Extraction Chromatography

Name: Extraction Chromatography
Brand: Elsevier
Price: 54.95 EUR
Availability: OnlineOnly

G. Ghersini(Autor*in)

Elsevier (Verlag)

Erschienen am 1. Juni 1975

565 Seiten

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978-0-08-085802-9 (ISBN)

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Front Cover
Extraction Chromatography
Copyright Page
Contributors
Preface
Contents
Chapter 1. Theoretical Aspects Of Extraction Chromatography
1. General comments
2. The influence of the support on the thermodynamic activities of the extractant and extracted complex
3. Main factors influencing the distribution coefficient and selectivity
4. Dynamic factors in extraction chromatography
Chapter 2. Correlation Between Extraction Chromatography And Liquid-Liquid Extraction
1. Theoretical correlation between liquid-liquid extraction and extraction chromatography
2. General considerations on the comparison of liquid-liquid extraction and extraction chromatographic results
3. Similarities in the practice of liquid-liquid extraction and extraction chromatography in each type of extraction system
4. Concluding remarks
Chapter 3. Techniques In Column Extraction Chromatography
Introduction
1. Standardization of support material
2. Loading of the support material with stationary phase
3. Bed dimensions, column types and column packing procedures
4. Determination of column parameters
5. Working techniques in operating extraction chromatographic columns
6. Detection methods
Chapter 4. Stationary Phases In Extraction Chromatography
Introduction
1. General performances of stationary phases
2. Systematic survey of the extractants used as stationary phases
Chapter 5. Inert Supports In Column Extraction Chromatography
1. Requirements for supports in partition chromatography
2. Materials used for supports
3. The influence of the structure and size of the support particles on the efficiency of chromatographic columns
4. Properties of the different supports
5. Loading of the stationary phase on the supports. Regeneration of supports
6. Supports for preparative and continuous chromatography
Chapter 6. Extraction Chromatography Of Metallic And Non-Metallic Ions
Introduction
1. Radiochemical separations and production of carrier-free radioisotopes. The separation of mother-daughter pairs
2. The separation of alkali and alkaline earth metals
3. The separation of I B and IIB sub-group elements
4. The separation of aluminium group metals
5. The separation of IVB sub-group elements
6. The separation of chromium sub-group elements
7. The separation of iron sub-group elements
8. The separation of noble metals
9. The separation of halide ions
10. The separation of other ions
Chapter 7. Extraction Chromatography Of Actinides
1. Introduction
2. Liquid-liquid extraction of actinides
3. Extraction chromatography of actinides
4. Examples of actinide separations by extraction chromatography
Chapter 8. Extraction Chromatography Of Lanthanides
Introduction
1. Extraction of lanthanides
2. The double-double effect and its significance for the lanthanide and actinide separation
3. The enthalpies of lanthanide extraction and the influence of temperature on the separation factor
4. Survey of the lanthanide separations
5 . Resolution ability of columns used for the separation of lanthanides
Chapter 9. Extraction Chromatography Of Fission Products
1. Introduction
2. Separation systems and procedures
3. Reprocessing analysis
4. Burn-up Analysis
5. Fission products in nuclear chemistry
6. Commercial fission product recovery
Chapter 10. Use Of Extraction Chromatography In Radiotoxicology
1. General remarks
2. Analytical procedures
3. Conclusions
Chapter 11. Chelating Agents As Stationary Phase In Extraction Chromatography
1. Introduction
2. Theory of extraction by chelating agents
3. Experimental technique
4. Chelating agents and systems used
Chapter 12. Use Of Extraction Chromatography For Trace Metal Preconcentration And Separation
1. Introduction
2. Experimental techniques
3. Individual and collective preconcentration and separation of trace impurities
4. Effects of certain factors on the preconcentration and separation of elements by column extraction chromatography
5. Conclusions
Chapter 13. Use Of Cellular Plastics In Extraction Chromatography
I. Introduction
2. Cellular plastics as extraction chromatographic supports
3. The application of foam-filled columns in some inorganic and radiochemical separations
Chapter 14. Laminar Techniques As An Aid In Planning Column Extraction Chromatographic Separations
1. Introduction
2. Experimental techniques in laminar extraction chromatography
3. Correlation between Rf values and distribution coefficients
4. Correlation between Rf values and retention volumes
5. Planning column separations from laminar results
6. Literature survey of available Rf spectra
7. Conclusions
Chapter 15. Bibliography Of Extraction Chromatography
1. Introduction
2. Selection of papers
3. Bibliographies
4. Reviews and books
5. Original publications on laminar extraction chromatography
6. Original publications on column extraction chromatography
7. Tabular survey of experimental data on column extraction chromatographic investigations
8. Stationary phases used in column extraction chromatography
9. Support materials used in column extraction chromatography
10. Author index
11. Corporate author index
Subject Index

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