
Cumulenes in Click Reactions
Henri Ulrich(Author)
Wiley (Publisher)
Published on 10. November 2009
Software
Other digital
562 pages
978-0-470-74795-7 (ISBN)
Description
Cumulenes are organic molecules with two or more cumulative (consecutive) double bonds. Their reactions often proceed at room temperature, with or without a catalyst, and are stereospecific, giving the reaction products in high yields - features characteristic of "click reactions". Cumulenes in Click Reactions presents a comprehensive list of cumulene systems and their reactions, with an emphasis on their "click-like" nature.
The chapters are structured according to the number of carbon atoms in the system, including coverage of: * introduction to the chemistry of cumulenes* one-carbon cumulenes: sulfines, sulfenes, thiocarbonyl S-imides, thiocarbonyl S-sulfides, and 1-aza-2-azoniaallene salts* two-carbon cumulenes: carbon oxides, carbon sulfides, carbon nitrides (isocyanates, isothiocyanates, and carbodiimides), phosphaallenes, and diarsaallenes*1,2-dicarbon cumulenes: ketenes, thioketenes, ketenimines, 1-silaallenes, 1-phosphaallenes, and other metal allenes*1,3-dicarbon cumulenes: thiocarbonyl S-ylides, 2-azaallenium salts, 1-oxa-3-azoniabutatriene salts, 1-thia-3-azoniabutatriene salts, and phosphorous ylides*1,2,3-tricarbon cumulenes: allenes, butatrienes, higher cumulenes and heterobutatrienes* noncarbon cumulenes: azides, triazaallenium salts, sulfur oxides, sulfur nitrides, N-sulfinylamines, sulfurdiimides, and dithionitronium cation Cumulenes in Click Reactionsis an essential guide for researchers and advanced students in academia and research working in synthetic organic, inorganic and bioorganic chemistry.
The chapters are structured according to the number of carbon atoms in the system, including coverage of: * introduction to the chemistry of cumulenes* one-carbon cumulenes: sulfines, sulfenes, thiocarbonyl S-imides, thiocarbonyl S-sulfides, and 1-aza-2-azoniaallene salts* two-carbon cumulenes: carbon oxides, carbon sulfides, carbon nitrides (isocyanates, isothiocyanates, and carbodiimides), phosphaallenes, and diarsaallenes*1,2-dicarbon cumulenes: ketenes, thioketenes, ketenimines, 1-silaallenes, 1-phosphaallenes, and other metal allenes*1,3-dicarbon cumulenes: thiocarbonyl S-ylides, 2-azaallenium salts, 1-oxa-3-azoniabutatriene salts, 1-thia-3-azoniabutatriene salts, and phosphorous ylides*1,2,3-tricarbon cumulenes: allenes, butatrienes, higher cumulenes and heterobutatrienes* noncarbon cumulenes: azides, triazaallenium salts, sulfur oxides, sulfur nitrides, N-sulfinylamines, sulfurdiimides, and dithionitronium cation Cumulenes in Click Reactionsis an essential guide for researchers and advanced students in academia and research working in synthetic organic, inorganic and bioorganic chemistry.
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Language
English
Place of publication
Hoboken
United Kingdom
Publishing group
John Wiley and Sons Ltd
Target group
Professional and scholarly
Dimensions
Height: 251 mm
Width: 176 mm
Thickness: 35 mm
Weight
1080 gr
ISBN-13
978-0-470-74795-7 (9780470747957)
Copyright in bibliographic data and cover images is held by Nielsen Book Services Limited or by the publishers or by their respective licensors: all rights reserved.
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Content
Preface Acknowledgements 1 General Introduction References 2 1-Carbon Cumulenes 2.1 Sulfines, R2C SO 2.2 Sulfenes, R2C S(O)O 2.3 Other 1-Carbon Cumulenes 3 2-Carbon Cumulenes 3.1 Carbon Oxides, O C O, :CO 3.2 Carbon Sulfides, S C S, S CO 3.3 Carbon Nitrides 3.4 Center Carbon Phosphorallenes, P C P 4 1,2-Dicarbon Cumulenes 4.1 Ketenes, R2C C O 4.2 Thioketenes, R2C C S 4.3 Ketenimines, R2C C NR 4.4 1-Silaallenes, R2C C Si 4.5 1-Phosphaallenes, R2C C P 4.6 Other Metal Allenes 5 1,3-Dicarbon Cumulenes 5.1 Thiocarbonyl S-ylides, R2C S CH2 5.2 2-Azaallenium Salts, R(Ce)C N+ C(Ce)R 5.3 1-Oxa-3-azoniabutatriene Salts, R2C N+ C O 5.4 1-Thia-3-azabutatriene Salts, R2C N+ C S 5.5 Phosphorus Ylides 6 1,2,3-Tricarbon Cumulenes 6.1 Allenes, R2C CR2 6.2 [3] Cumulenes, R2C C C CR2 6.3 [4] Cumulenes, R2C C C C CR2 6.4 [5] Cumulenes, R2C C C C C CR2 7 Noncarbon Cumulenes 7.1 Azides, RN N N 7.2 Triazaallenium Salts, RN N+ NR 7.3 Sulfur Oxides 7.4 Sulfur Nitrides 7.5 Cationic Boron Cumulenes, R2N B NR Index