Modern Liquid Chromatography of Macromolecules
Published on 14. May 2014
455 pages
978-0-08-085828-9 (ISBN)
Description
Modern Liquid Chromatography of Macromolecules
More details
Series
Language
English
Place of publication
Burlington
Netherlands
Product notice
Windows
ISBN-13
978-0-08-085828-9 (9780080858289)
Copyright in bibliographic data and cover images is held by Nielsen Book Services Limited or by the publishers or by their respective licensors: all rights reserved.
Schweitzer Classification
Other editions
Additional editions
B.G. Belenkii | L.Z. Vilenchik
Modern Liquid Chromatography of Macromolecules: Volume 25
Book
04/2000
Elsevier
€235.61
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Content
- Front Cover
- Modern Liquid Chromatography of Macromolecules
- Copyright Page
- Contents
- Journal of Chromatography Library
- Foreword
- Preface
- Chapter 1. General theory of chromatography
- 1.1. Characterization of the chromatographic method
- 1.2. Methods of the description of the chromatographic process for some specific chromatographic systems
- 1.3. Kinetics of the chromatographic process
- 1.4. Method of statistical moments in chromatography
- 1.5. Analysis of chromatographic spreading
- 1.6. Optimization of the chromatographic process
- References
- Chapter 2. Main features of the chromatography of macromolecules
- 2.1. Change in the free energy of the macromolecules during interphase transitions as the main characteristic of the behaviour of the substance in the chromatographic process
- 2.2. Essential features of the change in the free energy of macromolecules during interphase transitions. Two main variations of the chromatography of polymers
- 2.3. Gel-permeation chromatography of polymers (GPC) on rigid sorbents
- 2.4. Main relationships of adsorption chromatography of polymers on rigid macroporous sorbents
- 2.5. Main features of the chromatography of flexible-chain polymers on swelling macroporous sorbents
- References
- Chapter 3. Interpretation of data on the analysis of polymers by gel chromatography
- 3.1. Aims of interpretation
- 3.2. Levels of interpretation
- 3.3. Calibration dependences in GPC
- 3.4. Calibration of the chromatograph
- 3.5. Determination of calibration dependence in the absence of polymer standards
- 3.6. Determination of constants K. and a in the Mark-Kuhn-Houwink equation from experimental GPC data
- 3.7. Determination of molecular-weight characteristics of polymers without correcting chromatographic data for 'instrumental spreading' (first level of interpretation)
- 3.8. Determination of molecular weight characteristics of polymers in which 'instrumental spreading' described by a Gaussian function is taken into account (second level of interpretation)
- 3.9. Determination of molecular-weight characteristics of polymers in which the asymmetry of the chromatograms of homopolymers is taken into account (third level of interpretation)
- 3.10. Use of asymmetrical functions for the description of 'instrumental spreading' (fourth level of interpretation)ss
- 3.11 . Error in the determination of molecular weights by the GPC method
- References
- Chapter 4. Methodological problems of gel-permeation chromatography (GPC)
- 4.1. Sorbents used in the GPC of polymers
- 4.2. Preparation of chromatographic columns
- 4.3. Narrow-disperse polymer standards for column calibration in the GPC of polymers
- 4.4. Solvents for the GPC of polymers
- 4.5. Detectors
- 4.6. Equipment for liquid chromatography
- 4.7. Procedures of the GPC of polymers
- 4.8. Preparative GPC
- 4.9. Use of recycling for increasing the efficiency of the chromatographic system
- 4.10. Vacancy GPC
- 4.11. High-speed GPC
- 4.12. Microcolumn GPC
- References
- Chapter 5. Use of gel-permeation chromatography for the analysis of macro- molecules investigation of their interaction and the characterization of the porous structure of sorbentsss
- 5.1. Gel-permeation chromatography of oligomers
- 5.2. Gel-permeation chromatography of polyelectrolytes
- 5.3. Analysis of branched-chain polymers by a combination of GPC and viscometry
- 5.4. Determination of the MWD of branched polymers by a combination of GPC and sedimentation
- 5.5. Combination of GPC with independent methods for obtaining average mole- cular characteristics
- s5.6. Determination of the MWD of random copolymers by combining GPC, viscometry, osmometry, light scattering and pyrolysis gas chromatography
- 5.7. Determination of the composition and the MWD of block copolymers
- 5.8. Combined chromatographic methods for the analysis of complex polymer systems by gel-permeation, thin-layer and pyrolysis gas chromatography
- 5.9. Use of GPC for investigation of isomerization, association and complexation of proteins and determination of their molecular weight
- 5.10. Chromatographic porosimetry
- References
- Chapter 6. High-performance gel-filtration chromatography (HPGFC)
- 6.1. Sorbents for HPGFC
- 6.2. Applications of HPGFC
- References
- Chapter 7. Thin-layer chromatography of polymers
- 7.1. Development of thin-layer chromatography of polymers and its variations
- 7.2. Adsorption TLC of polymers
- 7.3. Precipitation and extraction TLC of polymers
- 7.4. Dependence of spot shape on concentration in the TLC of polymers
- 7.5. Investigations of the microstructure of polymers by TLC
- 7.6. TLC of block and graft copolymers
- 7.7. TLC of oligomers
- 7.8. Some methodological problems of the TLC of polymers
- References
- Chapter 8. One-phase chromatography: field-flow fractionation and hydrodynamic chromatography
- 8.1. Theoretical basis of FFF
- 8.2. Types of FFF
- 8.3. Separation efficiency and speed in FFF
- 8.4. FFF programming
- 8.5. Comparison of FFF with exclusion chromatography and other chromatographic methods of fractionation of macromolecules and microparticles
- 8.6. Polymer fractionation by FFF
- 8.7. Future prospects of using various types of FFF
- 8.8. Hydrodynamic chromatography
- References
- Subject Index
- Atomic Absorption Spectrometry
- Announcing a new journal
