Substoichiometry in Radiochemical Analysis
International Series of Monographs in Analytical Chemistry
Published on 22. October 2013
164 pages
978-1-4831-8412-8 (ISBN)
Description
Substoichiometry in Radiochemical Analysis considers application of simple chemistry than the use of complicated instrumentation in studying radiochemical analysis. This book is divided into nine chapters; the first chapter gives an introduction to the content of this monograph. This text then examines the neutron-activation and isotope-dilution analyses, complemented with the general technique and preliminary experiments. Specifically, this book provides the methods for the substoichiometric determination of traces of various elements by the neutron-activation and isotope-dilution analyses. Copper, mercury, gallium, gold, and zinc are some of the elements featured in this particular topic. This topic is followed by the discussion on the analysis of radioactive materials. This text also tackles the automation and comparison with other radiometric methods of substoichiometric analysis, as well as trends in substoichiometry. This book will be helpful for those concerned with substoichiometry, especially those who need a book that presents non-complicated study of the subject.
More details
Other editions
Additional editions
J. Stary | J. Ruzicka | Jarombir Rjuiziicka
Substoichiometry in Radiochemical Analysis
Book
01/1968
Franklin Book Co
€73.59
Article exhausted; check different version
Content
Preface1. Introduction2. Neutron-Activation Analysis 2.1. General 2.2. Substoichiometric Principle 2.3. Theory of Solvent Extraction of Metal Chelates 2.4. Theory of Solvent Extraction of Ion-Association Compounds 2.5. Theory of Ion-Exchange Separation of Water-Soluble Chelates 2.6. Theory of Precipitation Reactions 2.7. Limitations of Sensitivity of Method3. Isotope-Dilution Analysis 3.1. General 3.2. Substoichiometric Principle 3.3. Theory of Solvent Extraction of Metal Chelates 3.4. Theory of Solvent Extraction of Ion-Association Compounds 3.5. Theory of Ion-Exchange Separation of Water-Soluble Chelates 3.6. Limitations of Sensitivity of Method4. General Technique and Preliminary Experiments 4.1. Course of Analysis 4.2. Instrumentation 4.3. Reagent, Carrier and Standard Solutions 4.4. Reproducibility of Substoichiometric Separation 4.4.1. Influence of pH 4.4.2. Time for Reaching Equilibrium 4.4.3. Experimental Reproducibility 4.5. Selectivity of Substoichiometric Separation5. Procedures for Substoichiometric Determination of Traces of Elements 5.1. Antimony 5.1.1. Neutron-Activation Analysis 5.1.2. Isotope-Dilution Analysis 5.2. Arsenic 5.2.1. Neutron-Activation Analysis 5.3. Bismuth 5.3.1. Neutron-Activation Analysis 5.4. Cadmium 5.4.1. Isotope-Dilution Analysis 5.5. Chlorine 5.5.1. Isotope-Dilution Analysis 5.6. Cobalt 5.6.1. Neutron-Activation Analysis 5.6.2. Isotope-Dilution Analysis 5.7. Copper 5.7.1. Neutron-Activation Analysis 5.7.2. Isotope-Dilution Analysis 5.8. Fluorine 5.8.1. Isotope-Dilution Analysis 5.9. Gallium 5.9.1. Neutron-Activation Analysis 5.10. Gold 5.10.1. Neutron-Activation Analysis 5.11. Indium 5.11.1. Neutron-Activation Analysis 5.11.2. Isotope-Dilution Analysis 5.12. Iodine 5.12.1. Isotope-Dilution Analysis 5.13. Iron 5.13.1. Neutron-Activation Analysis 5.13.2. Isotope-Dilution Analysis 5.14. Lead 5.14.1. Isotope-Dilution Analysis 5.15. Manganese 5.15.1. Neutron-Activation Analysis 5.16. Mercury 5.16.1. Neutron-Activation Analysis 5.16.2. Isotope-Dilution Analysis 5.17. Molybdenum 5.17.1. Neutron-Activation Analysis 5.18. Rare Earths 5.18.1. Isotope-Dilution Analysis 5.19. Rhenium 5.19.1. Neutron-Activation Analysis 5.20. Scandium 5.20.1. Neutron-Activation Analysis 5.21. Silver 5.21.1. Neutron-Activation Analysis 5.21.2. Isotope-Dilution Analysis 5.22. Yttrium 5.22.1. Isotope-Dilution Analysis 5.23. Zinc 5.23.1. Neutron-Activation Analysis 5.23.2. Isotope-Dilution Analysis6. Analysis of Radioactive Materials 6.1. Substoichiometric Determination of Radioactive Impurities in Radioactive Preparations 6.2. Radiochemical Analysis of Fission Products 6.3. Determination of Small Amounts of Isotopic Carrier in Radioactive Preparations7. Automation of Substoichiometric Analysis8. Comparison of Substoichiometric Isotope-Dilution Analysis and Other Radiometric Methods 8.1. Radiometric Microanalysis 8.1.1. Non-Isotopic Tracer Method (Radioreagent Method) 8.1.2. Isotopic Tracer Method 8.2. Radiometric Titrations 8.3. Conclusions9. Trends in SubstoichiometryAppendixReferencesIndexOther Titles in the Series
