
Molecular Structure by Diffraction Methods
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Content
- Molecular Structure By Diffraction Methods
- Contents
- Part I Electron Diffraction
- Introduction to Part I
- Chapter 1 Electron Diffraction Determination of Gas-phase Molecular Structures
- 1 Introduction
- 2 Main Group Inorganic Compounds
- Groups II and III
- Group IV
- Group V
- Group VI
- 3 Transition-metal Compounds
- 4 Organic Compounds
- Hydrocarbons
- Carbon-Nitrogen Compounds
- Carbon-Oxygen and Carbon-Sulphur Compounds
- Carbon-Halogen Compounds
- Chapter 2 Recent Developments in Apparatus in America, Canada, and Japan
- 1 Introduction
- 2 Electron Optical System
- Alignment of Electron Optics
- Extraneous Scattering
- 3 The Inlet System
- 4 The Sector
- 5 Calibration
- 6 Photographic Plates
- 7 Microdensitometer
- 8 Recent Developments and Future Possibilities
- Chapter 3 Gases and Crystals: A Comparative Survey
- 1 Introduction
- 2 Molecular Association in Halides
- Halides of Main Group Elements
- Halides of Transition Elements
- Mixed and Substituted Halides
- 3 Oxides
- 4 Hydrogen Bonding and Charge Transfer
- 5 Differences in Molecular Geometry between Phases
- Conformational Differences
- Non-equivalence of Parameters
- Chapter 4 Augmented Analyses: Method of Predicate Obervations
- 1 Introduction
- 2 Method of Predicate Observations
- 3 Application to Difluorophosphate
- 4 Comparison with Other Methods
- Introduction to Parts II and III
- Part II Neutron Diffraction
- 1 Introduction
- 2 Experimental Methods
- 3 Hydrogen Bonding
- 4 Molecular Vibrations
- 5 Electron-density Distributions
- 6 PhaseTransitions
- 7 Organic and Organometallic Compounds
- 8 Inorganic Compounds
- Oxides
- Halides and Cyanides
- Heavy-atom Structures and Some Others
- Part III X-Ray Diffraction
- Chapter 1 Aromatic and Analogous Unsaturated Molecules
- 1 Benzene Derivatives
- 2 Pyridine and Related Heterocyclic Derivatives
- 3 Naphthalene, Anthracene, and Related Heterocyclic Derivatives
- 4 Non-benzenoid Aromatic and Pseudo-aromatic Systems
- Chapter 2 Molecular Complexes, Hydrogen-bonded Systems, and other Intermolecular Interactions
- 1 Charge-transfer and Related Interactions
- 2 Solid-state Reactions
- 3 Hydrogen-bonding Interactions
- Chapter 3 Non-aromatic Hydrocarbons, Heterocyclic Analogues, and Derivatives
- 1 Derivatives of the Simple Alkanes, Extended Hydrocarbons, and Ylides
- 2 Cyclopropane and Cyclobutane Derivatives, and Heterocyclic Analogues
- 3 Cyclopentyl Derivatives and Heterocyclic Analogues
- Cyclopentyl Derivatives
- Heterocyclic Analogues Containing One Heteroatom
- Heterocyclic Analogues Containing Two Heteroatoms
- Heterocyclic Analogues Containing more than Two Heteroatoms
- 4 Porphyrins and Phthalocyanines
- 5 Cyclohexane and Analogous Heterocyclic Derivatives
- 6 Polycyclic and Bridged-ring Systems
- 7 Seven-membered, Eight-membered, and Larger Ring Compounds
- Chapter 4 Natural Products and Related Compounds
- 1 Alkaloids and Amines
- 2 Amino-acids and Peptides
- 3 Nitrogen Heterocycles
- Porphyrins
- Flavins
- Thiazolidine, Thiazoline, and Thiazole Derivatives
- Pyrimidine Heterocycles
- Nucleosides and Nucleotides
- Metal Complexes of Nucleic Acid Fragments
- 4 Sugars
- 5 Terpenoids
- Monoterpenoids
- Sesquiterpenoids
- Diterpenoids
- Sesterterpenoids
- Triperpenoids
- 6 Steroids
- 7 Carboxylic Acids, Esters, Lactones, and Miscellaneous Materials
- Chapter 5 The Structure of Globular Proteins and Nucleic Acids
- 1 Introduction
- 2 Structural Principles
- 3 Proteases
- 4 Dehydrogenases
- 5 Kinases and Mutases
- 6 Haemoglobins
- 7 Redox proteins
- 8 Antibodies
- 9 Hormones
- 10 Virus Proteins
- 11 Other Proteins
- 12 Transfer RNA
- 13 Methods
- Chapter 6 Titanium, Zirconium, and Hafnium
- 1 Titanium
- Inorganic Compounds
- Organometallic Compounds
- 2 Zirconium and Hafnium
- Chapter 7 Vanadium, Niobium, and Tantalum
- 1 Vanadium
- 2 Niobium and Tantalum
- Inorganic Compounds
- Organometallic Compounds
- Chapter 8 Chromium, Molybdenum, and Tungsten
- 1 Chromium
- Inorganic Compounds
- Organometallic Compounds
- Carbonyl Complexes
- Alkyl Complexes
- p-Complexes of Carbocyclic and Heterocyclic Ligands
- 2 Molybdenum and Tungsten
- Inorganic Compounds
- Oxo-complexes
- Organometallic Compounds
- Carbonyl Complexes
- s-Phenyl, Vinylidene, Isocyanide, and Carbyne Complexes
- p-Olefin and p-Allyl Complexes
- Cyclobutadienyl, Cyclopentadienyl, and Cycloheptatrienyl Complexes
- Chapter 9 Manganese, Technetium, and Rhenium
- 1 Manganese
- Inorganic Compounds
- Organometallic Compounds
- Carbonyls
- Complexes with other One-carbon-donor Ligands and with Two-carbon-donor Ligands
- Complexes with Carbocyclic and Heterocyclic Ligands
- 2 Technetium and Rhenium
- Inorganic Compounds
- Organometallic Compounds
- Chapter 10 Iron, Ruthenium, and Osmium
- 1 Iron
- Inorganic Compounds of Iron
- Organo-iron Compounds
- Mononuclear Derivatives of Fe(CO)5
- Ferrocene Derivatives
- Dinuclear Derivatives of Fe2(CO)9
- Trinuclear Derivatives
- 2 Ruthenium and Osmium
- Inorganic Compounds
- Organo-ruthenium and Organo-osmium Compounds
- Chapter 11 Cobalt, Rhodium, and Iridium
- 1 Introduction
- 2 Cobalt
- Oxidation States Less than II
- Complexes of Cobalt(II)
- Tetrahedral Complexes
- Square-planar Complexes
- Five-co-ordinate Complexes
- Octahedral Complexes
- Other Complexes of Six- and Seven-co-ordinate Cobalt(II)
- Complexes of Cobalt(III)
- Porphyrin Complexes of Cobalt(II) and Cobalt(III)
- Organometallic Compounds of Cobalt
- Carbonyl and Isocyanide Complexes
- Alkyl and Aryl Cobalt(III) Dimethylglyoximato-complexes
- p-Complexes
- 3 Rhodium and Iridium
- Inorganic Complexes
- Four- and Five-co-ordinate Complexes
- Octahedral Complexes
- Organometallic Complexes
- Chapter 12 Nickel, Palladium, and Platinum
- 1 Introduction
- 2 Nickel
- Oxidation States Less Than II
- Complexes of Nickel(II)
- Square-planar Complexes
- Tetrahedral Complexes
- Five-co-ordinate Complexes
- Octahedral Complexes
- Complexes of Nickel(IV)
- Organometallic and Related Compounds of Nickel
- Compounds with Ni-C s-Bonds
- Complexes of Olefins and Related Molecules
- p-Allyl Compounds
- Cyclopentadienyl Compounds
- Carbaborane Compounds
- 3 Palladium and Platinum
- Platinum(o) Complexes
- Palladium(II) and Platinum(II) Complexes
- Palladium(IV) and Platinum(IV) Complexes
- Organometallic Compounds of Palladium and Platinum
- Square-planar Complexes Containing M-C s-Bonds
- Octahedral Platinum(IV) Compounds
- Other Compounds Containing M-C s-Bonds
- Olefin and Acetylene Complexes of Square-Planar Platinum (II)
- Olefin and Allene Complexes of Palladium(o)
- Miscellaneous p-Complexes
- Chapter 13 Copper, Silver, and Gold
- 1 Copper
- Complexes of Copper(I)
- Complexes of Copper(II)
- Chloro-, Hydroxo-, and Aquo-complexes
- Complexes of Simple Oxy-anions
- Other Non-chelate Complexes
- Chelate Complexes of Diamine, Triamine, and Tetra-amine Ligands
- Aminopyridine Complexes
- Complexes of other Multidentate Nitrogen Donors
- Salicylaldimine Complexes
- Complexes of Amino-acids and Related Ligands
- Complexes of Other N + O Chelating Ligands
- Acetylacetonate Complexes
- Complexes of Other O + O or S + S Chelating Ligands
- 2 Silver
- 3 Gold
- Chapter 14 Scandium, Yttrium, Lanthanides, and Actinides
- 1 Scandium
- 2 Yttrium and the Lanthanides
- Inorganic Compounds
- Complex Compounds
- 3 The Actinides
- Uranium
- Inorganic Compounds
- Complexes
- Organometallic Compounds
- Chapter 15 Zinc, Cadmium, and Mercury
- 1 Zinc
- 2 Cadmium
- 3 Mercury
- Chapter 16 Boron, Aluminium, Gallium, Indium, and Thallium
- 1 Boron
- 2 Aluminium
- 3 Gallium
- 4 Indium
- 5 Thallium
- Chapter 17 Carbon, Silicon, Germanium, Tin, and Lead
- 1 Carbon
- 2 Silicon
- 3 Germanium
- 4 Tin
- Tin(II) Compounds
- Tin(IV) Compounds
- 5 Lead
- Chapter 18 Nitrogen, Phosphorus, Arsenic, Antimony, and Bismuth
- 1 Nitrogen
- 2 Phosphorus
- 3 Arsenic
- 4 Antimony
- 5 Bismuth
- Chapter 19 Oxygen, Sulphur, Selenium, and Tellurium
- 1 Oxygen
- 2 Sulphur
- 3 Selenium and Tellurium
- Chapter 20 Fluorine, Chlorine, Bromine, Iodine, and the Noble Gases
- 1 The Halogens
- 2 The Noble Gases
- Chapter 21 Lithium, Beryllium, Magnesium, and the Alkali and Alkaline-earth Elements
- 1 Lithium
- 2 Beryllium
- 3 Magnesium
- 4 Sodium, Potassium, Rubidium, Caesium, Calcium, Strontium and Barium
- Author Index
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