A comprehensive survey of the field, this second edition has been thoroughly revised to include new material on nucleophilic aromatic substitution and organometallic reactions and reorganized for greater ease of use. The number of references has increased by more than 50%. Starting with a thorough discussion on the underlying physicochemical principles and extending through applications in various fields of synthesis, this book is written with the practicing chemist in mind and provides typical experimental procedures for more frequently used applications of phase transfer catalysis.
Reihe
Auflage
Sprache
Verlagsort
Zielgruppe
Für höhere Schule und Studium
Für Beruf und Forschung
Editions-Typ
Illustrationen
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ISBN-13
978-3-527-25897-0 (9783527258970)
Schweitzer Klassifikation
Ion Pairs and Ion Pair Extraction; Introduction: The Nature of Phase Transfer Catalysis; Ion Pairs in Organic Media; Extraction of Ion Pairs from Aqueous Solution; Crown Ethers, Cryptates, and Other Chelating Agents as Extractants; Solid-Liquid Anion Exchange; Mechanism of Phase Transfer Catalysis; Mechanistic Investigations; Empirical Catalyst Evaluations; Unusual and Polymer Supported Catalysts; Practical Applications of Phase Transfer Catalysis; General Experimental Procedures; Formation of Halides; Preparation of Nitriles; Ester Formation; Miscellaneous Displacements; Thiols and Sulfides; Preparation of Ethers; N-Alkylations; C-Alkylation of Activated CH-Bonds; Alkylation of Ambident Anions; Isomerizations and H/D Exchange; Additions across Multiple CC-Bonds; Addition to C=O and C=N Bonds; b'-Eliminations; Hydrolysis Reactions; Generation and Conversion of Phosphonium and Sulfonium Ylides; Nucleophilic Aromatic Substitution; Miscellaneous Reactions; Organometallic PTC Applications; a'-Eliminations; Reduction Reactions; Oxidation Reactions; References; Subject Index.
