This work on entropy analysis emphasizes the central role of the entropy function in determining thermodynamic outcomes and in doing so, employs direct application of the second law and the harmonic oscillator and cell models to display the workings of the entropy function at the microscopic level. At the same time, the book only uses minimum mathematics (finite differences and no calculus); emphasizes useful approximations; provides numerous examples of thermodynamic reasoning and of chemical problem-solving; and includes applications for electrochemical systems with a unified treatment of galvanic cells and electrolysis cells.
Reihe
Sprache
Verlagsort
Zielgruppe
Für höhere Schule und Studium
Für Beruf und Forschung
Illustrationen
Maße
Höhe: 235 mm
Breite: 155 mm
ISBN-13
978-3-527-89539-7 (9783527895397)
Schweitzer Klassifikation
Energy principle - the first law; the enthalpy function; the entropy principle - the second law; everyday energy convertors - refrigerators and heat engines; entropy from a microscopic point of view; the Gibbs free energy function; chemical equilibrium; electrochemical cells; energy conversions.