Organoselenium chemistry is proving increasingly valuable to the synthetic organic chemist. Selenium residues are easily introduced into organic molecules, they serve to effect a variety of useful transformations, and are easily removed at the end of the sequence. These processes are often characterized by high chemo- regio- and stereoselectivity. Recent enantioselective variations of selenium-mediated reactions are further extending their scope and utility. The use
of organoselenium compounds in organic conductors is another area of intense current interest. Organoselenium Chemistry - A Practical Approach is written by an international group of experts in the field.
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Höhe: 241 mm
Breite: 160 mm
Dicke: 21 mm
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978-0-19-850141-1 (9780198501411)
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Schweitzer Klassifikation
Professor Thomas G. Back Department of Chemistry University of Calgary 2500 University Drive N. W. Calgary, AB, Canada, T2N 1N4
Herausgeber*in
Department of ChemistryUniversity of Calgary
Preface ; 1. Organoselenium chemistry: an overview ; 2. Selenoxide eliminations ; 3. Addition of Electrophilic Organoselenium Reagents to Carbon-Carbon Double Bonds ; 4. Reactions of selenium nucleophiles ; 5. Oxidations with selenium reagents ; 6. Reductions with selenium reagents ; 7. Reactions of selenium-stabilized carbanions ; 8. Reactions of selenium stabilized carbocations ; 9. Free-radical reactions and reductive deselenizations ; 10. Selenium extrusion reactions ; 11. Sigmatropic rearrangements of organoselenium compounds ; 12. Synthesis and reactions of carbonyl selenide and isoselenocyanates ; 13. Reactions of selenones ; 14. Preparation of organic conductors ; Bibliography ; Appendix ; Index
