
Laser Sintering with Plastics
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Content
- Intro
- The Author
- Foreword
- Contents
- 1 Introduction
- 1.1 Manufacturing Technology
- 1.2 Additive Manufacturing
- 1.2.1 Application Areas and Technology Drivers
- 1.2.2 Main Groups of Additive Manufacturing
- 1.3 Additive Manufacturing with Plastics
- 1.3.1 Vat Photopolymerization (VPP)
- 1.3.2 Material Extrusion (MEX)
- 1.3.3 Material Jetting Technology (MJT)
- 1.3.4 Powder Bed Fusion (PBF)
- 1.3.5 Comparison of AM Processes for Plastics
- 1.4 Laser Sintering (LS) with Plastics
- 2 Laser Sintering Technology
- 2.1 Machine Technology
- 2.1.1 Machine Configuration
- 2.1.2 Temperature Control
- 2.1.2.1 Heat Sources
- 2.1.2.2 Surface Temperature at the Build Area
- 2.1.2.3 Laser Energy Input, Andrew Number (AN)
- 2.1.3 Powder Supply and Powder Application
- 2.1.3.1 Internal and External Powder Supply
- 2.1.3.2 Powder State (Conditioning)
- 2.1.4 Powder Application
- 2.1.4.1 Blade and Powder Cartridge
- 2.1.4.2 Roll Coater
- 2.1.4.3 Combined Coating Systems
- 2.1.5 Optical Components
- 2.1.5.1 Laser Beam Positioning
- 2.1.5.2 Focus Correction
- 2.2 Machine Market
- 2.2.1 Industrial Laser Sintering Equipment
- 2.2.1.1 Company: Electro Optical Systems, EOS (Germany)
- 2.2.1.2 Company: 3D Systems (USA)
- 2.2.1.3 Company: Farsoon Technologies (China)
- 2.2.1.4 Other Manufacturers of LS Equipment
- 2.2.2 Pilot Plant and Research & Development Facilities
- 2.2.2.1 R&D Plants with CO2 Lasers
- 2.2.2.2 R&D Systems with Laser Diodes
- 3 The Laser Sintering Process
- 3.1 Process Chain
- 3.1.1 Powder Supply
- 3.1.2 Data Preparation and Build Job
- 3.1.3 Build Process
- 3.1.3.1 Heating Up
- 3.1.3.2 Process Flow
- 3.1.3.3 Parts and Building Chamber Parameters
- 3.1.3.4 Exposure Strategy
- 3.1.3.5 Cooling and Unpacking
- 3.1.4 Process Error
- 3.1.4.1 Deformation of the Parts
- 3.1.4.2 Surface Defects: Orange Peel
- 3.1.4.3 Other Process Errors
- 3.2 Qualification for Industrial Series Production
- 3.2.1 Product-Related Processes
- 3.2.1.1 Pre-Process
- 3.2.1.2 In-Process
- 3.2.1.3 Post-Process
- 3.2.1.4 Process Validation
- 3.2.2 Functional Processes
- 3.2.2.1 Feedstock Management
- 3.2.2.2 Qualification of the Laser Sintering Machine
- 3.2.2.3 Qualification of the Laser Sintering Process
- 3.2.3 Status of Standardization
- 4 Laser Sintering Materials: Polymer Properties
- 4.1 Polymers
- 4.1.1 Polymerization
- 4.1.2 Chemical Structure (Morphology)
- 4.1.3 Thermal Behavior
- 4.1.4 Polymer Processing
- 4.1.5 Viscosity and Molecular Weight
- 4.2 Key Properties of LS Polymers
- 4.2.1 Thermal Properties
- 4.2.1.1 Crystallization and Melting (Sintering Window)
- 4.2.1.2 Heat Capacity (cp) and Enthalpy (?Hc, ?Hm)
- 4.2.1.3 Thermal Conductivity and Thermal Radiation
- 4.2.1.4 Modeling of the Processes in the Sintering Window
- 4.2.2 Rheology of the Polymer Melt
- 4.2.2.1 Melt Viscosity
- 4.2.2.2 Surface Tension
- 4.2.3 Optical Properties
- 4.2.3.1 Absorption
- 4.2.3.2 Transmission and (Diffuse) Reflection
- 5 Laser Sintering Materials: Polymer Powder
- 5.1 Powder Production for Laser Sintering
- 5.1.1 Emulsion, Suspension, and Solution Polymerization
- 5.1.2 Precipitation from Solutions
- 5.1.3 Grinding and Mechanical Comminution
- 5.1.4 Melt Emulsification
- 5.1.5 Laser Sintering Powder Production at a Glance
- 5.1.6 Other Powder Manufacturing Processes
- 5.2 Powder Properties for Laser Sintering
- 5.2.1 Powder Density
- 5.2.1.1 Particle Shape and Surface
- 5.2.1.2 Particle Size Distribution (Number and Volume Distribution)
- 5.2.2 Powder Rheology
- 5.2.3 Measurement of Powder Flowability
- 5.2.3.1 Hausner Ratio (HR)
- 5.2.3.2 Rotating Powder Analysis
- 5.2.3.3 Flow Agents
- 6 Laser Sintering Materials: Commercial Materials
- 6.1 Polyamide (Nylon)
- 6.1.1 Polyamide 12 (PA 12)
- 6.1.1.1 Particle Size Distribution and Particle Form
- 6.1.1.2 Thermal Properties
- 6.1.1.3 Crystal Structure
- 6.1.1.4 Molecular Weight and Post-Condensation
- 6.1.1.5 Powder Aging
- 6.1.1.6 Property Combination of PA 12
- 6.1.2 Polyamide 11 (PA 11)
- 6.1.3 Comparison of PA 12 and PA 11
- 6.1.4 Compound Materials of PA 12 and PA 11
- 6.1.5 Flame-Retardant Materials Based on PA 12 and PA 11
- 6.1.6 Other Polyamides (PA 6, PA 613, PA 1212)
- 6.2 Other Laser Sintering Polymers
- 6.2.1 Thermoplastic Elastomers (TPU, TPA, TPC)
- 6.2.2 High-Performance Polymers (PAEK, PPS)
- 6.2.3 Polyolefins (PP, PE)
- 6.2.4 Polyesters (PBT, PET)
- 6.2.5 Thermosets
- 7 Laser-Sintered Parts
- 7.1 Component Properties
- 7.1.1 Mechanical Properties
- 7.1.1.1 Short-Term Loading: Tensile Test
- 7.1.1.2 Laser Sintering Parameters
- 7.1.1.3 Component Density
- 7.1.1.4 Partial Melting (DoPM)
- 7.1.1.5 Anisotropy of Component Properties
- 7.1.1.6 Long-Term Resistance
- 7.1.2 Component Surfaces
- 7.1.2.1 Influencing Parameters
- 7.1.2.2 Roughness Determination
- 7.1.2.3 Surface Processing
- 7.1.2.4 Finishing
- 7.2 Applications and Examples
- 7.2.1 Prototype Construction and Small Series
- 7.2.2 Function Integration
- 7.2.3 Part List Reduction
- 7.2.4 Individualization and Personalization
- 7.2.5 Business Models and Outlook
- Index
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