This book describes modern electochemistry, beginning at elementary level and progressing through to the most recent advances in this interdisciplinary subject. The material is presented in three main parts. The first introduces the fundamental principles of thermodynamics, kinetics, and mass transport associated with electrode reactions. The second considers experimental methods that are available to study electrode and electrochemical processes: steady-state with forced convection, linear sweep and step/pulse voltammetric techniques and impedance, together with modern surface analysis, microscopic, and spectroscopic procedures that complement the elctrochemical information. The third part discusses wide-ranging applications, including sensors, industrial electrolysis and batteries, corrosion studies, and the rapidly expanding field of bioelectrochemistry. Easily accessible appendixes provide the necessary mathematical basics, principles of electrical circuits, and digital simulation.
Sprache
Verlagsort
Zielgruppe
Für höhere Schule und Studium
Für Beruf und Forschung
Illustrationen
228 line drawings, 3 half-tones
ISBN-13
978-0-19-855389-2 (9780198553892)
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Schweitzer Klassifikation
Part 1 Principles: electrochemical cells - thermodynamic properties and electrode potentials; the interfacial region; fundamentals of kinetics and mechanism of electrode reactions; mass transport; kinetics and transport in electrode reactions. Part 2 Methods: electrochemical experiments; hydronamic electordes; cyclic voltammetry and linear sweep techniques; step and pulse techniques; impedance methods; non-electrochemical probes of electordes and electrode processes. Part 3 Applications: potentiometric sensors; amperometric and voltammetric sensors; electrochemistry in industry; corrosion; bioelectrochemistry. Appendices: useful mathematical relations; principles of A.C. circuits; digital simulation; standard electrode potentials.