
Chemical Physics of Solids and Their Surfaces
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Content
- Chemical Physics Of Solids And Their Surfaces
- Contents
- Chapter 1 Defects and Microstructures in Feldspars
- 1 Introduction
- 2 The Structure of e-Plagioclase
- Background
- Microstructure
- High-resolution, Lattice-imaging TEM
- 3 Defects and Microstructures in Microline and Anorthoclase
- Background
- General Nature of the Microstructures
- Optical Microscopy
- Transmission Electron Microscopy
- Discussion of Observations
- 4 General Discussion
- Chapter 2 The Use of Atom-Atom Potentials in Interpreting the Behaviour of Organic Molecular Crystals
- 1 Introduction
- 2 Atom-Atom Potentials
- Fundamental Considerations
- Electrostatic Interactions
- Dispersive and Repulsive Interaction Potentials
- 3 Computation of Lattice Energies and Crystal Structures
- 4 Applications
- Molecular Conformations in Perfect Crystals
- 9, 10-Biphenyl Anthracene
- Pyrene
- Polyphenyls
- Barrier Heights to Molecular Rotation in Ordered Crystals
- Planar Faults in Organic Crystals
- Polymorphism and Co-existance of Phases
- Other Types of Defect Disorders in Molecular Crystals
- Lattice Dynamics
- 5 Concluding Remarks
- Chapter 3 The Characterization and Properties of Small Metal Particles
- 1 Introduction
- 2 Morphology and Electronic Properties of Small Metal Particles
- Structural Considerations
- Electronic Properties
- Theoretical Descriptions
- 3 Metal Particle Preparation on a Support Material
- The Vacuum Deposition Approach
- Cluster and Cluster Compounds
- 4 Matrix Isolation Techniques
- Metal Cluster Formation
- Chemisorption Simulation
- 5 Conclusions and Outlook
- Chapter 4 Neutron Scattering from Adsorbed Molecules, Surfaces, and Intercalates
- 1 Introduction
- 2 Experimental Techniques
- 3 Comparison with other Surface Techniques
- Inelastic Incoherent Neutron Scattering
- Elastic Coherent Scattering
- Diffusion Measurements
- Magnetic Scattering
- Inelastic Coherent Scattering
- 4 Theory
- Scattering Intensities in Inelastic Scattering
- The Influence of Diffusion on the Scattering Cross-section
- 5 Physisorbed Gases
- Nitrogen, Oxygen, and the Inert gases Adsorbed on Graphite
- Hydrogen and Hydrogenous Molecules Adsorbed on Graphite
- Hydrogen
- CH4, C2H4, and C2H2
- C4H10
- C5H12
- NH3
- 6 Chemisorbed Gases
- Chemisorption on Metal Surfaces
- Adsorption on Oxide Surfaces
- Vibration Spectra
- Quasielastic Scattering
- 7 Clean Surfaces
- The Density of Phonon States at the Surface
- Surface Magnetism
- 8 Intercalated Phases
- Structural Investigations
- Dynamics
- Spectroscopic Measurements
- Quasielastic Scattering
- 9 Future Applications
- Chapter 5 Photo-induced Reactivity at Oxide Surfaces
- 1 Introduction
- 2 Photoelectronic Processes
- Optical Absorption
- Photoconductivity and Photoluminescence
- Photochromic and Electro-optical Effects
- 3 Photoeiectrochemical Processes
- Photosensitization of Solids
- Photoelectrocatalysis
- 4 Photoadsorption and Photodesorption at Oxide Surfaces
- General Comments
- Zinc Oxide
- Photoadsorption and Photodesorption Induced by Ultraviolet/Visible Light
- Photoadsorption Induced by X-radiation
- Photoadsorption Induced by ?-radiation
- Magnesium Oxide
- Photoadsorption Induced by ?-radiation
- Titanium Dioxide
- Hydroxylated Surfaces
- Dehydroxylated Surfaces
- 5 Photocatalytic Reactions on Oxide Surfaces
- Zinc Oxide
- Photocatalytic Oxidation of Carbon Monoxide
- Hydrogen-Deuterium Exchange
- Titanium Dioxide
- Photocatalytic Oxidation of Alcohols
- Photocatalytic Oxidation of Alkanes
- Photohydrogenation of Ethyne and Ethene
- 6 Concluding Remarks
- Chapter 6 Reflection-absorption Infrared Spectroscopy
- 1 Introduction
- 2 Physical Basis of Reflection Infrared Spectroscopy
- 3 Experimental Methods
- Wavelength Modulation
- Polarization Modulation
- 4 Applications
- Carbon Monoxide
- Copper
- Silver and Gold
- Palladium
- Platinum
- Rhodium
- Nickel
- Tungsten
- Nitrogen
- Hydrogen
- Oxidation
- Nitric Oxide
- Organic Molecules
- Author Index
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