
Metals and Metal-Based Electrocatalytic Materials for Alternative Energy Sources and Electronics
Beschreibung
Weitere Details
Weitere Ausgaben
Inhalt
- Intro
- Contents
- Preface
- Chapter 1
- Interactive Catalytic Performances of Carbonaceous Materials in Electrochemistry
- Abstract
- 1. Glassy Carbon Characterization and Activation
- 1.1. Anodic Polarization
- 1.2. Cathodic Polarization
- 1.3. Auger-Electron Spectroscopy (AES)
- 1.4. X-Ray Photoelectron Spectroscopy (XPS)
- 1.5. Scanning Tunnelling Microscopy (STM)
- 2. Meth Modification of Glassy Carbon: A Case of Immersion in AgNO3 Solution
- 2.1. Cyclic Voltammetry
- 2.2. Surface Characterization
- 2.3. Scanning Tunnelling Microscopy (STM)
- 3. Carbon as a Electrocatalyst Support: Structure - Activity Relationships
- 3.1. Voltammetric Behavior
- 3.2. The Changes in Surface Morphology
- 3.3. EIS Manifestations of Differently Activated GC
- 3.4. MEO Activity of GC- and GCox-Supported Pt Black
- 4. Capacitive Properties of Thin-Layer Carbon Black Electrodes
- 4.1. CV Potential Window of Carbon Black Cycling Stability
- 4.2. Sweep Rate-Dependent Voltammetric Features of BP and XC
- 4.3. Electrochemical Impedance Spectroscopy
- Acknowledgments
- References
- Chapter 2
- Innovative Approaches toward the Synthesis of Electroactive RuO2-Based Materials of Intrinsic Structures
- Abstract
- 1. Introduction
- 1.1. Supercapacitors and Electrochemically Active Oxides as Their Plates
- 1.2. Synthesis of Ruthenium Oxide for Supercapacitor and Electrode Applications
- 1.3. Microwave Heating in Chemical Synthesis
- 1.3.1. Application of Microwave Heating
- 2. Microwave-Assisted Synthesis of RuO2 and Its Supercapacitive Properties
- 2.1. MW Synthesis of Colloidal RuO2 Suspensions
- 2.2. Physicochemical Properties of MW-Synthesised RuO2 Suspensions
- 2.2.1. Polydispersity Consideration
- 2.2.2. The Growth of Bulk Material from MW-Synthesised RuO2 Particles
- 2.3. Charging/Discharging Capabilities of Bulk MW-Synthesised RuO2 Supercapacitive Layers
- 3. Electroactive Titanium Anode Coatings from MW-Synthesised RuO2
- 3.1. Dimensionally Stable Anodes (DSA®)
- 3.2. MW-Based Preparation of DSA Coatings
- 3.3. The Electrochemical Properties of MW-Synthesised RuO2/Ti Electrodes
- 3.4. Anodic Polarisation Measurements
- 3.5. Electrochemical Impedance Spectroscopy Measurements
- 3.6. The Effect of MW Temperature on EIS Parameters of MW-Synthesised RuO2/Ti Electrodes
- Conclusion and Perspectives
- Acknowledgments
- References
- Chapter 3
- Catalytic Activity and Stability of Pt and Pt-Based Electrodes towards the Formic Acid Oxidation
- Abstract
- 1. Introduction
- 2. About Our Research
- 2.1. Pt and Pt-Based Bulk Catalysts
- 2.1.1. Activity of Polycrystalline Pt and Pt-Bi Bulk Alloys in FAO
- 2.1.2. Stability of Polycrystalline Pt and Pt-Bi Bulk Alloys in FAO
- 2.2. Pt and Pt-Based Nanocatalysts
- 2.2.1. Activity of Carbon Supported Pt and PtRu Catalysts for FAO
- 2.2.2. Activity of FAO at Platinum-Bismuth Clusters
- 2.2.3. Stability of Platinum-Bismuth Clusters in FAO
- 2.2.4. Activity of FAO on Pt(Bi)/GC Core-Shell Catalysts
- 2.3. Surface Modifed Pt and Pt-Based Nanocatalysts
- Conclusion
- Acknowledgments
- References
- Chapter 4
- Structural, Electrocatalytic and Capacitive Properties of Ruthenium/Titanium-Oxide Based Electrodes Synthesized by Novel Methods
- Abstract
- 1. Introduction
- 1.1. Metal Oxides as Electrocatalytic Materials
- 1.2. Types of Synthesis of Modern Electrocatalysts
- 2. Titanium Based Anodes
- 2.1. Titanium Dioxide in General
- 2.2. Ruthenium Oxide in General
- 2.2.1. Activated Titanium Anodes and Their Service Lives
- 2.2.2. Dimensionally Stable Anodes in Industrial Electrochemical Processes
- 2.3. The Stability of Dimensionally Stable Anodes
- 3. The Activity of Activated Titanium Anodes
- 3.1. Chlorine Evolution
- 3.2. Oxygen Evolution
- 3.3. Electrochemical Remediation of Water and Soil
- 4. Spray Pyrolysis Technique for DSA Coating Synthesis
- 4.1. Spray Pyrolysis for Material Synthesis
- 4.1.1. Ultrasonic Spray Pyrolysis Technique
- 5. Physicochemical and Electrochemical Characteristics of Ruthenium and Titanium Oxides
- 5.1. Physicochemical Structure of Titanium Oxide Sol
- 5.2. Characteristics of Binary RuO2-TiO2 Oxide
- 5.3. The Structure and Morphology of RuO2-TiO2 Sol Particles and Corresponding DSA Coatings
- 6. Electrochemical Behavior of the Activated Titanium Electrodes
- 6.1. Cyclic Voltammetry Measurements
- 6.2. Electrochemical Impedance Spectroscopy
- 6.3. The Stability of Activated Titanium Electrodes
- 6.3.1. The Changes in Electrochemically Active Surface Area during Deactivation
- Conclusion
- Acknowledgments
- References
- Chapter 5
- Novel Biodegradable Composites Based on Lignocellulose and Electrodeposited Copper Powders
- Abstract
- 1. Introduction
- 1.1. Biomaterials - Biopolymers
- 1.2. Biocomposites
- 1.3. Lignocellulose
- 1.4. Polymers with Metal Fillers
- 1.5. Electrical Conductivity of Composites and Percolation Theory
- 1.5.1. Conducting Polymer Composites
- 1.5.2. Models of Electrical Conductivity in Composites with Metal Fillers
- 1.5.2.1. Continuum Percolation Models for Electric Conductivity
- 1.5.2.2. Continuum Percolation Model for Non Spherical Particles
- 2. Lignocellulose and PMMA Based Polymer Composites with Copper as Filler
- 2.1. Characteristics of Electrolytic Copper Powder Used as Filler
- 2.2. Lignocellulose
- 2.3. Lignocellulose Polymer Composites
- 2.4. Poly(methylmetacrylate) (PMMA) polymer composites
- Conclusion
- Acknowledgments
- References
- Chapter 6
- Chemical and Electrochemical Synthesis of Contemporary Materials Based on Biopolymers and Metals
- Abstract
- 1. Introduction
- 2. Chemical Grafting of Vinyl Monomers onto Biopolymers
- 3. Electrochemical Synthesis of Grafted Biopolymers with Vinyl Monomers
- 4. The Application of New Grafted Biopolymers for the Selective Sorption of Noble Metals
- 5. Thermogravimetric Analysis of Biopolymers and Grafted Biopolymers
- 6. Electrochemical Synthesis of Metal Powders
- 7. Composites and Nanocomposites Made from Metals and Biopolymers
- 8. Chemical and Electrochemical Synthesis of Electrically Conducting Biopolymers
- 9. Electrical Conductivity of Composite Biopolymers Filled with Metal Powders
- Conclusion
- Acknowledgments
- References
- Chapter 7
- Copper Electrorefining from Anodes with Non-Standard Content of Ni, Pb, Sb and Sn
- Abstract
- 1. Theoretical Background
- 2. Investigation with Non-Standard Anodes
- 2.1. Materials and Electrochemical Methods
- 2.1.1. Equipment
- 2.1.2. Copper Anodes with High Content of Ni, Pb, Sb and Sn
- 2.1.3. Starting Cathodes
- 2.1.4. Working Solution
- 2.1.5. Organic Additives
- 2.2. Input Data Obtaining
- 3. Influencing Parameters and Correlation
- 3.1. Chemical Composition of Copper Anodes
- 3.2. Anodes Mass Changing
- 3.3. Chemical Composition Change of the Working Solution
- 3.4. Anode Slime
- 3.5. Cell Voltage
- 3.6. Copper Mass Balance
- Conclusion
- Acknowledgments
- References
- Chapter 8
- Advances in Alkaline Water Electrolyzer Catalysis
- Abstract
- 1. Introduction
- 1.1. Renewable Power Sources and Hydrogen Energy
- 1.2. Hydrogen Production
- 1.3. Water Electrolysis
- 2. Alkaline Water Electrolysis
- 2.1. Monopolar Alkaline Electrolyzers
- 2.2. Bipolar Alkaline Electrolyzers
- 3. Energy Efficiency and Catalytic Effects in the Electrolytic Process
- 3.1. Electrocatalysis
- 4. In-Situ Activation in Alkaline Water Electrolysis
- 4.1. Binary D-Metal Combinations for In-Situ Activation
- 4.1.1. Energy Saving in Alkaline Electrolysis
- 4.1.2. The Electrocatalysis of In-Situ Activated Alkaline Electrolysis
- 4.2. Ternary D-Metal Combinations for In-Situ Activation
- 4.3. Ni and Stainless Steel Electrodes and an In-Situ Activated Alkaline Electrolyzer
- References
- Chapter 9
- Aluminium and Magnesium Alloy Synthesis by Means of Underpotential Deposition from Low Temperature Melts
- Abstract
- 1. Underpotential Deposition and Alloy Generation, History, Theory, Techniques and Contemporary Developments
- 2. Common Features of the Systems Studied
- 2.1. Linear Sweep Voltammograms: Influence of Deposition Time and Temperature
- 2.2. Low-Current Galvanostatic Stripping
- 2.3. Alloy Formation
- 2.4. Thickening of Intermetallic Compound Layers as a Function of Time
- 2.5. Calculation of Gibbs Energy of Alloy Formation from Potential Data
- 3. Aluminium Underpotential Deposition on Various Substrates from Chloroaluminate Melts and the Resulting Alloys
- 3.1. Deposition of Al on Au
- 3.2. Deposition of Al on Ag
- 3.3. Deposition of Al on Cu
- 3.4. Deposition of Al on Fe
- 3.5. Deposition of Al on Cd
- 3.6. Deposition of Al on Zn
- 3.7. Deposition of Al on V
- 4. Mg Deposition on Al, Pt and Au from Nitrate Melts
- 5. Al and Nb Codeposition on Au from Chloroaluminate Melts
- Acknowledgments
- References
- About the Editor
- Index
- Blank Page
- Blank Page
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