
Nuclear Magnetic Resonance
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Content
- Nuclear Magnetic Resonance
- Contents
- Chapter 1 Theoretical and Physical Aspects of Nuclear Shielding
- 1 Theoretical Aspects of Nuclear Shielding
- A Ab Initio Calculations
- B Semi-empirical Calculations
- 2 Physical Aspects of Nuclear Shielding
- A Anisotropy of the Shielding Tensor
- B Isotope Effects on Nuclear Shielding
- C Intermolecular Effects on Nuclear Shielding
- Chapter 2 Applications of Nuclear Shielding
- 1 Introduction
- A Shielding Scales
- B Computer Assisted Structural Assignment
- C Diastereotopic Nuclear Shielding Non-equivalence
- D Isotope Effects on Nuclear Shielding
- 2 Transmission of Effects within Molecules
- A Introduction
- B Chemical Shift Calculations
- C Substituent Effects in General, including Inductive and Resonance Effects
- D Van der Waals, Electric Field, and Bond Anisotropy Effects
- E Ring Current Effects
- F Hydrogen Bonding
- 3 Shieldings of Particular Nuclei
- A Introduction
- B Hydrogen Shieldings
- C Lithium Shieldings
- D Beryllium Shieldings
- E Boron Shieldings
- F Carbon Shieldings
- G Nitrogen Shieldings
- H Oxygen Shieldings
- I Fluorine Shieldings
- J Phosphorus Shieldings
- K Other Nuclei
- Group IA
- Group IB
- Group IIA
- Group IIB
- Group IIIA
- Group IIIB
- Group IVA
- Group IVB
- Group VA
- Group VB
- Group VIA
- Group VIB
- Group VIIA
- Group VIIB
- Group VIII
- Xenon
- Chapter 3 Theoretical Aspects of Spin-Spin Couplings
- 1 Introduction
- 2 Theory and Computational Methods
- 3 Calculations of Couplings in Model Compounds
- 4 Empirical Correlations
- A Proton-Proton Couplings
- B Proton-Other Nucleus Couplings
- C Couplings involving Group IV Elements
- D Other Couplings
- 5 Intermolecular Effects
- Chapter 4 Applications of Spin-Spin Couplings
- 1 Introduction
- 2 Coupling of Directly Bonded Nuclei, 1J
- A Coupling to Hydrogen
- (i) Boron
- (ii) Carbon
- (iii) Nitrogen and Phosphorus
- (iv) Metals
- B Coupling to Boron
- C Coupling to Elements of Group TV
- (i) Elements of Group IV
- (ii) Nitrogen
- (iii) Phosphorus
- (iv) Selenium and Tellurium
- (v) Fluorine
- (vi) Metals
- D Coupling to Nitrogen and Phosphorus
- (i) Nitrogen and Phosphorus
- (ii) Selenium and Tellurium
- (iii) Fluorine
- (iv) Metals
- E Miscellaneous Couplings
- 3 Coupling over Two Bonds, 2J
- A Geminal Proton Coupling
- B Coupling of Protons to other Nuclei
- (i) Elements of Group IV
- (ii) Nitrogen and Phosphorus
- (iii) Selenium and Tellurium
- (iv) Metals
- C Coupling to Boron
- D Coupling to Elements of Group IV
- (i) Elements of Group IV
- Nitrogen, Phosphorus, and Selenium
- (iii) Metals and Fluorine
- E Coupling to Nitrogen and Phosphorus
- (i) Nitrogen and Phosphorus
- (ii) Tellurium and Fluorine
- (iii) Metals
- F Miscellaneous Couplings
- 4 Coupling over Three Bonds, 3J
- A Coupling between Protons
- B Coupling of Protons to other Elements
- (i) Elements of Group IV
- (ii) Nitrogen and Phosphorus
- (iii) Selenium, Tellurium, Fluorine, and Metals
- C Coupling to Elements of Group IV
- (i) Carbon and Tin
- (ii) Phosphorus
- (iii) Selenium, Fluorine and Metals
- D Coupling to Nitrogen and Phosphorus
- (i) Nitrogen and Phosphorus
- (ii) Fluorine and Metals
- E Other Couplings
- 5 Long-range Couplings
- A Proton-Proton Couplings
- B Coupling of Protons to other Nuclei
- C Other Long-range Couplings
- Chapter 5 Nuclear Spin Relaxation in Liquids and Gases
- 1 Introduction
- 2 Theoretical and Physical Aspects of Nuclear Spin Relaxation
- A Molecular Reorientation
- B Internal Motions
- C Relaxation by Intermolecular DD Interaction
- D Relaxation in Presence of Paramagnetic Ions
- E Chemical Exchange
- 3 Relaxation of Less-common Nuclei
- A Relaxation by QF Interaction
- B Relaxation by SC Interaction of the Second Kind
- C Relaxation by CSA Interaction
- D Relaxation of Particular Nuclei
- (i) Group IA
- (ii) Group III A
- (iii) Group IVA
- (iv) Group VA
- (v) Group VIA
- (vi) Group VIIA
- (vii) Group VIIIA
- (viii) First Row Transition Metals
- 4 Applications of Nuclear Spin Relaxation
- A Rotational Motions in Pure Liquids and Liquid Mixtures of Non-electrolytes
- B Molecular Association Studies
- C Electrolyte Solutions
- D Transition Metal Complexes
- E Ionic Complexes with Ionophores
- F Miscellaneous Applications
- 5 Nuclear Spin Relaxation in Gases
- 6 Self Diffusion Measurements by the Spin-Echo Technique
- Chapter 6 Solid State N.M.R.
- 1 Introduction
- 2 High Resolution N.M.R. of Solids
- A Techniques
- B General Applications
- C Macromolecules
- D Amino Acids, Polypeptides, and Polysaccharides
- E Biological Samples
- F Fossil Fuels, Wood, Soil and Soil Related Materials
- G Silicates, Aluminosilicates and Aluminium-containing Compounds
- 3 Polymeric Systems
- 4 Solidified Gases and Liquids
- 5 Hydrogen and Hydrides
- 6 Hydrates
- 7 Organic Solids
- 8 Inorganic Solids
- 9 Clathrates and Intercalation Compounds
- 10 Tunnelling
- 11 Doped Systems
- 12 Glasses
- 13 Electric and Magnetic Properties
- Chapter 7 Multiple Resonance
- 1 Introduction
- 2 Theory of Multiple Resonance
- 3 Experimental Methods
- 4 Special Pulse Sequences
- 5 Two-Dimensional N.M.R.
- 6 Miscellaneous Uses of Multiple Resonance
- A The Nuclear Overhauser Effect
- B Various Experiments
- Chapter 8 Natural Macromolecules
- 1 Introduction
- 2 Amino-acids, Linear and Cyclic Peptides
- 3 Polypeptides and Proteins
- A Methods
- B Function
- 4 Oligo- and Poly-nucleotides
- 5 Oligo- and Poly-saccharides
- Chapter 9 Synthetic Macromolecules
- 1 Introduction
- 2 Books, Reviews, and Conference Papers
- 3 Structural Studies of Polymers in Solution
- A Tacticity of Homopolymers
- B Geometrical Isomerism
- C End Groups, Kinetics and Mechanism
- D Chain Branching
- E Copolymers
- F Polycondensates and Resins
- G Chemical Modification and Degradation
- 4 Conformational and Relaxation Studies of Polymers in Solution
- A Conformation
- B Relaxation
- 5 Bulk Polymers
- A High Resolution Structural Studies
- B Dynamic Studies
- C Broadline Studies
- D Melts
- Chapter 10 Nuclear Magnetic Resonance of Living Systems
- 1 Introduction
- 2 N.M.R. Imaging
- A Basic Principles and Safety Aspects
- B New Techniques and Instrumentation
- C Other Nuclei and Chemical Shift Imaging
- D Contrast Agents for N.M.R. Imaging
- E Medical Applications of N.M.R. Imaging
- 3 High Resolution N.M.R.
- A Introduction and Methods
- B Cells
- C Tissue Studies
- Brain
- Epithelial Tissues
- Eye
- Heart
- Kidney and Adrenal Glands
- Liver
- Muscle (skeletal)
- Muscle (smooth)
- Tumours
- D Clinical Applications of High Resolution N.M.R.
- E Plants
- F Water
- Chapter 11 N.M.R. of Paramagnetic Species
- 1 Introduction
- 2 Theoretical Developments
- 3 Radicals and Radical Ions
- A Free Radicals
- B Radical Ions
- 4 Transition-metal Complexes
- A Isotopic Shifts
- B Dynamics
- C Relaxation
- 5 Lanthanide Complexes
- A Methodology of Shift Reagents
- B Dynamic and Conformational Studies
- C Solution Structures of Lanthanide Complexes and their Adducts
- 6 Actinide Complexes
- 7 Ion Pairing and Outer-sphere Effects
- 8 Miscellaneous
- Chapter 12 N.M.R. of Liquid Crystals and Micellar Solutions
- 1 Introduction
- 2 Reviews
- 3 Theory
- 4 Thermotropic Liquid Crystals
- A Relaxation Studies
- B Bandshape Methods
- C Other Studies
- 5 Micelles, Microemulsions, and Emulsions: Non-aqueous Lipid Systems
- A Simple Micelles
- B Solubilization and Mixed Micelles
- C Reversed Micelles and Microemulsions: Non-aqueous Lipid Systems: Emulsions
- 6 Lyotropic Liquid Crystals
- A Phase Diagrams and Phase Structures
- B Alkyl Chains and Headgroups in Single Phases
- C Alkyl Chains and Headgroups in Dispersions/Liposomes
- D Alkyl Chains and Headgroups in Vesicles
- E Alkyl Chains and Headgroups in Natural Systems
- F Water and Ions
- G Non-aqeous Systems
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