Presents comprehensively and clearly structured this important research field. Covering synthesis, characterization and applications this is a must-read for everyone in the field.
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Höhe: 24.4 cm
Breite: 17 cm
ISBN-13
978-3-527-34887-9 (9783527348879)
Schweitzer Klassifikation
Botao Qiao earned his Ph. D degree from Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences in 2007, and then became a postdoctoral fellow in Dalian Institute of Chemical Physics (DICP), Chinese Academy of Sciences where he has worked until present. He visited the Department of Physics, Arizona State University, USA, from 2012 to 2015. After coming back to DICP he was promoted to a full professor in 2017. His research interests are focused on the design, synthesis and characterization of highly dispersed supported metal catalysts and their applications in energy and environmental catalysis.
Ding Ma read chemistry in Sichuan University (1996), and obtained his Ph.D from the State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics (2001). After his postdoctoral stay in Oxford University and University of Bristol, he started his research career in Dalian Institute of Chemistry as associate professor (2005). He was promoted as a full professor in 2007 and moved to Peking University in 2009. His research interests are heterogeneous catalysis, especially those related with energy issues, including C1 chemistry (methane and syngas conversion), hydrogen production/transportation, new reaction route for sustainable chemistry and the development of in-situ spectroscopic method that can be operated at working reaction condition to study reaction mechanism. He is Fellow of Royal Society of Chemistry, and on the Editorial Boards of Journal of Energy Chemistry, Chinese Journal of Chemistry, Science Bulletin, Joule, ACS Catalysis, and Catalysis Science & Technology etc.
CONTENTS
Preface
Chapter 1 Introduction: A Brief History of Single-Atom Catalysis
PART I. SYNTHESIS METHODS OF SINGLE-ATOM CATALYSTS
Chapter 2 Thermally Stable Single Atom Catalysts
2.1 Introduction
2.2 Preparation Strategies and Catalyst Structures of Thermally Stable SACs
2.3 Catalytic Applications of Thermally Stable SACs
2.4 Summary and perspectives
Chapter 3 Synthesis of single-atom catalysts by wet chemical routes
3.1 Preparation by co-precipitation method
3.2 Preparation by impregnation method
3.3 Preparation by hydrothermal method
3.4 Other wet-chemical approaches
PART II. CHARACTERIZATION OF SINGLE-ATOM CATALYSTS
Chapter 4 XAFS Method
4.1 Introduction
4.2 Brief Introduction of X-ray Absorption Fine Spectroscopy
4.3 Application of EXAFS spectra
4.4 Application of XANES spectra
4.5 Emerging advanced X-ray spectroscopy methods
4.6 In-situ and operando XAFS cells
Chapter 5 FT-IR
5.1 Principles and setups
5.2 FT-IR for SA structure characterization
5.3 Monitoring structure change
5.4 Limitations and prospects
Chapter 6 Electron Microscopy Characterizations
6.1 Introduction
6.2 Scanning Transmission Electron Microscopy
6.3 Energy spectrum analysis
6.4 In situ/operando electron microscopy
6.5 Methodology for SACs Microscopy Data analysis
6.6 Challenges for Microscopy research on SACs
PART III. APPLICATION METHODS OF SINGLE-ATOM CATALYSTS
Chapter 7 Electrocatalysis of Single-Atom Catalysts
7.1 For Oxygen Reduction Reaction
7.2 For Hydrogen Evolution Reaction
7.3 For Oxygen Evolution Reaction
7.4 For CO2 Reduction Reaction
7.5 For Nitrogen Reduction Reaction
7.6 Perspectives
Chapter 8 Atomically Dispersed Metal Sites for CO2 Electroreduction
8.1 Introduction
8.2 Emerging SACs and DACs with different ECR product selectivity
8.3 Conclusion and perspectives
Chapter 9 Bridging homogeneous and heterogeneous catalysis by SACs
9.1 Introduction
9.2 Carbonyl transformation catalyzed by SACs
9.3 Hydrosilylation catalyzed by SACs
9.4 Amine and alcohols Transformation catalyzed by SACs
9.5 Summary and Perspective
Chapter 10 Applications of Single-Atom Catalysts: Selective Activation of CH4 and Removal of CO and NOx
10.1 Introduction
10.2 Selective methane activation on SACs
10.3 Pollutants (CO and NOx) removal by SACs
10.4 Conclusions
Chapter 11 Single-atom Catalysts for Thermocatalysis
11.1 Introduction
11.2 Single-atom Catalysis: Analyzed by Bond Activation and Reaction Mechanisms
11.3 Dynamic Changes and in-situ Characterization of SAC in Reaction
11.4 Conclusion and Perspective
Chapter 12 Single-atom photocatalysts for artificial carbon cycle
12.1 Introduction
12.2 Potential roles of single-atoms in photocatalysis
12.3 Strategies of anchoring single-atoms on light-harvesting support
12.4 Applications of single-atom photocatalyst
12.5 Conclusion
Chapter 13 Dynamic Single Atom Catalysis
13.1 Introduction
13.2 Dynamic Behaviors of Oxide Supported Metal Catalysts: Gold Catalysis as An Example
13.3 Mechanism of Dynamic Single Atom Catalysis (DSAC)
13.4 DSAC on Other Metal Catalysis
13.5 Summary and Outlook
Chapter 14 Single-Atom Alloy Catalysts: More Than Just the Sum of Their Parts
14.1 Introduction
14.2 Methods
14.3 General Properties
14.4 Industrial Scale-up
14.5 Conclusion and Future Directions
Index
