Inorganic Reactions and Methods V11 - Formation of Bonds to C, Si, Ge, Sn, Pb Pt 3

How to Use this Book Preface to the Series Editorial Consultants to the Series Contributors to Volume 11 5. The Formation of Bonds to Elements of Group IVB (C, Si, Ge, Sn, Pb) (Part 3) 5.5. Formation of Bonds between Elements of Groups IVB (C, Si, Ge, Sn, Pb) and IA (Li, Na, K, Rb, Cs, Fr) 5.5.1. Introduction 5.5.2 Carbon Lithium Bonds 5.5.2.1 from the Elements. 5.5.2.2. from Lithium and its Alloys 5.5.2.2.1. with Organic Halides. 5.5.2.2.2. with Organomercurials. 5.5.2.2.3. with Adducts of Conjugated Hydrocarbons in Donor Solvents. 5.5.2.2.4. with Acidic Hydrocarbons Evolving H2. 5.5.2.2.5 with Ethers, Amines, Sulfides and Phosphines Cleaving the Carbon Element Bonds. 5.5.2.3. from Other Organolithiums 5.5.2.3.1. by Metal Metal Exchange with Less Active Organometallics. 5.5.2.3.2. by Proton Metal Exchange with Acidic C - H Bonds. 5.5.2.3.3. by Halogen Lithium Exchange with Organic Halides. 5.5.2.3.4. by Addition of Organolithiums to Olefins or Acetylenes. 5.5.2.3.5. by Action of Lithium Arene Radical Anions and Dianions. 5.5.3. Carbon Group IA Bonds 5.5.3.1. from the Elements 5.5.3.1.1. Giving Na Carbides. 5.5.3.1.2. Giving K, Rb and Cs Carbides. 5.5.3.2. from the Group IA Metals and Their Alloys 5.5.3.2.1. with Organic Halides. 5.5.3.2.2. with Ethers. 5.5.3.2.3. with Organomercurials. 5.5.3.2.4. with Adducts of Conjugated Hydrocarbons in Donor Solvents. 5.5.3.2.5. with Acidic Hydrocarbons Evolving H2. 5.5.3.2.6. by Cleavage of Carbon Carbon Bonds. 5.5.3.3. from Other Group IA Organometallics of the Same Metal 5.5.3.3.1. by Proton Metal Exchange with Acidic C - H Bonds. 5.5.3.3.2. by Metal Metal Exchange with Less Active Organometallics. 5.5.3.3.3. by Addition to Olefins and Acetylenes. 5.5.4. Silicon Group IA Bonds 5.5.4.1. from the Elements. 5.5.4.2. from Organodi and Organopolysilanes 5.5.4.2.1. with Alkali Metals. 5.5.4.2.2. with Anionic Reagents. 5.5.4.3. from Organohalosilanes with Alkali Metals. 5.5.4.4. from Organosilicon Hydrides with Alkali Metals and Metal Hydrides. 5.5.4.5. from Tetraorganosilanes with Alkali Metals. 5.5.4.6. from Silylmercurials. 5.5.4.7. from Exchange. 5.5.5. Germanium Group IA Bonds 5.5.5.1. from the Elements. 5.5.5.2. from Organodigermanes 5.5.5.2.1. with Alkali Metals. 5.5.5.2.2. with Alkali Metal Alkoxides and Organolithiums. 5.5.5.3. from Organohalogermanes with Alkali Metals. 5.5.5.4. from Organogermanium Hydrides with Alkali Metals and Derivatives. 5.5.5.5. from Tetraorganogermanes with Alkali Metals. 5.5.5.6. from Germy Mercury and Thallium with Alkali Metals. 5.5.5.7. from Exchange and/or Ge(II) Derivatives. 5.5.6. Tin Group IA Bonds 5.5.6.1. from the Elements 5.5.6.1.1. Lithium. 5.5.6.1.2. Sodium. 5.5.6.1.3. Potassium. 5.5.6.1.4. Rubidium. 5.5.6.1.5. Cesium. 5.5.6.2. from Organodistannanes with Alkali Metals 5.5.6.2.1. Lithium. 5.5.6.2.2. Sodium. 5.5.6.2.3. Potassium. 5.5.6.3. from Organotin Halides with Alkali Metals 5.5.6.3.1. Lithium. 5.5.6.3.2. Sodium. 5.5.6.3.3. Potassium. 5.5.6.4. from Organotin Hydrides with Alkali Metals. 5.5.6.5. from Tetraorganotins with Alkali Metals. 5.5.6.6. from Tin(II) Compounds with Organoalkali Reagents. 5.5.7. Lead Group IA Bonds 5.5.7.1. in Alloys and Intermetallics 5.5.7.1.1. from the Elements. 5.5.7.1.2. by Reduction. 5.5.7.1.3. by Electrolysis. 5.5.7.2. from Hexaorganodiplumbanes. 5.5.7.2.1. with Alkali Metals. 5.5.7.2.2. with Organoalkali Reagents. 5.5.7.3. from Tetraorganoleads with Alkali Metals. 5.5.7.4. from Organolead Halides with Alkali Metals. 5.5.7.5. from Lead(II) Compounds with Organoalkali Reagents. 5.5.7.6. by Miscellaneous Routes. 5.6. Formation of Bonds between Elements of Group IVB (C, Si, Ge, Sn, Pb) and Group IIB (Cu, Ag, Au) 5.6.1. Introduction 5.6.2. from the Elements. 5.6.3. from the Group IB Metals and Alloys. 5.6.4. from the Metal Salts 5.6.4.1. by Metal Metal Exchange with Another Organometallic. 5.6.4.2. by Metal Halogen Exchange. 5.6.4.3. by Metallation. 5.6.4.4. by Insertion. 5.6.4.5. by Addition, Decarboxylation. 5.6.4.6. by Forming Adducts with Unsaturated Hydrocarbons. 5.6.5. From the Metal Phosphine Complexes 5.6.5.1. with Triaryl Group IV Alkali Metal Derivatives. 5.6.5.2. by Insertion. 5.6.5.3. by Transmetallation. 5.6.5.4. by Metal Halide Exchange. 5.7 Formation of Bonds between Elements of Group IVB (C, Si, Ge, Sn, Pb) and Group lib (Zn, Cd, Hg) 5.7.1. Introduction 5.7.2. Carbon Group IIB Bonds 5.7.2.1. from the Elements. 5.7.2.2. from the Group IIB Metals and Alloys 5.7.2.2.1. with Organic Halides and Sulfates. 5.7.2.2.2. with Organomercurials. 5.7.2.2.3. with Aryldiazonium Salts. 5.7.2.3. from Metal Salts 5.7.2.3.1. with Organometallics. 5.7.2.3.2. by Redistribution with the Organometallics of the Same Metal. 5.7.2.3.3. by Addition to Olefins and Acetylenes or Cyclopropanes by Ring Opening. 5.7.2.3.4. with Acidic Hydrocarbons. 5.7.2.3.5. with Diazoalkanes. 5.7.2.3.6. with Diazonium Salts. 5.7.2.3.7. with Organosulfinic, Organosulfonic and Organoboronic Acid Derivatives. 5.7.2.4. from Other Group IIB Organometallics of the Same Metal 5.7.2.4.1. by Proton Metal Exchange with Acidic Hydrocarbons. 5.7.2.4.2. by Olefin Insertion. 5.7.2.4.3. by Metal Metal Exchange with Other Organometallics. 5.7.3. Silicon Group IIB Bonds 5.7.3.1. from Silyl Alkali Metal Reagents with Group IIB Halides and Organohalides. 5.7.3.2. from Organohalosilanes with Na or Al Amalgam. 5.7.3.3. from Organosilicon Hydrides with Zn, Cd and Hg Dialkyls. 5.7.3.4. from Silylcadmiums and Thalliums with Hg Metal. 5.7.3.5. from Redistribution and Related Reactions. 5.7.4. Ge Group IIB Bonds 5.7.4.1. from Germyl Alkali Metal Reagents with Group IIB Halides and Organohalides. 5.7.4.2. from Organogermanium Hydrides with Zn, Cd and Hg Dialkyls. 5.7.4.3. from Organohalogermanes with Na Amalgam. 5.7.4.4. from Germylcadmiums, thalliums and bismuths with Hg. 5.7.4.5. from Digermanes with Hg(II) Compounds. 5.7.4.6. from Germyl Group IIB Compounds by Redistribution. 5.7.4.7. from Silyl or Germylmercurials and Ge(IV) Halides. 5.7.4.8. by Insertion of Germylenes into Hg - C or Hg - Ge Bonds. 5.7.5. Tin Group IIB Bonds 5.7.5.1. from the Elements 5.7.5.1.1. with Zn. 5.7.5.1.2. with Cd. 5.7.5.1.3. with Hg. 5.7.5.2. from Organotin Hydrides with Zn, Cd and Hg Dialkyls 5.7.5.2.2. with CD Alkyls. 5.7.5.2.3. with Hg Alkyls. 5.7.5.3. from Organotin Halides with Germylmercurials. 5.7.5.4. from Organotin Alkoxides with Silylmercurials. 5.7.6. Lead Group IIB Bonds 5.7.6.1. in Alloys and Intermetallics 5.7.6.1.1. from the Elements. 5.7.6.1.2. by Reduction. 5.7.6.1.3. by Electrolysis. 5.7.6.2. in Organolead Group IIB Compounds.