Inorganic Reactions and Methods V12B - Formation Bonds to C, Si, Ge, Sn, Pb Pt 4

5. The Formation of Bonds to Elements of Group IVB (C, Si, Ge, Sn, Pb) (Part 4) 5.8. Formation of Bonds between Elements of Groups IVB (C, Si, Ge, Sn, Pb) and Transition and Inner Transition Metals 5.8.1. Introduction. 5.8.2. Formation of the Carbon Transition and Inner Transition Metal Bond. 5.8.2.1. from the Elements. 5.8.2.2. from Saturated Hydrocarbons. 5.8.2.2.1. eta1 sigma Alkyl Complexes by Direct Hydrocarbon Activation. 5.8.2.2.2. eta1 sigma Alkyl and Aryl Complexes by Cyclometallation on gamma and More Remote Carbon - Hydrogen Bonds. 5.8.2.2.3. eta1 eta Alkyl Complexes by Cyclometallation of Donor Ligands. 5.8.2.2.4. Metallacycles by Oxidative Addition of Strained Carbocyclic Rings. 5.8.2.2.5. eta2 PI Olefin Complexes by s Hydride Elimination. 5.8.2.2.6. Alkylidene Complexes by alpha Hydride Elimination. 5.8.2.3. from Monoolefins 5.8.2.3.1. eta2 PI Olefin Complexes by Reaction of Metal Complexes with Monoolefins by Ligand Displacement. 5.8.2.3.2. eta2 PI Olefin Complexes by Reaction of Metal Vapors with Monoolefins. 5.8.2.3.3. eta1 sigma Alkyl Complexes by Addition of Metal Hydrides to Monoolefins. 5.8.2.3.4. eta1 sigma Alkyl Complexes from Nucleophilic Attack on PI Olefin Metal Complexes. 5.8.2.3.5. eta1 sigma Alkyl Complexes by Insertion of Monoolefins into sigma Alkyl - , sigma Aryl - , sigma Vinyl - , and sigma Acyl - Metal Bonds. 5.8.2.3.6. Metallacycles from Insertion of Monoolefins into Metal - Carbene Complexes. 5.8.2.3.7. Metallacycles by Cyclodimerization of Monoolefins. 5.8.2.3.8. PI Allyl Complexes from Allylic C - H Bond Cleavage in Olefins by Metal Complexes. 5.8.2.3.9. Metallacyclobutanes from Nucleophilic Attack on PI Allyl - Metal Complexes. 5.8.2.3.10. PI Olefin Complexes from Nucleophilic Attack on PI Ally - Metal Complexes. 5.8.2.3.11. Metal - Carbene Complexes from Olefin Metathesis Reactions. 5.8.2.4. from Conjugated Dienes 5.8.2.4.1. Conjugated Diene Complexes by Reaction with Metal Complexes by Ligand Displacement. 5.8.2.4.2. Diene Complexes by Nucleophilic Attack on Metal Cationic Complexes. 5.8.2.4.3. Cationic Dienyl Complexes from Metal Diene Complexes. 5.8.2.4.4. PI Allyl Complexes by Nucleophilic Attack. 5.8.2.4.5. PI Allyl Metal Complexes by Oligomerization of Conjugated Dienes. 5.8.2.4.6. PI Allyl Metal Complexes by Metal Atom and Related Reactions. 5.8.2.5. from Chelating Dienes 5.8.2.5.1. Chelating Diene Complexes by Direct Reaction with Metal Complexes via Ligand Displacement. 5.8.2.5.2. eta1 sigma Alkyl Complexes by Nucleophilic Attack on Metal Chelating Diene Complexes. 5.8.2.5.3. by Metal Atom and Related Reactions. 5.8.2.6. from Arenes 5.8.2.6.1. Formation of (eta6 Arene) Metal Complexes by Ligand Displacement 5.8.2.6.2. Formation of eta5 Cyclohexdienyl Complexes by Nucleophilic Attack on (eta6 Arene) Metal Complexes. 5.8.2.6.3. Formation of eta5 Cyclohexadienide Complexes via Electrophilic Addition to Metal Arene Complexes. 5.8.2.6.4. eta1 sigma Aryl - Metal Complexes by Orthometallation Reactions. 5.8.2.6.5. eta1 sigma Aryl - Metal Complexes by Oxidative Addition of Arenes. 5.8.2.6.6. eta1 sigma Aryl - Metal Complexes by Electrophilic Attack on Arenes. 5.8.2.6.7. by Metal Atom and Related Reactions. 5.8.2.7. from Alkynes 5.8.2.7.1. eta2 PI Alkyne Complexes from Reaction of Metal Complexes with Alkynes by Ligand Displacement 5.8.2.7.2. eta1 sigma Vinyl - Metal Complexes by Addition of HX to eta2 PI Alkyne Complexes. 5.8.2.7.3. eta1 sigma Vinyl Complexes by Addition of Alkynes to Metal Hydrides. 5.8.2.7.4. Metallacyclopentadiene and Metallacyclopentene Complexes by Cyclodimerization of Alkynes with Alkynes or Alkenes. 5.8.2.7.5. eta6 PI Arene Complexes by Cyclooligomerization of Alkynes. 5.8.2.7.6. eta1 sigma Alkenyl Complexes by Nucleophilic Attack on PI Alkyne - and Allene - Metal Complexes. 5.8.2.7.7. by Metal Atom and Related Reactions. List of Abbreviations Author Index Compound Index Subject Index