This database examines the use of the Scienta ESCA300 spectrometer in polymer surface analysis. The prototype, developed jointly with ICI, has been used in the systematic reinvestigation of over 100 standard homo polymers. It provides the full spectral information: survey and core line regions (with fitted components), shake-up spectra, valence bands and in some cases, Auger spectra. All the data are parameterized and tabulated, and full details of sample preparation etc. are given. The instrument performance and operating conditions are extensively documented.
Sprache
Verlagsort
Verlagsgruppe
Zielgruppe
Für höhere Schule und Studium
Für Beruf und Forschung
Maße
Höhe: 237 mm
Breite: 157 mm
Gewicht
ISBN-13
978-0-471-93592-6 (9780471935926)
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Schweitzer Klassifikation
Description of the spectrometer; x-ray source; monochromator; electron lens; hemispherical analyser; multichannel detector; sample analysis chamber; charge compensation; performance on conducting samples; performance on insulating samples; performance on testing of the spectrometer; experimental protocol; sample mounting; data acquisition; correction of binding energy scale for sample charging; curve fitting; lineshapes; shake-up structure; valence bands; impurities; x-ray degradation; organization of the database; list of polymers and acronyms; the database; appendix 1 - primary C 1s shifts; appendix 2 - secondary C 1s shifts; appendix 3.1 - 0 1s binding energies in CHO polymers; appendix 3.2 - 0 1s binding energies in other polymers; appendix 4 - N 1s binding energies; appendix 5 - F 1s binding energies; appendix 6 - binding energies and spin-orbit constants for core-line doublets; apendix 7 - binding energies of peaks appearing in the valence band region.