Cycloaddition Reactions of Heterocumulenes
Published on 2. December 2012
374 pages
978-0-323-16276-0 (ISBN)
Description
Cycloaddition Reactions of Heterocumulenes reviews cycloaddition reactions, particularly on hetercocumulenes having "four-electron" bonds. This book discusses the chemical relationship among the various classes of heterocumulenes, including their chemical reactivity which ranges from highly reactive species to nearly inert compounds. This text also investigates the nucleophilic reactions of ketenes and isocyanates with suitable substrates, and if possible, correlates available data with the reactivity of these species in cycloaddition reactions. This book also investigates the cycloaddition reactions of carbon suboxide and other aspects of its chemistry due to the presence of many other interrelated reactions. The synthetic organic chemist should also investigate the application of isocyanate reactions associated with the cumulative double bonds. This text investigates carbodiimides as useful reagents for peptide synthesis, and notes that the stability of carbodiimides increases significantly with sterical hindrance around the cumulative double bond system. This book discusses three compounds that have a central electrophilic carbon atom, namely, carbon dioxide, carbonyl sulfide, and carbon disulfide. The book also describes the cycloaddition reactions of sulfenes, of N-sulfinylamines, of N-sulfinylsulfonamides, and of sulfurdiimides. This book can prove useful for researchers, technicians, and scientists whose works involve organic chemistry, analytical chemistry, and other related fields of chemistry.
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Content
PrefaceChapter I. General Introduction I. Scope II. Reactivity III. Cycloaddition Reactions IV. Physiochemical Data ReferencesChapter II. Ketenes I. Introduction II. Homopolymerization III. 1,2-Cycloaddition Reactions IV. 1,3-Cycloaddition Reactions V. 1,4-Cycloaddition Reactions ReferencesChapter III. Carbon Suboxide I. Introduction II. Cycloaddition Reactions III. Nucleophilic Reactions IV. Photochemical Reactions ReferencesChapter IV. Isocyanates I. Introduction II. Homopolymerization III. 1,2-Cycloaddition Reactions IV. 1,3-Cycloaddition Reactions V. 1.4-Cycloaddition Reactions ReferencesChapter V. Isothiocyanates I. Introduction II. 1,2-Cycloaddition Reactions III. 1,3-Cycloaddition Reactions IV. 1,4-Cycloaddition Reactions ReferencesChapter VI. Carbodiimides I. Introduction II. Homopolymerization III. 1,2-Cycloaddition Reactions IV. 1,3-Cycloaddition Reactions V. 1,4-Cycloaddition Reactions ReferencesChapter VII. Carbon Dioxide, Carbonyl Sulfide, and Carbon Disulfide I. Introduction II. 1,2-Cycloaddition Reactions III. 1,3-Cycloaddition Reactions ReferencesChapter VIII. Sulfenes I. Introduction II. 1,2-Cycloaddition Reactions III. 1,3-Cycloaddition Reactions IV. 1,4-Cycloaddition Reactions ReferencesChapter IX. N-Sulfinylamines, N-Sulfinylsulfonamides, and Sulfurdiimides I. Introduction II. 1,2-Cycloaddition Reactions III. 1.3-Cycloaddition Reactions IV. 1,4-Cycloaddition Reactions V. Sulfurdiimide Reactions ReferencesAppendix Text ReferencesAuthor IndexSubject Index
