Recent Advances in Post-Combustion CO2 Capture Chemistry

Name: Recent Advances in Post-Combustion CO2 Capture Chemistry
Brand: Oxford University Press Inc
Price: 240.5 EUR
Availability: OutOfStock

Moetaz Attalla(Herausgeber*in)

Oxford University Press Inc

Erschienen am 14. März 2013

Buch

Hardcover

360 Seiten

978-0-8412-2621-0 (ISBN)

240,50 €inkl. 7% MwSt.

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Beschreibung

Carbon dioxide has become a major target for emission reduction strategies due to its rapidly increasing atmospheric levels. The dominant driving force is anthropogenic carbon dioxide emissions from fossil fuel combustion and industrial processes. It is for this reason aqueous amine based carbon capture technologies of carbon dioxide generated from these sources has been identified as a crucial part of the global solution to mitigating these greenhouse gas emissions.

Since the 1980's, amine-based post combustion carbon dioxide capture has become widely recognized as the most viable and near-ready technology to reduce carbon dioxide emissions in the midterm. However, the large scale roll-out of the technology has been hindered by a number of technical challenges, several of which are addressed in the chapters of this monograph, including i) cost of scaleup; ii) energy efficiency penalty for solvent regeneration; iii) solvent degradation in the presence of
the various flue gas constituents; and iv) the potential environment impacts of solvents and solvent degradation products released to the environment. In line with this resurgence in the technology a considerable amount of research was undertaken in an attempt to further understand the chemistry
involved in the capture of carbon dioxide from flue gas streams using aqueous amines. In developing amine-based post combustion carbon dioxide capture as a commercially viable solution for the reduction of carbon dioxide emissions in a carbon-constrained future, researchers worldwide are addressing all challenges to the technology to accelerate its implementation while maintaining a realistic approach to the economics of the process and its environmental impacts. Over the past 6-7 years there
has been an intense global resurgence in developing a deeper understanding of the chemistry of post combustion carbon dioxide capture in an endeavor to reduce the cost of the process and determine the environmental footprint of this technology to make it a practical option for mitigating carbon
dioxide emissions from coal-fired power stations.

The chapters in this monograph are contributions from the Chemistry of Post- Combustion Carbon Dioxide Capture symposium held at the Pacifichem 2010, International Chemical Congress of Pacific Basin Societies. The symposium was dedicated to capturing snapshots of the most recent advances in carbon dioxide capture using solvent-based post combustion carbon dioxide capture technology.

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Inhalt

Preface ; 1. The Effect Molecular Structural Variations Has on the CO2 Absorption Characteristics of Heterocyclic Amines ; K. Robinson, A. McCluskey, and M. I. Attalla ; 2. Influence of Amine Chemical Structures to Amine Capacities in CO2 Capture ; Qi Yang, Susan James, Mathew Ballard, and Mark Bown ; 3. Kinetics and Dissociation Constants (pKa) of Polyamines of Importance in Post-Combustion Carbon Dioxide (CO2) Capture Studies ; F. Khalili, A. V. Rayer, A. Henni, A. L. L. East, and P. Tontiwachwuthikul ; 4. CO2 Absorption Characteristics of 2-Isopropylaminoethanol (IPAE) Aqueous Solution ; K. Goto, F. A. Chowdhury, S. Kodama, H. Okabe, and Y. Fujioka ; 5. Novel Amine Solution Development for High Pressure CO2 Capture and Application Examination to IGCC Gas ; Shin Yamamoto, Hiroshi Machida, Yuichi Fujioka, Takayuki Higashii, and Shingo Kazama ; 6. The Kinetics and Thermodynamics of CO2 Capture by Aqueous Ammonia Derived Using Meta-GGA Density Functional Theory and Wavefunction-Based Model Chemistry Methods ; P. Jackson, A. Beste, and M. I. Attalla ; 7. Theoretical Study of Optimal Conditions in Continuous CO2 Capture Process Using Aqueous Ammonia Solution ; S. Y. Park, C. H. Ko, J. H. Park, and J. N. Kim ; 8. Tailoring Ionic Liquids for Post-Combustion CO2 Capture ; Hanming Liu, Junhua Huang, and Phillip Pendleton ; 9. Silica/Polyethyleneimine Composite Adsorbent S-PEI for CO2 Capture by Vacuum Swing Adsorption (VSA) ; Gregory P. Knowles, Paul A. Webley, Zhijian Liang, and Alan L. Chaffee ; 10. Environmental Impacts of Post-Combustion Capture: New Insight ; M. I. Attalla, P. Jackson, and K. Robinson ; 11. Oxidation of Aqueous Piperazine: Oxidation Rates, Products, and High-Temperature Oxidation ; Stephanie A. Freeman, Fred B. Closmann, and Gary T. Rochelle ; 12. Identification and Quantification of Degradation Products by Ion Chromatography ; Solrun Johanne Vevelstad, Andreas Grimstvedt, Helene Lepaumier, Kolbjorn Zahlsen, Marianne Steinsvik Kjos, Jacob N. Knudsen, and Hallvard F. Svendsen ; 13. Sequential Degradation of Aqueous Monoethanolamine for CO2 Capture ; Alexander K. Voice, Daniel Wei, and Gary T. Rochelle ; 14. An Investigation into the Photochemistry of Monoethanolamine (MEA) in NOx ; Dennys Angove, Merched Azzi, Anne Tibbett, and Ian Campbell ; 15. Surpassing Photosynthesis: High-Efficiency and Scalable CO2 Utilization through Artificial Photosynthesis ; Y.-H. Percival Zhang, Chun You, Hongge Chen, and Rui Feng ; 16. Developing Efficient Amine-Containing Mesoporous CO2 Adsorbent ; Kun Kun Han and Jian Hua Zhu ; 17. Energy Performance of New Amine-Based Solvents for CO2 Capture from Blast Furnace Gas ; K. Goto, S. Kodama, H. Okabe, and Y. Fujioka ; Editor>'s Biography ; Indexes ; Author Index ; Subject Index

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