Metal carbonyls
Neutral spectator ligands: Phosphines and N- heterocyclic carbenes
Alkenes and alkynes as ligands
Carbenes and carbynes: complexes with metal carbon double and triple bonds
Alkyl, aryl and ligands with higher hapticity
Unique reactions in organometallic chemistry
Ligand substitution reactions, metal-metal bonding and fluxionality in organometallic compounds
Organometallic clusters
Homogeneous catalysis using organometallic compounds
Hydrogenation, hydrosilylation and hydrocyanation of alkenes and asymmetric hydrogenation
Hydroformylation
Methanol carbonylation and olefin oxidation: Monsanto, Cativa and Wacker processes
Olefin metathesis
Palladium catalysed C-C and C-N cross coupling reactions
Olefin polymerisation reactions
Ferrocene: Structure, bonding and reactions
Organometallic polymers
Bioorganometallic chemistry