Polymer Coatings
A Guide to Chemistry, Characterization, and Selected Applications
1st Edition
Published on 3. July 2018
XXVI, 568 pages
978-3-527-80633-1 (ISBN)
Description
A practical guide to polymer coatings that covers all aspects from materials to
applications
Polymer Coatings is a practical resource that offers an overview of the fundamentals
to the synthesis, characterization, deposition methods, and recent developments of
polymer coatings. The text includes information about the different polymers and
polymer networks in use, resins for solvent- and water-based coatings, and a variety
of additives. It presents deposition methods that encompass frequently used mechanical and electrochemical approaches, in addition to the physical-chemical aspects of the coating process. The author covers the available characterization methods including spectroscopic, morphological, thermal and mechanical techniques.
The comprehensive text also reviews developments in selected technology areas
such as electrically conductive, anti-fouling, and self-replenishing coatings. The author includes insight into the present status of the research field, describes systems currently under investigation, and draws our attention to yet to be explored systems. This important text:
-Offers a thorough overview of polymer coatings and their applications
-Covers different classes of materials, deposition methods, coating processes, and
ways of characterization
-Contains a text that is designed to be accessible and helps to apply the acquired
knowledge immediately
-Includes information on selected areas of research with imminent application
potential for functional coatings
Written for chemists in industry, materials scientists, polymer chemists, and physical chemists, Polymer Coatings offers a text that contains the information needed to gain an understanding of the charaterization and applications of polymer coatings.
applications
Polymer Coatings is a practical resource that offers an overview of the fundamentals
to the synthesis, characterization, deposition methods, and recent developments of
polymer coatings. The text includes information about the different polymers and
polymer networks in use, resins for solvent- and water-based coatings, and a variety
of additives. It presents deposition methods that encompass frequently used mechanical and electrochemical approaches, in addition to the physical-chemical aspects of the coating process. The author covers the available characterization methods including spectroscopic, morphological, thermal and mechanical techniques.
The comprehensive text also reviews developments in selected technology areas
such as electrically conductive, anti-fouling, and self-replenishing coatings. The author includes insight into the present status of the research field, describes systems currently under investigation, and draws our attention to yet to be explored systems. This important text:
-Offers a thorough overview of polymer coatings and their applications
-Covers different classes of materials, deposition methods, coating processes, and
ways of characterization
-Contains a text that is designed to be accessible and helps to apply the acquired
knowledge immediately
-Includes information on selected areas of research with imminent application
potential for functional coatings
Written for chemists in industry, materials scientists, polymer chemists, and physical chemists, Polymer Coatings offers a text that contains the information needed to gain an understanding of the charaterization and applications of polymer coatings.
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Gijsbertus de With
Polymer Coatings
A Guide to Chemistry, Characterization, and Selected Applications
Book
09/2018
1st Edition
Wiley-VCH
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Polymer Coatings - A Guide to Chemistry, Characterization, and Selected Applications
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07/2018
Wiley-VCH
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Person
Gijsbertus de With has been full professor in materials science at Eindhoven University of Technology (TU/e) since 1995. After graduating from Utrecht University and receiving his PhD in 1977 from Twente University, he joined Philips Research Laboratories, Eindhoven. In 1985 he was appointed part-time professor and in 1995 he became full professor at TU/e. His research interests include structure and interfacial phenomena related to the chemical and thermomechanical behavior of multi-phase materials. He has (co)-authored more than 350 research papers and holds about 15 patents. Throughout he has cooperated with other researchers, both from academia and industry and co-organized the Coatings Science International conferences from 2004 to 2014. In 2006 his two-volume monograph Structure, Deformation, and Integrity of Materials was published, followed by Liquid-state Physical Chemistry in 2013.
Content
INTRODUCTION
Classes of Materials
Why Coatings and What Are Their Benefits
Various Applications: Electrical, Decorative/Protective, Wetting Behavior
Generic Problems: Independent of Application: Adhesion, Water/Environmental Resistance
Specific Problems: Dependent on Application: Gloss, Transparency
General Considerations: Multiple Property Relevance, Durability
Outline of Chapters and Selective Topics
POLYMERS AND POLYMER NETWORKS
Characteristics of Polymers
Ideal and Non-Ideal Networks
Kinetics of Network Formation
CLASSIC THERMOSET CHEMISTRIES
Petro-Based Thermoset Chemistries
Bio-Based Thermoset Chemistries
New Bio-Based Raw Materials for Renewable Thermosets
ALTERNATIVE CHEMISTRIES
Solvent-Borne and Water-Borne Coatings
Chemistry of (Hyper)Branched Resins and "High-Solids" Coatings
Powder Coatings
Water-Borne Coatings: Specific Aspects
Radiation Curing
ADDITIVES
Why Additives
Thickeners
Surface Active Agents
Surface Modifiers
Leveling and Coalescing Agents
Catalytically Active Agents
Special Effect Agents
APPLICATION METHODS
Laboratory and Industrial Methods
Dip-Coating
Doctor-Blade Coating
Spin-Coating
Spray-Coating
Electrophoretic Coating
An Example: Automotive Coatings
PHYSICAL-CHEMICAL ASPECTS
Solubility of Monomers, Polymers and Solvents
Intermolecular Interactions and Colloidal Stabilization
Wetting and Dewetting, CA, Regimes, Hysteresis, Topography and Chemistry
Rheology
Emulsions
Adhesion
CHARACTERIZATION
Chemical: IR, Raman, XPS
Morphological: OM, SEM, TEM, AFM, Confocal Optical Microscopy
Thermal and Mechanical: DSC, Rheological Measurements, DMTA, Hardness, Adhesion Tests
Bibliography
GENERAL CONSIDERATIONS
Generic Problems
Sustainability and Durability
Weathering and Water Sensitivity of Polymer Coatings
Color
ELECTRICALLY CONDUCTIVE COATINGS
Intrinsically Conducting: Bands, Defect Level, Conduction Mechanisms
Extrinsic: Particles, Fibers, Platelets, Percolation
Characterization: 2-Point, (Guarded) 3-Point, 4-Point, Lateral, Through-the-Depth, Frequency Dependence, C-AFM
HYDROPHOBIC AND HYDROPHILIC BEHAVIOR
Hydrophobic: Chemistry, Morphology, Effect of Particles,
Hydrophilic: Chemistry, Swelling, Friction, Integrity
SELF-REPLENISHING COATINGS
Concepts, Requirements and Assessment Methods
Heterogeneous: Capsules, Once-Only, Discrete
Homogeneous: Dangling Chains, Repetitive, Homogeneous
OUTLOOK
Present Status
Systems Under Investigation
Unexplored Systems
E excess 8 infinite dilution ° standard * pure substance ╬ activated complex id ideal
f formation reaction fus fusion mix mixing m molar r reaction in general sol solution sub sublimation trs transition vap vaporization
AC alternative current AF antifouling AFAM atomic force acoustic microscopy AFM atomic force microscopy APTES aminopropyltriethoxysilane AT associative thickener ATO antimony-doped tin oxide ATR attenuated total reflection ATRP atom transfer radical...
Classes of Materials
Why Coatings and What Are Their Benefits
Various Applications: Electrical, Decorative/Protective, Wetting Behavior
Generic Problems: Independent of Application: Adhesion, Water/Environmental Resistance
Specific Problems: Dependent on Application: Gloss, Transparency
General Considerations: Multiple Property Relevance, Durability
Outline of Chapters and Selective Topics
POLYMERS AND POLYMER NETWORKS
Characteristics of Polymers
Ideal and Non-Ideal Networks
Kinetics of Network Formation
CLASSIC THERMOSET CHEMISTRIES
Petro-Based Thermoset Chemistries
Bio-Based Thermoset Chemistries
New Bio-Based Raw Materials for Renewable Thermosets
ALTERNATIVE CHEMISTRIES
Solvent-Borne and Water-Borne Coatings
Chemistry of (Hyper)Branched Resins and "High-Solids" Coatings
Powder Coatings
Water-Borne Coatings: Specific Aspects
Radiation Curing
ADDITIVES
Why Additives
Thickeners
Surface Active Agents
Surface Modifiers
Leveling and Coalescing Agents
Catalytically Active Agents
Special Effect Agents
APPLICATION METHODS
Laboratory and Industrial Methods
Dip-Coating
Doctor-Blade Coating
Spin-Coating
Spray-Coating
Electrophoretic Coating
An Example: Automotive Coatings
PHYSICAL-CHEMICAL ASPECTS
Solubility of Monomers, Polymers and Solvents
Intermolecular Interactions and Colloidal Stabilization
Wetting and Dewetting, CA, Regimes, Hysteresis, Topography and Chemistry
Rheology
Emulsions
Adhesion
CHARACTERIZATION
Chemical: IR, Raman, XPS
Morphological: OM, SEM, TEM, AFM, Confocal Optical Microscopy
Thermal and Mechanical: DSC, Rheological Measurements, DMTA, Hardness, Adhesion Tests
Bibliography
GENERAL CONSIDERATIONS
Generic Problems
Sustainability and Durability
Weathering and Water Sensitivity of Polymer Coatings
Color
ELECTRICALLY CONDUCTIVE COATINGS
Intrinsically Conducting: Bands, Defect Level, Conduction Mechanisms
Extrinsic: Particles, Fibers, Platelets, Percolation
Characterization: 2-Point, (Guarded) 3-Point, 4-Point, Lateral, Through-the-Depth, Frequency Dependence, C-AFM
HYDROPHOBIC AND HYDROPHILIC BEHAVIOR
Hydrophobic: Chemistry, Morphology, Effect of Particles,
Hydrophilic: Chemistry, Swelling, Friction, Integrity
SELF-REPLENISHING COATINGS
Concepts, Requirements and Assessment Methods
Heterogeneous: Capsules, Once-Only, Discrete
Homogeneous: Dangling Chains, Repetitive, Homogeneous
OUTLOOK
Present Status
Systems Under Investigation
Unexplored Systems
List of Most Important Symbols and Abbreviations
[X] dimension dependent on property, [-] dimensionless property, bold italic = vector
F potential energy [J] G excess [mol?m-2] ? disjoining pressure [Pa] ? electrical potential [J] aconstant [X]
thermal expansion coefficient [K-1]
polarizability [C2 m2 J-1]
branching index [-]
Dundurs parameter [-]
ßconstant [X]
1/kT [J-1]
Dundurs parameter [-]
?activity coefficient [-]
interface energy [J?m-2]
crosslinking index [-]
dsolubility parameter [MPa1/2]
Dirac delta function [-]
eenergy [J]
permittivity [C2 N-1 m-2]
strain [-]
? contact angle [°] ? (bulk) viscosity [Pa s] ?inverse Debye length [m-1]
curvature [m-1]
compressibility [m2 N-1]
?parameter [X]
wave length [m]
µ dipole moment [C m] ?frequency [s-1]
Poisson's ratio
p spreading pressure [Pa] ?number density [m-3]
mass density [kg m-3]
radius of curvature [m]
s(hard sphere) diameter [m]
surface charge density [C?m-2]
t characteristic time [s] f(pair) potential energy [J]
electrical potential [V m-1]
volume fraction [-]
? Flory parameter [-] ? electrical potential [J] ? circular frequency [s-1] E electric field [V?m-1] F force [N] e unit vector [m] f force [N] r coordinate [m] u displacement [m] v velocity [m s-1] x coordinate [m] Aarea [m2]
constant [X]
B constant [X] Cconstant [X]
characteristic ratio [-]
concentration [mol l-1]
D diffusivity [m2 s-1] D dispersity [-] Eenergy [J]
electric field [V m-1]
Young's modulus [GPa]
FHelmholtz energy [J]
force [N]
G Gibbs energy [J] Henthalpy [J]
Hamaker constant [J]
I intensity [X] J flux [s-1 m-2] K equilibrium constant [X] L length [m] M molar mass [g?mol-1] N number of particles [-] NA Avogadro's number [mol-1] Na number of particles of component a [-] P pressure [Pa] Qcharge [C]
heat [J]
Rgas constant [J K-1 mol-1]
radius of object [m]
distance between objects [m]
fracture energy [J?m-2]
Rg radius of gyration [m] Sentropy [J K-1]
spreading coefficient [J?m-2]
Tkinetic energy [J]
temperature [K]
Tg glass transition temperature U (internal) energy [J] Vpotential energy [J]
volume [m3]
W work [J] X degree of polymerization Y yield strength acapillary constant [m-1]
constant [X]
b constant [X] cconstant [X]
inverse spring constant [m N-1]
concentration [mol l-1]
e unit charge [C] f(volume) fraction [-]
specific Helmholtz energy [J kg-1]
force [N]
spring constant [N m-1]
functionality [-]
g specific Gibbs energy [J kg-1] j flux [s-1 m-2] kBoltzmann's constant [J K-1]
spring constant [N-1]
rate constant [X]
l length [m] m mass [kg] n material constant [X] na number of moles of component a [-] q charge [C] rdistance [m]
rate [X]
s specific entropy [J K-1 kg-1] t time [s] u (pair) potential energy [J] v volume [m3] wregular solution parameter [J]
potential [J]
xi mole fraction of component i [X] x coordinate [X] y coordinate [X] z coordinate [X] zi valency of particle i [-] = identical to ? approximately equal to ~ very approximately equal to ~ proportional to ? corresponds with ?(x) order of magnitude xSuperscripts
E excess 8 infinite dilution ° standard * pure substance ╬ activated complex id ideal
Subscripts
f formation reaction fus fusion mix mixing m molar r reaction in general sol solution sub sublimation trs transition vap vaporization
Abbreviations
AC alternative current AF antifouling AFAM atomic force acoustic microscopy AFM atomic force microscopy APTES aminopropyltriethoxysilane AT associative thickener ATO antimony-doped tin oxide ATR attenuated total reflection ATRP atom transfer radical...
