Inorganic Syntheses
1st Edition
Published on 22. September 2009
327 pages
978-0-470-13285-2 (ISBN)
Description
The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.
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D.F. Shriver
Inorganic Syntheses: v. 19
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02/1979
Wiley
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Content
- INORGANIC SYNTHESES
- CONTENTS
- Chapter One ELECTRICALLY CONDUCTING SOLIDS
- 1. Potassium Tetracyanoplatinate Bromide (2:1:0.3) Trihydrate, K2[Pt(CN)4]Br0.3 . 3H2O
- 2. Cation-Deficient, Partially Oxidized Tetracyanoplatinates
- A. Cesium Tetracyanoplatinate (2:1) Monohydrate and Cesium Tetracyanoplatinate (1.75:1) Dihydrate
- B. Potassium Tetracyanoplatinate (1.75:1) Sesquihydrate, K1.75[Pt(CN)4] . 1.5H2O
- C. Rubidium Tetracyanoplatinate (1.6:1) Dihydrate, Rb1.6 [Pt(CN)4] . 2H2O
- 3. Guanidium Tetracyanoplatinate Bromide (2:1:0.5) Hydrate, [C(NH2)3]2[Pt(CN)4] Br0.25 . H2O
- 4. Electrochemical Syntheses of Partially Oxidized Platinum Complexes
- A. Partially Oxidized Potassium Tetracyanoplatinates
- B. Partially Oxidized Potassium Bis(oxalato)platinate
- 5. Linear-chain Iridium Carbonyl Halides
- A. Ir(CO)3Cl1.10
- B. K0.60 Ir(CO)2Cl2 . 0.05H2O
- 6. Polymercury Cations
- A. Trimercury Bis[u-fluoro-bis(pentafluoroantimonate(V))] Hg3(Sb2F11)2, and Trimercury Bis[hexafluoroarsenate(V)] Hg3(AsF6)2
- B. The Infinite-Chain Compounds, Hg2.86(AsF6) and Hg2.91(SbF)6
- 7. 2,2'-Bi-1,3-Dithiolytidene (Tetrathiafulvalene, TTF) and Its Radical Cation Salts
- A. 2,2'-Bi-1,3-Dithiolylidene (Tetrathiafulvalene, TTF)
- B. [Tris(2,2'-bi-1,3-dithiolylidene) Radical Cation (2+)] Bis[tetra-fluoroborate(1-)] (Tetrathiafulvalenium Tetrafluoroborate), (TTF)3(BF4)2
- C. 2,2'-Bi-1,3-dithiolylidene Radical Cation Salts (Tetrathiafulvalenium Salts)
- D. [2,2'-Bi-1,3-dithiolylidene Radical Cation(1+)] [2,2'-(2,5-Cyclohexadiene-1,4-diylidene)bis[ propanedinitrite] Radical Anion (1-)] (Tetrathiafulvalenium Tetracyanoquinodimethanide), [(TTF)-(TCNQ)]
- 8. Tantalum Disulfide (TaS2) and Its Intercalation Compounds
- A. Polycrystalline 2H(a) Phase of TaS2
- B. Single Crystal 2H(a) Phase of TaS2
- C. Intercalation Compounds of TaS2
- 9. Platinum Disulfide and Platinum Ditelluride
- 10. Substituted B-Aluminas
- A. Silver B-Alumina [Aluminum Silver(I) Oxide]
- B. Thallium(I) B-Alumina [Aluminum Thallium(I) Oxide]
- C. Lithium B-Alumina (Aluminum Lithium Oxide)
- D. Potassium B-Alumina (Aluminum Lithium Oxide)
- E. Rubidium B-Alumina (Aluminum Rubidium Oxide)
- F. Ammonium B-Alumina (Aluminum Ammonium Oxide)
- G. Gallium(I) B-Alumina [Aluminum Gallium(I) Oxide]
- H. Nitrosyl B-Alumina (Aluminum Nitrosyl Oxide)
- Chapter Two METAL ATOM SYNTHESES
- 11. Introduction to Metal Atom Syntheses
- 12. Bis[1,3-bis(trifluoromethyl)benzene] chromium(0) [1.3-(CF3)2C6H4]2Cr
- 13. Bis(pentafluorophenyl)(n6-toluene)nickel(II)
- 14. Tetrachlorodiborane(4) (Diboron Tetrachloride)
- 15. An Active Cadmium-Toluene Slurry and Its Use in the Preparation of Ethyliodocadmium
- 16. Bis(n6-Chlorobenzene)molybdenum, Bis(n6-N,N-dimethylaniline)molybdenum and (1-3:6-7:-12-n-2,6,10-Dodecatriene-1,12-diyl)nickel
- A. Bis(n6-chlorobenzene)molybdenum
- B. Bis(n6-N,N-dimethylaniline)molybdenum
- C. (1-3:6-7:10-12-n-2,6,10-Dodecatriene-1,12-diyl)nickel
- Chapter Three TRANSITION METAL COMPOUNDS AND COMPLEXES
- 17. Hydrido(triphenylphosphine)copper(I)
- 18. Tetrakis(acetonitrile)copper(I) Hexafluorophosphate
- 19. Coordination Complexes of Copper(1) Nitrate
- A. Nitratobis(triphenylphosphine)copper(I)
- B. Nitratotris(triphenylstibine)copper(I)
- C. Nitratotris(triphenylarsine)copper(I)
- D. Tetrahydroboratobis(triphenylphosphine)copper(I)
- 20. (Dimethyl Phosphito) Complexes of Platinum(II)
- A. Chloro(dimethyl hydrogen phosphite-P)(dimethyl phosphito-P)(triphenylphosphine)platinum(II)
- B. Bis(dimethyl phosphito-P) [o-phenylenebis(dimethylarsine)] platinum(II)
- 21. Two-Coordinate Phosphine Complexes of Palladium(0) and Platinum(0)
- A. Bis(di-tert-butylphenylphosphine)palladium(0)
- B. Bis(tricyclohexylphosphine)palladium(0)
- C. Bis(tri-tert-butylphosphine)palladium(0)
- D. Bis(di-tert-butylphenylphosphine)platinum(0)
- E. Bis(tricyclohexylphosphine)platinum(0)
- 22. ThreeCoordinate Phosphine Complexes of Platinum(0)
- A. Tris(triethylphosphine)platinum(0)
- B. Tris(triisopropylphosphine)platinum(0)
- 23. Tetrakis(triethylphosphine)platinum(0)
- 24. Barium Tetracyanoplatinate(II) Tetrahydrate
- 25. Trans Phosphine Complexes of Platinum(II) Chloride
- A. trans-[Dichlorobis(triphenylphosphine)platinum(II)]
- B. trans-[Dichlorobis(tributylphosphine)platinum(II)]
- 26. Tris(ethylenediamine)ruthenium(II) and Tris(ethylenediamine)ruthenium(III) Complexes
- A. Tris(ethylenediamine)ruthenium(II) Tetrachlorozincate
- B. Tris(ethylenediamine)ruthenium(II) Chloride
- C. Tris(ethylenediamine)ruthenium(III) Chloride
- 27. Manganese Diphosphate (Manganese Pyrophosphate)
- 28. Electrochemical Synthesis of Chromium(III) Bromide
- A Facile Route to Chromium(III) Complexes
- A. Anhydrous Chromium(III) Bromide
- B. Tris(ethylenediamine)chromium(III) Bromide, [Cr(en)3]Br3
- C. Hexakis(dimethyl Sulfoxide)chromium(III) Bromide, [Cr-(DMSO)6] Br3
- D. Potassium Tris(oxalato)chromate(III) Trihydrate
- 29. Dinuclear Molybdenum Complexes
- A. Octachlorodimolybdate(4-), [Mo2Cl8]4-, di-u-chloro-1,1,1,2,2,2-hexachloro-u-hydrido-dimolybdate(3-), [Mo2Cl8H]3-, and Di-u-bromohexabromo-u-hydrido-dimolybdate(3-), [Mo2Br8H]3- Anions
- B. Tetrahalodimolybdenum(II) Complexes
- C. Bis- and Tetrakis(carboxylato)dimolybdenum(II) Complexes
- 30. (2,2'-Bipyridine)trichlorooxomolybdenum(V)
- A. 2,2'-Bipyridinium Pentachlorooxomolybdenum(V) [BpyH2]-[MoOCI5]
- B. [(2,2'-Bipyridine)trichlorooxomolybdenum(V)]-Red Form, [MoOCl3(bpy)]
- C. [(2.2'-Bipyridine)trichlorooxomolybdenum(V)] -Green Form, [MoOCl3(bpy)]
- 31. Metal Pentafluorides
- 32. Sodium and Ammonium Decavanadate(V)
- A. Sodium Decavanadate(V) Octadecahydrate, Na6[V10O28] . 18H2O]
- B. Ammonium Decavanadate(V) Hexahydrate, (NH4)6[V10O28] . 6H2O
- 33. cis-[Dihalobis(2,4-pentanedionato)titanium(IV)] Complexes
- Chapter Four TRANSITION METAL ORGANOMETALLIC COMPOUNDS
- 34. Bis(n8-cyclooctatetraene)uranium(IV)
- 35. (n6-Arene)tricarbonylchromium Complexes
- A. (n6-Anisole)tricarbonylchromium
- B. Other Arenetricarbonylchromium Complexes
- 36. Pentacarbonylmanganese Halides
- A. Pentacarbonylchloromanganese, MnCl(CO)5
- B. Pentacarbonylbromomanganese MnBr(CO)5
- C. Pentacarbonylbromomanganese Pentacarbonyliodomanganese. MnI(C0)5
- D. Pentacarbonyliodomanganese, Alternate Procedure
- 37. Methylene (Carbene) Complexes of Transition Metals
- A. Carbene Complexes obtained from Acyl- and Carbamoylmetallates
- 1. Pentacarbonyl(methoxyphenylmethylene)tungsten(0)
- 2. Pentacarbonyl(trimethylsiloxy-p-tolylmethylene)tungsten(0)
- 3. Pentacarbonyl[ethoxy(diethylamino)methylene] chromium(0)
- B. Carbene Complexes Obtained by NucleophiIic Substitution, Pentacarbonyl[(dimethylamino)phenylmethylene] tungsten(0)
- 38. Methylidyne (Carbyne) Complexes. trans-(Bromotetracarbonyl(phenylmethylidyne)tungsten]
- 39. Isocyanide and Methylene (Carbene) Complexes of Platinum(II)
- A. cis-(Dichloro(phenyl isocyanide)(triethylphosphine)platinum(II)]
- B. cis-[Dichloro(anilinoethoxymethylene)(triethylphosphine)platinum(II)]
- C. cis-[Dichloro(dianilinomethylene)(triethylphosphine)platinum(II)]
- D. trans-[(Anilino)(ethylamino)methylene] chlorobis(triethylphosphine)platinum(II)] Perchlorate
- 40. Pentacarbonyl(dihydro-2(3H)-furanylidene)chromium(0), (CO)5Cr(C4H6O)
- 41. Pentacarbonyl(diphenylmethylene)tungsten(0)
- 42. Thiocarbonyl Complexes of Tungsten(0)
- A. Pentacarbonyl(thiocarbonyl)tungsten(0)
- B. Tetrabutylammonium trans-[ tetracarbonyliodo(thiocarbonyl)tungstate]
- C. Pentacarbonyl(thiocarbonyl)tungsten(0)
- 43. Cyclopentadienylmanganese) Thiocarbonyls
- A. Carbonyl(n5-cyclopentadienyl)(thiocarbonyl)(triphenylphosphine)manganese(I)
- B. [1,2.Bis(diphenylphosphinoethane)] (n5-cyclopentadienyl)(thiocarbonyl)manganese(I)
- 44. Dicarbonyl(n5-cyclopentadienyl)(selenocarbonyl)manganese(I)
- 45. Arene Thiocarbonyl Chromium(0) Complexes
- A. Dicarbonyl(n6-o-dimethylbenzene)(thiocarbonyl)chromium(0)
- B. Dicarbonyl(methyl n6-benzoate)(thiocarbonyl)chromium(0)
- C. Dicarbonyl(methyl n6-m-methylbenzoate)(thiocarbonyl)chromium(0)
- D. Carbonyl(methyl n6-m-methylbenzoate)(thiocarbonyl)(triphenyl phosphite)chromium(0)
- 46. trans-[Chloro(thiocarbonyl)bis(triphenylphosphine)rhodium(l)]
- 47. trans-[Chloro(thiocarbonyl)bis(triphenylphosphine)iridium(l)]
- 48. (n5-Cyclopentadienyl)nitrosyl Chromium, Molybdenum, and Tungsten Complexes
- A. Alkyl- and Aryl(n5-cyclopentadienyl)dinitrosyl Cromium, Molybdenum, and Tungsten Complexes
- B. Bis[(n5-cyclopentadienyl)dinitrosylchromium]
- 49. Olefin Complexes of Platinum
- A. Bis(1,5-cyclooctadiene)platinum(0)
- B. Tris(ethylene)platinum(0)
- C. Bis(ethylene)(tricyclohexylphosphne)platinum(0)
- 50. Di-u-chloro-bis(n4-1,5-cyclooctadiene)dirhodium(I)
- 51. (n3-Allyl)palladium(II) Complexes
- A. Bis(n3-allyl)di-u-chloro-dipalladium(II)
- B. (n3-Allyl)(n5-cyclopentadienyl)palladium(II)
- 52. (n5-Cyclopentadienyl)hydridozirconium Complexes
- A. Bis(n5-cyclopentadienyl)dihydridozirconium
- B. Chlorobis(n5-cyclopentadienyl)hydridozirconium
- 53. Tetracarbonyl[octahydrotriborato(1-)]manganese, (CO)4Mn(B3H8)
- Chapter Five MAIN GROUP COMPOUNDS
- 54. Dihydro(isocyano)(trimethylamine)boron
- 55. 1-Methyldiborane(6)
- 56. 1,6-Diboracyclodecane, B2H2(C4H8)2
- 57. Tetrabutylammonium u-Hydro-dihydro-bis-(u-tetramethylene)-diborate(1-), [(C4H7)4N] [B2H3(C4H8)2
- 58. Hexaborane(10)
- 59. Dimethylzinc
- 60. Electrochemical Synthesis of Indium(III) Complexes
- A. Indium(III) Chloride
- B. Tris(dimethyl Sulfoxide)indium(III) Chloride [Trichlorotis(Dimethyl Sulfoxide)indium(III)
- C. Indium(III) Bromide
- D. Tris(dimethyl Sulfoxide)indium(III) Bromide (Tribromotis(Dimethyl- sulfoxide)indium(III)]
- E. Bis(tetraethylamrnonium)pentachloroindate(IlI)
- F. Tris(2,4-pentanedionato)indium(III) [Tris(acetylacetonato)indium(III)]
- 61. Bis[(trimethylsilyl)methyl] magnesium
- 62. Dodecamethylcyclohexasilane
- 63. Iodosilane and Its Methyl Derivatives
- A. Iodosilane
- B. Iodomethylsilane and Iododimethylsilane
- C. Iodotrimethylsilane
- 64. Silyl Sulfides
- A. Disilathiane
- B. 1,3-Dimethyl-, 1,1,3,3-Tetramethyl- and Hexamethyldisilathiane
- 65. Crystalline Polyammonium Catena-Polyphosphate
- Correction
- Index of Contributors
- Subject Index
- Formula Index
