Compounds of Arsenic, Antimony, and Bismuth

Arsenic.- 1. Compounds of Trivalent Arsenic.- 1.1 Tertiary Arsines.- 1.1.1 Symmetric Derivatives.- 1.1.2 Unsymmetric R2R?As Derivatives.- 1.1.3 Unsymmetric and Asymmetric RR?R? As Derivatives.- 1.1.4 Ditertiary Arsines.- 1.1.5 Tritertiary Arsines.- 1.1.6 Tetratertiary Arsines.- 1.1.7 Polymers with Tertiary Arsine Groups.- 1.2 Secondary Arsines.- 1.3 Primary Arsines.- 1.4 Compounds with As-As Bonds.- 1.4.1.1 Diarsines.- 1.4.1.2 Triarsines.- 1.4.1.3 Tetraarsines.- 1.4.2 Arseno Derivatives.- 1.4.2.1 Symmetric Arseno Compounds.- 1.4.2.2 Unsymmetric Arseno Compounds.- 1.5 Compounds with Arsenic-Halogen and Arsenic-Pseudohalogen Bonds.- 1.5.1 Secondary Haloarsines, R2AsX and RR?AsX.- 1.5.2 Primary Dihaloarsines, RAsX.- 1.5.5 Secondary Pseudohaloarsines, R2AsX.- 1.5.6 Primary Dipseudohaloarsines, RAsX2.- 1.6 Compounds of Arsenic Bonded to Group VIA Elements.- 1.6.1 Compounds with Arsenic-Oxygen Bonds.- 1.6.1.1 Arsinous Acids.- 1.6.1.2 Arsinous Acid Esters.- 1.6.1.3 Arsinous Acid Anhydrides with Carboxylic and Phosphorus Acids.- 1.6.1.4 Oxybisarsines, (R2As)2O and (RR?As)2O.- 1.6.1.5 Arsonous Acids.- 1.6.1.6 Arsenoso Compounds.- 1.6.1.7 Arsonous Acid Esters.- 1.6.1.9 Oxybis(hydroxyarsines), [RAs(OH)]2O.- 1.6.2 Compounds with Arsenic-Sulfur Bonds.- 1.6.2.2 Thioarsinous Acid Esters with Thiols.- 1.6.2.3 Thioarsinous Acid Anhydrosulfides with Thioacids.- 1.6.2.4 Thiobisarsines, (R2As)2S and R2AsSAs(S)R2.- 1.6.2.6 Thioarsenoso Compounds.- 1.6.2.7 Dithioarsonous Acid Esters with Thiols.- 1.6.2.8 Dithioarsonous Acid Anhydrosulfides with Thioacids.- 1.7 Compounds of Arsenic Bonded to Group VA Elements.- 1.7.1 Compounds with Arsenic-Nitrogen Bonds.- 1.7.1.1 Aminoarsines, R2AsNR?2.- 1.7.1.4 Diarsinoamines, (R2As)2NR?.- 1.7.1.6 Diaminoarsines, (R2N)2AsR?.- 1.7.2 Compounds with Arsenic-Phosphorus Bonds.- 1.7.2.1 Phosphinoarsines, R2PAsR?2.- 1.7.2.3 Arsinophosphonium Derivatives.- 1.7.2.4 Diarsinophosphines, (R2As)2PR?.- 1.7.2.5 Triarsinophosphines, (R2As)3P.- 1.7.2.6 Diphosphinoarsines, (R2P)2AsR?.- 1.7.2.7 Arsinophosphonic Acid Derivatives, R2AsP(O) (OR?)2.- 1.8 Compounds of Arsenic Bonded to Metals.- 1.8.1 Compounds with Elements of Group IA-IVA Elements.- 1.8.1.1 Compounds with Alkali Metals.- 1.8.1.2 Compounds with Group IIA Metals.- 1.8.1.3 Compounds with Group IIIA Elements.- 1.8.1.4 Compounds with Group IVA Elements 2l.- 1.8.2 Compounds with Transition Metals.- 1.8.2.1 Compounds with Group IB Metals.- 1.8.2.2 Compounds with Group IIB Metals.- 1.8.2.5 Compounds with Group VB Metals.- 1.8.2.6 Compounds with Group VIB Metals.- 1.8.2.7 Compounds with Group VIIB Metals.- 1.8.2.8 Compounds with Group VIII Metals.- 1.9 Miscellaneous Compounds.- 2. Compounds of Pentavalent Arsenic.- 2.1 Quinquenary Derivatives.- 2.2 Quaternary Derivatives.- 2.2.1 Arsonium Ylids.- 2.2.2 Quaternary Arsonium Bases and Salts.- 2.3 Tertiary Derivatives.- 2.3.5 Compounds with Arsenic-Halogen and -Pseudohalogen Bonds.- 2.3.5.2 Dihalo, Tetrahalo, and Dipseudohalo- Derivatives.- 2.3.5.3 Halohydroxy and Haloalkoxy Derivatives.- 2.3.5.9 Miscellaneous Halotriorganoarsenic Derivatives.- 2.3.6 Compounds with Arsenic Bonded to Group VIA Elements.- 2.3.6.1 Compounds with Arsenic-Oxygen Bonds.- 2.3.6.1.1 Monohydroxy Derivatives.- 2.3.6.1.5 Dihydroxy Derivatives.- 2.3.6.1.6 Tertiary Arsine Oxides.- 2.3.6.1.7 Dialkoxy and Dinitrato Derivatives.- 2.3.6.1.9 Oxybis(tertiary Arsine) Derivatives.- 2.3.6.2 Compounds with Arsenic-Sulfur Bonds.- 2.3.6.2.6 Tertiary Arsine Sulfides.- 2.3.6.3 Compounds with Arsenic-Selenium Bonds.- 2.3.6.3.6 Tertiary Arsine Selenides.- 2.3.7 Compounds of Arsenic Bonded to Group VA Elements.- 2.3.7.1 Compounds with Arsenic-Nitrogen Bonds.- 2.3.7.2 Compounds with Arsenic-Phosphorus Bonds.- 2.3.8 Compounds with Arsenic Bonded to Metals.- 2.3.8.1.2 Compounds with Group IIB Metals.- 2.4 Secondary Derivatives.- 2.4.2 Secondary Arsonium Salts.- 2.4.5 Compounds with Arsenic-Halogen Bonds.- 2.4.5.1 Trihalo Derivatives.- 2.4.5.3 Haloarsine Oxides.- 2.4.5.6 Amino-Halo-Arsonium Salts and Related Compounds.- 2.4.6 Compounds with Arsenic Bonded to Group VIA Elements.- 2.4.6.1 Compounds with Arsenic-Oxygen Bonds.- 2.4.6.1.1 Arsinic Acids.- 2.4.6.1.2 Arsinic Acid Esters.- 2.4.7 Compounds of Arsenic Bonded to Group VA Elements.- 2.4.7.1 Compounds with Arsenic-Ni trogen Bonds.- 2.5 Primary Derivatives.- 2.5.5.2 Compounds with Arsenic-Halogen Bonds.- 2.5.6 Compounds with Arsenic Bonded to Group VIA Elements.- 2.5.6.1 Compounds with Arsenic-Oxygen Bonds.- 2.5.6.1.1 Aliphatic Arsonic Acids.- 2.5.6.1.2 Aromatic Arsonic Acids.- 2.5.6.1.2.1 Benzenearsonic Acid and Derivatives with Aliphatic and Arylaliphatic Substituents.- 2.5.6.1.2.2 Halobenzenearsonic Acids.- 2.5.6.1.2.3 Hydroxybenzenearsonic Acids and O-Substituted Derivatives.- 2.5.6.1.2.5 Nitrogen-Substituted Benzenearsonic Acids.- 2.5.6.1.2.5.1 Nitroso- and Nitro-Benzenearsonic Acids.- 2.5.6.1.2.5.2 o-Arsanilic Acid and N-Substituted Derivatives.- 2.5.6.1.2.5.3 m-Arsanilic Acid and N-Substituted Derivatives.- 2.5.6.1.2.5.4 p-Arsanilic Acid and N-Substituted Derivatives.- 2.5.6.1.2.5.6 Azobenzenearsonic Acid Derivatives.- 2.5.6.1.2.5.8 Formazanobenzenearsonic Acid Derivatives.- 2.5.6.1.2.6 Benzenearsonic Acid Derivatives Containing Heterocyclic Substituents.- 2.5.6.1.2.7 Di- to Penta-Substituted Benzenearsonic Acids.- 2.5.6.1.4 Di-, Tri-, and Tetraarsonic Acids.- 2.5.6.1.5 Polymers Containing Arsono Groups.- 2.5.6.1.6 Arsonic Acid Esters.- 2.5.6.2.5 Trithioarsonic Acids.- 2.5.6.2.7 Alkyl- and Arylarsenic Disulfides.- 3. Heterocyclic Arsenic Compounds.- 3.2 Four-Membered Rings.- 3.2.1 Ring Systems with Arsenic Heteroatoms.- 3.2.1.4 Tetrarsetane Derivatives.- 3.2.6 Ring Systems with Arsenic and Sulfur Heteroatoms.- 3.2.9 Ring Systems with Arsenic, Oxygen, and Nitrogen Heteroatoms.- 3.3 Five-Membered Ring Systems.- 3.3.1 Ring Systems with Arsenic Heteroatoms.- 3.3.1.1 Arsolane and Arsole Derivatives.- 3.3.1.5 Diarsolane and Benzodiarsole Derivatives.- 3.3.1.6 Dibenzarsole Derivatives.- 3.3.1.7 Spiro(dibenzarsole) Derivatives and Tris(2,2?-biphenylylene)arsenates.- 3.3.1.8 Spirobi(benzodiarsole) Derivatives.- 3.3.1.9 Miscellaneous Heterocyclic Arsenic Derivatives Containing Five-Membered Rings.- 3.3.5 Ring Systems with Arsenic and Oxygen Heteroatoms.- 3.3.5.1 Oxarsolane, Oxadiarsolane, and Benzoxadiarsole Derivatives.- 3.3.5.2 Diarsolane and Dioxarsindan Derivatives.- 3.3.6 Ring Systems with Arsenic and Sulfur Heteroatoms.- 3.3.6.1 Dithiarsolane and Dithiarsindan Derivatives.- 3.3.7 Ring Systems with Arsenic and Nitrogen Heteroatoms.- 3.3.9 Ring Systems with Three Different Heteroatoms.- 3.3.9.1 Compounds with Arsenic, Oxygen, and Sulfur Heteroatoms.- 3.3.9.3 Compounds with Arsenic, Sulfur, and Nitrogen Heteroatoms 398 3.4 Six-Membered Ring Systems.- 3.4.1 Ring Systems with One Heteroatom.- 3.4.1.2 Arsinoline Derivatives.- 3.4.1.3 Isoarsinoline Derivatives.- 3.4.1.8 Spiroarsinolineisoarsinoline Derivatives.- 3.4.2 Ring Systems with Two Arsenic Heteroatoms.- 3.4.2.1 Diarsenane and Diarsenin Derivatives.- 3.4.2.2 Arsanthrene Derivatives.- 3.4.5 Ring Systems with Arsenic and Oxygen Heteroatoms.- 3.4.5.1 Oxarsinane and Phenoxarsine Derivatives.- 3.4.5.2 Tetroxadiarsaspiro[5,5]hendecane Derivatives.- 3.4.7 Ring Systems with Arsenic and Nitrogen Heteroatoms.- 3.4.7.2 Phenarsazine Derivatives.- 3.4.7.3 Benzophenarsazine Derivatives.- 3.4.7.5 Dibenzo-, Tribenzo-, Benzonaphtheno-, Dinaphtho-, and Benzophenaleno-phenarsazine Derivatives.- 3.4.7.7 Benzarsazinothianaphthene Derivatives.- 3.4.7.8 Triazatriarsenine Derivatives.- 3.5 Seven-Membered Ring Systems.- 3.5.1 Ring Systems with One Heteroatom.- 3.5.1.1 Arsepin Derivatives.- 3.6 Eight-Membered Ring Systems.- 3.6.2 Ring Systems with Two Arsenic Heteroatoms.- 3.6.2.1 Dibenzodiarsocin Derivatives.- 3.6.6 Ring Systems with Arsenic and Sulfur Heteroatoms.- 3.6.6.4 Tetrathiatetrarsocane Derivatives.- 3.6.7 Ring Systems with Arsenic and Nitrogen Heteroatoms.- 3.6.7.4 Tetrarsatetrazocine Derivatives.- 3.7 Nine-Membered Ring Systems.- 3.7.1 Ring Systems with One Heteroatom.- 3.7.1.1 Tetrabenz[b,d,f,h]arsonin Derivatives.- 3.7.2 Ring Systems with Two Arsenic Heteroatoms.- 3.7.2.2 Tribenzo[d,f,h][1,3]diarsonin Derivatives.- 3.8 Ten-Membered Ring Systems.- 3.8.2 Ring Systems with Two Arsenic Heteroatoms.- 3.8.2.1 Tribenzodiarsecin Derivatives.- 3.9 Large Ring Systems.- 3.9.1 Eleven-Membered Ring Systems.- 3.9.2 Twelve-Membered Ring Systems.- Antimony.- 1. Compounds of Trivalent Antimony.- 1.1 Tertiary Stibines.- 1.1.1 Symmetric Derivatives.- 1.1.2 Unsymmetric R2R?Sb Stibines.- 1.1.4 Ditertiary Stibines.- 1.2 Secondary Stibines.- 1.3 Primary Stibines.- 1.4 Compounds with Sb-Sb Bonds.- 1.4.1 Distibines.- 1.5 Compounds with Antimony-Halogen and Antimony-Pseudohalogen Bonds.- 1.5.1 Secondary Halostibines, R2SbX and RR?SbX.- 1.5.2 Primary Dihalostibines.- 1.5.5 Secondary Pseudohalostibines.- 1.5.6 Primary Pseudohalostibines.- 1.5.9 Miscellaneous Halostibine Derivatives.- 1.6 Compounds of Antimony Bonded to Group VIA Elements.- 1.6.1 Compounds with Antimony-Oxygen Bonds.- 1.6.1.2 Stibonous Acid Esters.- 1.6.1.3 Stibinous Acid Anhydrides with Carboxylic Acids.- 1.6.1.4 Oxybisstibines, (R2Sb)2O.- 1.6.1.6 Stiboso Compounds.- 1.6.1.7 Stibonous Acid Esters.- 1.6.2 Compounds with Antimony-Sulfur Bonds.- 1.6.2.2 Thiostibinous Acid Esters with Thiols.- 1.6.2.3 Thiostibinous Acid Anhydrosulfides with Thioacids.- 1.6.2.4 Thiobisstibines.- 1.6.2.6 Thiostiboso Compounds.- 1.6.2.7 Dithiostibonous Acid Esters with Thiols.- 1.6.2.8 Dithiostibonous Acid Anhydrosulfides with Thioacids.- 1.7 Compounds of Antimony Bonded to Group VA Elements.- 1.7.1 Compounds with Antimony-Nitrogen Bonds.- 1.7.1.1 Secondary Stibinoamine, R2SbNR?2.- 1.7.1.6 Stibylenediamines.- 1.8 Compounds of Antimony Bonded to Metals.- 1.8.1 Compounds with Elements of Groups IA to IVA.- 1.8.1.1 Compounds with Group IA Elements.- 1.8.1.2 Compounds with Group IIA Elements.- 1.8.1.3 Compounds with Group IIIA Elements.- 1.8.1.4 Compounds with Group IVA Elements.- 1.8.2 Compounds with Transition Metals.- 1.8.2.8 Compounds with Group VIII Metals.- 2. Compounds of Pentavalent Antimony.- 2.1 Quinquenary Derivatives.- 2.2 Quaternary Derivatives.- 2.2.1 Antimony Ylids.- 2.2.2 Quaternary Stibonium Bases and Salts.- 2.2.4 Quaternary Alkoxy-Antimony Derivatives.- 2.3 Tertiary Derivatives.- 2.3.2 Trialkylstibonium Salts.- 2.3.5 Compounds with Antimony-Halogen Bonds.- 2.3.5.2 Dihalo and Tetrahalo Derivatives.- 2.3.5.3 Halohydroxy, Haloalkoxy, and Halosiloxy Derivatives.- 2.3.5.6 Dipseudohalo Derivatives.- 2.3.6 Compounds with Antimony Bonded to Group VIA Elements.- 2.3.6.1 Compounds with Antimony-Oxygen Bonds.- 2.3.6.1.5 Dihydroxy Derivatives and the Corresponding Salts.- 2.3.6.1.6 Tertiary Stibine Oxides.- 2.3.6.1.7 Dialkoxy, Diaryloxy, and Diquinolinolato Derivatives.- 2.3.6.1.8 Tertiary Stibine Peroxide Derivatives.- 2.3.6.1.9 Oxybis(tertiary Antimony) Derivatives, (R3SbX)2O.- 2.3.6.2 Compounds with Antimony-Sulfur Bonds.- 2.3.6.2.6 Tertiary Stibine Sulfides.- 2.3.6.2.8 Bis(acylthio)antimony Derivatives.- 2.3.7 Compounds of Antimony Bonded to Group VA Elements.- 2.3.7.1 Compounds with Antimony-Nitrogen Bonds.- 2.3.7.1.4 Iminobisantimony Derivatives.- 2.3.7.1.7 Tertiary Stibine Imides.- 2.4 Secondary Derivatives.- 2.4.5 Compounds with Antimony-Halogen Bonds.- 2.4.5.1 Trihalo Derivatives.- 2.4.6 Compounds of Antimony Bonded to Group VIA Elements.- 2.4.6.1 Compounds with Antimony-Oxygen Bonds.- 2.4.6.1.2 Triaryloxy Derivatives, R2Sb(OR?)3.- 2.4.6.1.3 Stibinic Acid Anhydrides.- 2.4.6.1.9 Oxybis(secondary Antimony) Derivatives.- 2.5 Primary Derivatives.- 2.5.5 Compounds with Antimony-Halogen Bonds.- 2.5.5.2 Tetrahalo Derivatives.- 2.5.5.3 Trihaloenolato Derivatives.- 2.5.6 Compounds of Antimony Bonded to Group VIA Elements.- 2.5.6.1 Compounds with Antimony-Oxygen Bonds.- 2.5.6.1.2 Aromatic Stibonic Acids.- 2.5.6.1.2.1 Benzenestibonic Acid and Derivatives with Aliphatic and Arylaliphatic Substituents.- 2.5.6.1.2.3 Hydroxybenzenestibonic Acid and 0-Substituted Derivatives.- 2.5.6.1.2.5 Nitrogen-Substituted Benzenestibonic Acid Derivatives.- 2.5.6.1.4 Distibonic Acids.- 2.5.6.1.9 Tetrakisaryloxy Derivatives.- 3. Heterocyclic Antimony Compounds.- 3.2.1 Four-Membered Rings with Antimony Heteroatoms.- 3.2.1.4 Tetrastibetane Derivatives.- 3.2.5 Ring Systems with Antimony and Oxygen Heteroatoms.- 3.2.6 Ring Systems with Antimony and Sulfur Heteroatoms.- 3.2.9 Ring Systems with Three Different Heteroatoms.- 3.2.9.1 Compounds with Antimony, Oxygen, and Sulfur Heteroatoms.- 3.2.9.2 Compounds with Antimony, Oxygen, and Nitrogen Heteroatoms.- 3.3 Five-Membered Ring Systems.- 3.3.1 Ring Systems with One Heteroatom.- 3.3.1.6 Dibenzostibole Derivatives.- 3.3.5 Ring Systems with Antimony and Oxygen Heteroatoms.- 3.3.5.2 Dioxastibolane Derivatives.- 3.3.6 Ring Systems with Antimony and Sulfur Heteroatoms.- 3.3.6.1 Dithiastibole Derivatives.- 3.6 Eight-Membered Ring Systems.- 3.6.7 Ring Systems with Antimony and Nitrogen Heteroatoms.- Bismuth.- 1. Compounds of Trivalent Bismuth.- 1.1 Tertiary Bismuth.- 1.1.1 Symmetric Derivatives.- 1.1.4 Ditertiary Bismuthines.- 1.2 Secondary Bismuthines.- 1.4 Compounds with Bi-Bi Bonds.- 1.4.1 Dibismuthines.- 1.5 Compounds with Bismuth-Halogen and Bismuth-Pseudohalogen Bonds.- 1.5.1 Secondary Halobismuthines.- 1.5.2 Primary Dihalobismuthines.- 1.5.5 Secondary Pseudohalobismuthines.- 1.5.6 Primary Pseudohalobismuthines.- 1.6 Compounds with Bismuth Bonded to Group VIA Elements.- 1.6.1 Compounds with Bismuth-Oxygen Bonds.- 1.6.1.1 Secondary Hydroxybismuthines.- 1.6.1.2 Secondary Alkoxy- and Aryloxy-Bisrauthines.- 1.6.1.3 Secondary Acyloxybismuthines.- 1.6.1.6 Primary Oxobismuthines.- 1.6.1.7 Primary Dialkoxy- and Diaryloxy-Bismuthines.- 1.6.1.8 Primary Bis(acyloxy)bismuthines.- 1.6.2 Compounds with Bismuth-Sulfur Bonds.- 1.6.2.2 Secondary Alkylthiobismuthines.- 1.6.2.6 Primary Thioxobismuthines.- 1.6.2.7 Primary Bis(thio)bismuthine Derivatives, RBi(SR?)2.- 1.6.2.8 Primary Bis(carbamoyl)bismuthines.- 1.7 Compounds of Bismuth Bonded to Group VA Elements.- 1.7.1 Compounds with Bismuth-Nitrogen Bonds.- 1.8 Compounds of Bismuth Bonded to Metals.- 1.8.1 Compounds with Elements of Groups IA to IVA.- 1.8.1.3 Compounds with Group IIIA Metals.- 1.8.1.4 Compounds with Group IVA Metals.- 1.8.2 Compounds with Transition Metals.- 1.8.2.7 Compounds with Group VIIB Metals.- 2. Compounds of Pentavalent Bismuth.- 2.1 Quinquenary Derivatives.- 2.2 Quaternary Derivatives.- 2.2.1 Bismuth Ylids.- 2.2.2 Quaternary Bismuthonium Salts.- 2.3 Tertiary Derivatives.- 2.3.5 Compounds with Bismuth-Halogen Bonds.- 2.3.5.2 Dihalo Derivatives.- 2.3.5.3 Halohydroxy Derivatives.- 2.3.5.6 Dipseudohalo Derivatives.- 2.3.5.9 Miscellaneous Tertiary Bismuth Derivatives.- 2.3.6 Compounds with Bismuth Bonded to Group VIA Elements.- 2.3.6.1 Compounds with Bismuth-Oxygen Bonds.- 2.3.6.1.3 Dihydroxybismuth Derivatives and Their Anhydrides with Inorganic and Carboxylic Acids.- 2.3.6.1.6 Tertiary Bismuthine Oxides.- 2.3.6.1.7 Dialkoxy and Diaryloxy Derivatives.- 2.3.6.2 Compounds with Bismuth-Sulfur Bonds.- 2.3.6.2.6 Tertiary Bismuthine Sulfides.- 2.3.6.2.9 Miscellaneous Tertiary Bismuth Compounds.- 2.4 Secondary Derivatives.- 2.4.6 Compounds with Bismuth Bonded to Group VIA Elements.- 2.4.6.1 Compound with Bismuth-Oxygen Bonds.- Supplement.- Review Publications and Monographs.