
Surface and Defect Properties of Solids
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Content
- Surface and Defect Properties of Solids
- Contents
- Chapter 1 Surface Electronic Structure
- 1 Introduction
- 2 Intrinsic Surface States
- General Results on Surface State Existence
- Surface States on Semiconductors
- Surface States on Metals
- 3 Terminating Bulk States at the Surface
- 4 Concluding Remarks
- Chapter 2 Disclination Structures in Carbonaceous Mesophase and Graphite
- 1 Introduction
- 2 Background
- Formation of the Carbonaceous Mesophase
- Formation of Mesophase Microstructures
- Properties of the Carbonaceous Mesophase
- 3 Optical Microscopy of the Carbonaceous Mesophase
- Micrographic Technique
- Disclination Structures in Coalesced Mesophase
- Disclination Structures in Deformed Mesophase
- 4 Electron Microscopy of Disclinations in Graphite
- 5 Geometry of Disclinations in the Carbonaceous Mesophase
- Crystal Symmetry
- Layer-stacking Disclinations
- Layer Disclinations
- Chapter 3 The Role of Defects in Vaporization: Arsenic and Antimony
- 1 Retarded Vaporization and Surface Defects
- 2 Retarded Vaporization of Arsenic and Antimony: Summary of Steady-state Results
- 3 Vaporization Pit Characteristics and the Role of Defects
- 4 Changes in Vaporization Rate and in Surface Morphology Caused by Defects
- 5 Role of Defects in the Vaporization Mechanism
- Arsenic
- Antimony
- 6 Closing Comments
- Chapter 4 Interaction of High-energy Electrons with Organic Crystals in the Electron Microscope: Difficulties Associated with the Study of Defects
- 1 Introduction
- 2 Detection of Radiation Damage
- 3 The Establishment of Optimum Conditions in the Electron Microscope
- Damage as a Function of the Electron Beam Velocity
- Damage as a Function of Sample Temperature
- Damage as a Function of Specimen Thickness
- Damage as a Function of Chemical Substituents
- Damage as a Function of the Sample Environment
- 4 Changes in Organic Materials
- 5 Energy-loss Measurements
- 6 Implications of Radiation Damage in the Study of Organic Crystals
- High-resolution Microscopy
- Defect Analysis
- 7 Conclusions
- Chapter 5 The Dehydrogenation of Hydroaromatic Compounds on Metals
- 1 Summary
- 2 Introduction
- 3 Adsorption of Cyclohexane and Benzene
- 4 Intermediates in Cyclohexane Dehydrogenation
- 5 Dehydrogenation of Five-membered Cyclic Hydrocarbons
- 6 Kinetics
- 7 Mechanism
- 8 The Catalysts for Cyclohexane Dehydrogenation
- Chapter 6 Ultraviolet Photoemission Spectroscopy of Surfaces and Surface Sorption
- 1 Introduction
- 2 Surface Electronic Structure and Reactions on Si and GaAs
- Silicon Studies
- Detection of Empty Surface States
- Studies of GaAs and Other III-V Compounds
- Electronic Reconstruction on Clean (110) GaAs
- Oxygen Chemisorption on (110) GaAs
- 3 Examination of UPS Spectra from Au for 80 & hv & 180 eV
- 4 Physical Adsorption or Condensation on MoS2
- 5 Chemisorption of CO and Simple Hydrocarbons on 3d Metals
- Changes in Gas Spectra due to Chemisorption
- Changes in Substrate Photoemission due to Chemisorption
- 6 Studies of Cu-Ni Alloys and the Adsorption of CO Thereon
- Introduction
- Surface versus Bulk Composition
- Use of UPS to Study Surface Composition and Electronic Structure
- Chemisorption of CO on Cu-Ni Alloys
- 7 Use of UPS and Thermal Desorption to Study the Mechanism of a Catalytic Reaction
- 8 UPS Studies of Oxidation
- Introduction
- Experimental Means for Distinguishing between Adsorption and Absorption
- Sr and Cs
- Examples of Metals where the Surface is Oxidized Last
- Ce
- An Example of Surface Oxidation and Comparison with Sr Oxidation
- Al
- An Example where the Initial Oxide Lies beneath the Surface but Bulk Oxide is not Formed
- Concluding Remarks and Discussion of Oxidation Results
- 9 Discussion and Conclusions
- Surface Chemistry of Compounds
- Use of UPS to Identify Substrate and Adsorbate Orbitals involved in Chemisorption
- Cu?Ni Alloys
- UPS Studies of Oxidation in Three Dimensions
- Chapter 7 Secondary Ion Mass Spectrometry (SIMS): A Technique for Studying Surface Reactivity
- 1 Introduction
- Static SIMS
- Dynamic SIMS
- Microprobe SIMS
- Imaging SIMS
- 2 Instrumentation
- 3 The Phenomenology and Theory of Sputtering
- 4 Application of SIMS to Surface Problems
- Surface Oxidation of Metals
- Characterization of Non-metal Surfaces
- Adsorption at Surfaces
- 5 Conclusions
- Chapter 8 The Chemical Physics and Organometallic Chemistry of Transition-metal Surfaces
- 1 Introduction
- 2 The Geometrical Arrangement of Metal Atoms at Clean Surfaces
- A Summary of the Low-energy Electron Diffraction (LEED) Method
- The Crystallography of Low-index Surfaces
- The Surface Crystallography of Aluminium
- The Surface Structures of Copper
- The Surfaces of Silver
- The Surface Crystallography of Nickel
- Platinum
- The Early Transition Metals
- The Crystallography of High Miller Index Surfaces
- 3 The Geometry of Metal-Ligand Surface (Overlayer Structures)
- Simple Overlayer Structures
- The Al(001)-(V2 × V2)R45°-Na Surface
- The Ni(001)-(V2 × V2)R45°-Na Surface
- The Crystallography of Chalcogen-Nickel Surfaces
- Overlayer Structures on Copper and Silver Surfaces
- The Surface Crystallography of Some Physisorbed Systems
- Structural Studies of Alkene- and Carbonyl-Metal Surfaces
- Carbon Monoxide Chemisorbed on Nickel, Palladium, and Platinum Surfaces
- Carbon Monoxide Chemisorbed on Other Transition-Metal Surfaces
- The Organometallic Chemistry of Alkene-Transition-metal Surfaces
- Chemisorption of Other Organic Molecules on Simple Transition-metal Surfaces
- Sorption and Reactions of Organic Molecules at High Miller Index Surfaces
- Author Index
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