The Chemistry of Ruthenium
Published on 22. October 2013
1414 pages
978-1-4832-8990-8 (ISBN)
Description
The Chemistry of Ruthenium is concerned with the chemistry of ruthenium, with emphasis on synthesis and structure. The discussion spans a wide range of fields, from coordination chemistry and organometallic chemistry to structural chemistry (of both molecular and extended lattices), electrochemistry and photochemistry, as well as kinetics and spectroscopy. Comprised of 15 chapters, this book begins with an introduction to the discovery and early history of ruthenium, along with its extraction and purification, isotopes, physical and chemical properties, and applications. The discussion then turns to the concept of oxidation state and a scheme for systematizing descriptive inorganic chemistry together with its applicability to ruthenium chemistry. Subsequent chapters focus on the chemistry of ruthenium(VIII), ruthenium(VII), ruthenium(VI), ruthenium(V), ruthenium(IV), ruthenium(III), ruthenium(II), ruthenium(I), and ruthenium(0). The book also considers ruthenium carbonyl clusters and nitrosyls before concluding with a review of the photophysics and photochemistry of tris(diimine)ruthenium(II) complexes. This monograph will be useful to students, practitioners, and researchers in the field of inorganic chemistry, as well as those who are interested in the chemistry of ruthenium.
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Additional editions
E.A. Seddon | K.R. Seddon | R. J. H. Clark
The Chemistry of Ruthenium: Volume 19
Book
07/1984
Elsevier
€70.55
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Content
¿FrontispieceAbbreviationsSign Conventions and Conversion FactorsChapter 1 Introduction 1.1 Scope and Vera Causa 1.2 Ordering of the Chapters 1.3 Ordering within the Chapters 1.4 Discovery and Early History of Ruthenium 1.5 Extraction and Purification of Ruthenium 1.6 Analysis 1.7 Applications and Uses of Ruthenium 1.8 Isotopes of Ruthenium 1.9 Physical Properties of Ruthenium 1.10 Chemical Properties of RutheniumChapter 2 Oxidation State 2.1 What is Oxidation State? 2.2 Does Oxidation State have a Chemical Significance? 2.3 The MLX System 2.3.1 Definitions and Scope 2.3.2 The Classification of Neutral Molecules Containing Monodentate Ligands 2.3.3 The Rules for Classifying Vovalent Anions and Cations 2.3.4 Polyfunctional Atoms and Polydentate Ligands 2.3.5 Bridging Ligands 2.4 MLX Plots 2.4.1 Construction of MLX Plots 2.4.2 Use of MLX Plots 2.5 Mössbauer SpectroscopyChapter 3 Ruthenium(VIII) 3.1 Ruthenium(VIII) Fluoride 3.2 Ruthenium(VIII) Oxide 3.2.1 Physical and Spectroscopic Properties 3.2.2 Preparation 3.2.3 Adducts 3.2.4 Reactions 3.2.5 Oxidation of Organic Compounds AddendaChapter 4 Ruthenium(VII) 4.1 Potassium Ruthenate(VII) 4.1.1 Preparation 4.1.2 Physical and Spectroscopic Properties 4.1.3 Reactions 4.2 Sodium Ruthenate(VII) 4.3 µ-Oxo-Bis[Trioxo(1,10-Phenanthroline)Ruthenium(VII)]Chapter 5 Ruthenium(VI) 5.1 Ruthenium(VI) Fluoride 5.2 Ruthenium(VI) Oxide Tetrafluoride 5.3 Potassium Octafluororuthenate(VI) 5.4 Dioxoruthenium(VI) Complexes 5.4.1 Tetrahalodioxoruthenates(VI) and Related Species 5.4.2 Bis(Amine)Dichlorodioxoruthenium(VI), Bis(Amine)Dihydroxodioxoruthenium(VI) and Related Species 5.5 Nitridoruthenium(VI) Complexes 5.5.1 Tetra- and Penta-Halonitridoruthenates(VI) 5.5.2 Trichloronitridoruthenium(VI) Adducts 5.6 Ruthenium(VI) Oxide 5.7 Metal Ruthenates(VI) 5.7.1 Preparation 5.7.2 Physical and Spectroscopic Properties 5.7.3 Reactions 5.8 Ruthenium(VI) Sulphates and Related Species 5.9 Ruthenium(VI) Amides 5.9.1 Ruthenium(VI)-1,2-Diaminoethane Complex 5.9.2 Ruthenium(VI)-Ammonia Derivative AddendaChapter 6 Ruthenium(V) 6.1 Ruthenium(V) Fluoride 6.2 Metal Hexafluororuthenates(V) 6.3 Non-Metal Hexafluororuthenates 6.3.1 Xenon Salts 6.3.2 Dioxygenyl Hexafluororuthenate(V) 6.3.3 Other Hexafluororuthenates(V) 6.4 Bis(Tricarbonyldifluororuthenium(II)-Ruthenium(V) Fluoride) 6.5 Caesium Tetracyanobis(Isocyanato)Oxoruthenate(V) 6.6 Ruthenium(V) Oxide 6.7 Quaternary Ruthenium(V) Oxides 6.8 Sodium and Lithium Ruthenates(V) AddendaChapter 7 Ruthenium(IV) 7.1 Ruthenium(IV) Halides and Oxohalides 7.1.1 Ruthenium(IV) Fluoride 7.1.2 Ruthenium(IV) Chloride 7.1.3 Ruthenium(IV) Bromide and Ruthenium(IV) Iodide 7.1.4 Ruthenium(IV) Oxohalides and Related Species 7.2 Hexahaloruthenates(IV) 7.2.1 Hexafluororuthenates(IV) 7.2.2 Hexachlororuthenates(IV) 7.2.3 Hexabromoruthenates(IV) 7.2.4 Hexaiodoruthenates(IV) 7.3 µ-Oxo-Bis[Pentahaloruthenates(IV)] and Related Complexes 7.3.1 Potassium µ-Oxo-Bis[Pentachlororuthenate(IV)] Monohydrate 7.3.2 Potassium µ-Oxo-Bis[pentabromoruthenate(IV)] 7.4 µ-Nitrido-Bis[Aquatetrahaloruthenates(IV)] and Related Complexes 7.5 Adducts of Ruthenium(IV) Halides and Related Complexes 7.5.1 Complexes with Nitrogen-Donor Ligands 7.5.2 Phosphineiminato Complexes 7.5.3 Triphenylphosphine-Carbon Disulphide Complex 7.5.4 Phthalocyanine-Tetrasulphonate Complexes 7.5.5 Selenourea Complexes 7.5.6 o-Diolato Complexes 7.
