History of Organometallic Chemistry.- History of Organometallic Chemistry.- Structures of the Transition-Metal Complexes.- Monometallic Transition-Metal Complexes.- Bimetallic Transition-Metal Complexes and Clusters.- The Stoichiometric Reactions of Transition-Metal Complexes.- Redox Reactions, Oxidative Addition and ?-Bond Metathesis.- Reactions of Nucleophiles and Electrophiles with Complexes.- Ligand Substitution Reactions.- Insertion and Extrusion Reactions.- The Main Families of Organometallic Complexes.- Metal Carbonyls and Complexes of Other Monohapto L Ligands.- Metal-Alkyl and -Hydride Complexes and Other Complexes of Monohapto X Ligands.- Metal-Carbene and -Carbyne Complexes and Multiple Bonds with Transition Metals.- ? Complexes of Mono- and Polyenes and Enyls.- Metallocenes and Sandwich Complexes.- Ionic and Polar Metal-Carbon Bonds: Alkali and Rare-Earth Complexes.- Covalent Chemistry of the Organoelements of Frontier (11, 12) and Main (13-16) Groups.- Catalysis.- to Catalysis.- Hydrogenation and Hydroelementation of Alkenes.- Transformations of Alkenes and Alkynes.- Oxidation of Olefins.- C-H Activation and Functionalization of Alkanes and Arenes.- Carbonylation and Carboxylation Reactions.- Bio-Organometallic Chemistry: Enzymatic Catalysis.- Heterogeneous Catalysis.- Applications in Organic Synthesis.- Organometallic Complexes in Organic Synthesis Examples of Applications.
