Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes
Cuvillier Verlag eBooks
Published on 20. June 2019
138 pages
978-3-7369-6034-3 (ISBN)
Description
The phosphinoamide chemistry has attracted a considerable attention owing to the structural
diversity of the associated complexes.[16-21] To further understand the properties of the P-N bond,
Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)]2 (Figure 1.1.1) through the
deprotonation reaction of the corresponding aminophosphine with nBuLi.[22] X-ray diffraction
analyses indicated the presence of Li-P bonds (2.684(3) and 3.004(4) Å). In addition, the P-N
bond length (1.672(2) Å) was relatively smaller than that of a single bond (mean value of 1.70
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Content
- Intro
- 1. Introduction
- 2. Aim of the project
- 3. Results and discussion
- 4. Experimental section
- 5. Crystal Data
- 6. Summary
- 7. References
- 8. Appendix
