
Optimizing Air Pollution Control Equipment Performance
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Comprehensive overview of the air pollution control technology field including the design, selection, operation, and maintenance of relevant devices
Optimizing Air Pollution Control Equipment Performance delivers an analysis of the subject of air pollution control equipment from the perspective of the practicing engineer or an applied scientist, rather than a theoretical perspective.
Written by a team of highly qualified authors with experience in both industry and academia, coverage includes:
- Design and selection of a variety of relevant devices as well as carbon dioxide capture processes and technologies related to control of NOx
- Strategies to ensure that air pollution control systems meet stringent emission standards and latest technological requirements, with up-to-date references throughout
- Typical problems related to air pollution control equipment, emphasizing where and how these factors can have a major impact on the maintenance problems of control devices
- Methods to reduce maintenance costs and prevent deterioration of collector performance
A timely reference detailing problems that have plagued users for nearly 100 years, Optimizing Air Pollution Control Equipment Performance earns a well-deserved spot on the bookshelves of professionals working in environmental control, including consultants, engineers, and government agency personnel, as well as advanced students in related programs of study.
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Jay Richardson is a combustion engineer. He has over a decade of experience custom-engineering, fabricating, and installing industrial and utility burner systems. He is skilled in combustion diagnostics, flow modeling, specialized boiler testing, and ultra-low NOx research.
Louis Theodore, MChE and EngScD, is a retired professor of chemical engineering (50 years). He is the author of several notable air pollution publications and a section editor (environmental management) and contributor to the last five editions of Perry's Chemical Engineers' Handbook.
Content
About the Authors xiii
Foreword xiv
Preface xv
Comments from Afar xvii
Part I Prologue 1
1 Definitions/Glossary of Terms 3
1.1 Glossary of Terms 3
References 19
2 The Air Pollution Problem 20
2.1 Early History 20
2.2 Sources and Classifications of Air Pollution 22
2.3 The Need for Control 22
2.4 Estimating Pollutant Emissions 23
2.5 Measurement Methods 24
References 25
3 Classifications, Sources, and Effects of Air Pollution 26
3.1 Sources of Air Pollutants 26
3.2 Atmospheric Air Pollutants 27
3.3 Airborne Particulates 28
3.4 Airborne Toxins 28
3.5 Sulfur Dioxide and Acid Deposition 28
3.6 Indoor Air Pollutants 28
3.7 Water and Land Pollutants 29
3.8 Effects of Air Pollution 30
References 31
4 Multimedia Concerns 32
4.1 Environmental Problems 33
4.2 The Multimedia Approach 33
4.3 Multimedia Application 34
4.4 Education and Training 35
References 36
5 Regulations 37
5.1 Early Air Pollution Legislation 37
5.2 Clean Air Act of 1970 38
5.3 Clean Air Act Amendments of 1977 40
5.4 Clean Air Act Amendments of 1990 43
5.5 Other Considerations 47
References 49
6 Environmental and Health Risk 50
6.1 Risk Variables and Categories 50
6.2 Risk Assessment 51
6.3 Health Risk Assessment/Analysis 52
6.4 Health Risk Assessments Components 53
6.5 Hazard Risk Assessment/Analysis 56
6.6 Risk Uncertainties/Limitations 57
References 58
7 Introduction to Air Pollution Control Equipment 59
7.1 Air Pollution Control Equipment for Particulates 59
7.2 Air Pollution Control Equipment for Gaseous Pollutants 62
7.3 Hybrid Systems 64
7.4 Factors in Selecting and Comparing Equipment 66
References 66
8 Introduction to Operation, Maintenance, and Inspection 67
8.1 The Need for an Operation and Maintenance Program 67
8.2 System Description 68
8.3 Personnel 69
8.4 Installation Procedures 70
8.5 Operation 71
8.6 Maintenance and Inspection 71
8.7 Improving Operation and Performance 71
8.8 Special Tools and Equipment 72
8.9 Records 72
References 73
Part II Air Pollution Control Equipment 75
9 Absorbers 77
9.1 Description of Control Device 77
9.2 Design Considerations 78
9.3 Installation Procedures 79
9.4 Operation 81
9.5 Maintenance 83
9.6 Improving Operation and Performance 84
9.7 Recent Developments 85
9.8 Conclusions 86
References 86
10 Adsorbers 87
10.1 Description of Control Device 87
10.2 Design Considerations 88
10.3 Installation Procedures 90
10.4 Operation 92
10.5 Maintenance 97
10.6 Improving Operation and Performance 98
10.7 Monitoring 100
10.8 Recent Developments 101
10.9 Conclusions 101
References 102
11 Incinerators 103
11.1 Description of Control Devices 103
11.2 Design Considerations 105
11.3 Installation Procedures 105
11.4 Operation 106
11.5 Maintenance 108
11.6 Improving Operation and Performance 109
11.7 Recent Developments 109
11.8 Conclusions 109
References 110
12 Condensers 111
12.1 Description of Control Device 112
12.2 Design Considerations 113
12.3 Installation Procedures 114
12.4 Operation 115
12.5 Maintenance 115
12.6 Improving Operation and Performance 116
12.7 Recent Developments 117
12.8 Conclusions 117
References 118
13 Mechanical Collectors 119
13.1 Description of Control Device 120
13.2 Design Considerations 122
13.3 Installation Procedures 122
13.4 Operation 122
13.5 Maintenance 124
13.6 Improving Operation and Performance 125
13.7 Recent Advances 126
13.8 Conclusions 126
References 126
14 Wet Scrubbers 127
14.1 Description of Control Devices 128
14.2 Design Considerations 130
14.3 Installation Procedures 131
14.4 Operation 133
14.5 Maintenance 136
14.6 Improving Operation and Performance 138
14.7 Recent Developments 145
14.8 Conclusions 145
References 146
15 Electrostatic Precipitators 147
15.1 Description of Control Device 150
15.2 Design Considerations 152
15.3 Installation Procedures 153
15.4 Operation 154
15.5 Maintenance 162
15.6 Improving Operation and Performance 167
15.7 Recent Developments 171
15.8 Conclusions 172
References 173
16 Baghouses 174
Paul Farber
16.1 Description of Control Device 175
16.2 Cleaning Methods 177
16.3 Design Considerations 181
16.4 Installation Procedures 182
16.5 Operation 185
16.6 Startup and Shutdown 186
16.7 Improving Operation and Performance 192
16.8 Recent Advances 193
16.9 Conclusions 194
References 194
17 Hybrid Systems 195
Sean Dooley
17.1 Dry Scrubbers 196
17.2 Ionizing Wet Scrubber (IWS) 198
17.3 Wet Electrostatic Precipitators (WEPs) 200
17.4 Electrostatic Stimulation of Fabric Filtration 201
17.5 Recent Advances in Control Equipment Technology 202
17.6 Conclusion 202
References 202
18 Controlling the Oxides of Nitrogen 203
18.1 The Oxides of Nitrogen 203
18.2 NoX Control Methods 206
18.3 Reducing NoX Generation Via Pollution Prevention 207
18.4 Control of Flue Gas NoX 210
18.5 Operation, Maintenance, Inspection, and Optimization Considerations 212
18.6 Conclusions 212
References 212
19 Carbon Capture and Storage 213
19.1 Properties of Carbon Dioxide 213
19.2 Global Carbon Cycle 214
19.3 The Greenhouse Effect 214
19.4 Effects of Global Warming/Climate Change 215
19.5 Carbon Dioxide Control Technologies 216
19.6 Carbon Dioxide Sequestration 217
19.7 Final Editorial Thoughts (of One of the Authors) 218
19.8 Final Editorial Thoughts (of the Other Author) 218
References 219
20 Flue Gas Desulfurization Systems 221
20.1 Description of Control Device 221
20.2 Design Procedures 223
20.3 Installation Procedures 227
20.4 Operation 227
20.5 Startup 230
20.6 Maintenance 230
20.7 Improving Operation and Performance 231
20.8 Conclusions 231
References 232
21 Biofiltration 233
21.1 Description of Control Device 234
21.2 Design Considerations 235
21.3 Operation and Maintenance 237
21.4 Improving Operation and Performance 237
21.5 Conclusions 238
References 239
22 Stacks 240
22.1 Description of Control Device 240
22.2 Design Considerations 241
22.3 Sulfuric Acid Attack 251
22.4 Inspection and Repair of Liners 255
22.5 Recent Advances 258
22.6 Conclusions 259
References 259
23 Ventilation 261
23.1 Introduction to Industrial Ventilation Systems 261
23.2 Dilution Ventilation 262
23.3 Local Exhaust Systems 263
23.4 Selecting Ventilation Systems 264
23.5 Ventilation Models 264
23.6 Model Limitations 265
References 266
Part III Epilogue 267
24 Atmospheric Dispersion 269
Sarah Forster
24.1 The Nature of Dispersion 269
24.2 Meteorological Concerns 270
24.3 Plume Rise 271
24.4 Effective Stack Height 272
24.5 The Pasquill-Gifford Model 273
24.6 Types of Emission Sources 274
24.7 Choosing A Model 274
24.8 Conclusions 275
References 276
25 Control Equipment Cost Considerations 277
25.1 Capital Costs 277
25.2 Operating Costs 278
25.3 Hidden Economic Factors 279
25.4 Project Evaluation 280
25.5 Future Trends 280
References 281
26 Measurement Methods 282
Vincenza Imperiale
26.1 Source Sampling 283
26.2 Sampling Guidelines 283
26.3 Continuous Emission Monitoring 286
26.4 Opacity Measurements 287
26.5 Sampling Statistical Analysis 288
26.6 Maintenance 289
26.7 Conclusions 289
References 290
27 Optimization Considerations 291
27.1 The History of Optimization 291
27.2 Optimization Overview 292
27.3 The Scope of Optimization 292
27.4 General Analytical Formulation of Optimization Problems 293
27.5 Optimizing Performance 294
27.6 Recent Developments 296
27.7 Conclusions 296
References 297
28 Factors in Pollution Control Equipment Selection 298
28.1 Environmental, Engineering, and Economic Factors 298
28.2 Comparing Control Equipment Alternatives 299
28.3 Equipment and Material Specifications 302
28.4 Instrumentation and Controls 303
28.5 Equipment Fabrication 304
28.6 Installation Procedures 304
28.7 Equipment Purchasing Guidelines 304
28.8 Future Trends 306
References 306
29 Control Equipment for Specific Industries 307
Emma Parente
29.1 Continue Techniques Applicable to Specific Sources 307
29.2 Control Techniques Applicable to Other Sources 313
Reference 313
Index 314
1
Definitions/Glossary of Terms
As noted in the Preface, this book is concerned with air pollution control equipment and as such, this chapter primarily addresses air pollution control equipment-related terms. It has been written not only for academic use in colleges, and universities but also for both engineers and scientists who work in the air pollution control equipment field. This glossary may be used whenever and wherever information is needed about words and/or terms in air pollution.
Some additional points deserve mentioning:
- Each definition avoids technical jargon.
- No mathematical equations - in any form - are employed in the definition. In some instances, where necessary, common scientific and engineering units have been included.
- Only keywords or terms used in practice are provided, as is the case in preparing a text, particularly a dictionary, the problems of what to include and what to omit have been particularly difficult.
- Only one spelling is used for words with multiple accepted spellings, e.g., modeling versus modeling.
- Some important acronyms are also included with a one-sentence definition.
- As with nearly every glossary, the terms have been alphabetized.
This chapter defines many - but not all - of the terms that the reader will encounter in this book. The following list is therefore not a complete glossary of all terms that appear in this field. It should also be noted that many of the terms have come to mean slightly different things to different people; this will become evident as one delves deeper into the literature.1-3
1.1 Glossary of Terms
- Absolute humidity.
- The amount of water vapor present in a unit mass of air, which is usually expressed in kg water vapor/kg dry air or lb water vapor/lb dry air.
- Absolute pressure.
- The actual pressure exerted on a surface that is measured relative to zero pressure; it equals the gauge pressure plus the atmospheric pressure.
- Absolute temperature.
- The temperature expressed in degrees of Kelvin or Rankine.
- Absorbate.
- A substance that is taken up and retained by an absorbent.
- Absorbent.
- Any substance that takes in or absorbs other substances.
- Absorber.
- A device in which a gas is absorbed by contact with a liquid.
- Absorption.
- The process in which one material (the absorbent) takes up and retains another (the absorbate) to form a homogeneous solution; it often involves the use of a liquid to remove certain gas components from a gaseous mixture.
- Actual cubic feet per minute (acfm).
- A unit of flow rate measured under actual pressure and temperature conditions.
- Acute (risk).
- Risks associated with short periods of time. For health risk, it usually represents short exposures to high concentrations of an agent.
- Adiabatic.
- A term used to describe a system in which no gain or loss of heat is allowed to occur.
- Adiabatic flame temperature.
- The maximum temperature that a combustion system can reach.
- Adiabatic lapse rate.
- The rate at which the temperature of a moving air parcel decreases in the atmosphere as height above the surface increases when no heat is added or subtracted from the moving air parcel; the adiabatic lapse rate is 10 °C/km.
- Adsorbent.
- A substance (e.g., activated carbon, activated alumina, silica gel) that has the ability to condense or hold molecules of other substances on its surface.
- Adsorber.
- An apparatus in which molecules of gas or liquid are retained on the surface of an adsorbent.
- Adsorption.
- The physical or chemical bonding of molecules of gas, liquid, or dissolved solid to the external or internal (if porous) surface of a solid (adsorbent); it is an advanced method of treating waste that is employed to remove odor, color, or organic matter from a system.
- Afterburner.
- A secondary burner is located so that combustion gases from the primary incinerator are further burned to remove smoke, odors, and other pollutants.
- Agent.
- A biological, physical, or chemical entity capable of causing disease or adverse health effects.
- Alpha (a) particle.
- A positively charged helium nucleus (i.e., two protons and two neutrons) that is emitted spontaneously from the decay of radioactive elements.
- Amines.
- Organic compound related to ammonia.
- Ammonia.
- An alkaline gas composed of hydrogen and nitrogen; it has a strong odor when present in high concentrations.
- Asphyxiant.
- A vapor or gas that has little or no positive toxic effect but that can bring about unconsciousness and death by replacing air and thus depriving an organism of oxygen.
- Aspirator.
- A hydraulic device that creates a negative pressure by forcing liquid through a restriction, thus increasing the velocity head.
- Atmosphere.
- The general volume of air above the earth; it is the lower portion of the atmosphere in which pollution must be controlled.
- Atmospheric dispersion.
- The mixing of a gas or vapor (usually from a discharge point) with air in the lower atmosphere. The mixing is the result of convective motion and turbulent eddies.
- Atmospheric stability.
- A measure of the degree of atmospheric turbulence, often defined in terms of the vertical temperature gradient in the lower atmosphere.
- Atomic fission.
- The breaking down of a large atom into smaller atoms or elements, involving the liberation of heat, gamma rays, alpha particles, and beta particles.
- Audit.
- The examination of something with the intent to check, verify, or inspect a particular subject matter.
- Auto-ignition temperature.
- The lowest temperature at which a flammable gas in the air will ignite without an ignition source.
- Auto-ignition.
- The starting of a fire without the addition of an external source such as a flame, spark, or heat.
- Average rate of death (ROD).
- The average number of fatalities that can be expected per unit time (usually on an annual basis) from all possible risks and/or incidents.
- Baffle.
- A flow-regulating device usually consisting of a plate placed horizontally across a pipe or channel to restrict or divert the passage of a fluid, usually used for the purpose of providing a uniformly dispersed flow.
- Ball joint.
- A flexible pipe joint formed in the shape of a ball or a sphere.
- Ball valve.
- A nonreturn valve consisting of a ball resting on a cylindrical seat within a fluid passageway or pipe.
- Barometric pressure.
- The pressure of the ambient air in the atmosphere at a particular point on or above the surface of the earth.
- Basic event.
- A fault tree event (FTE) that is sufficiently basic that no further explanation or development of additional events is necessary.
- Batch process.
- A process that is not continuous; its operations are carried out with discrete quantities of material added and removed from it at appropriate time intervals.
- Benzene.
- Aromatic hydrocarbon formerly used in paints and varnishes, but now considered toxic for this purpose.
- Beta (ß) particle.
- A charged particle emitted from a radioactive atomic nucleus; it has moderate penetrative power and is able to damage living tissue.
- Bias.
- The systematic distortion of data; it is the tendency of a sample to be unrepresentative of all the cases involved in a study.
- Bleeding.
- The gradual release of material and/or reduction of pressure from a system or process (e.g., by a valve or leak).
- Blowdown.
- The cyclic or constant removal of a portion of any process flow to maintain the constituents of the flow at a desired level.
- Blower.
- A fan employed to force or move air or gas under pressure.
- Brownian movement.
- The constant, random movement of small, suspended particles due to collisions with other molecules.
- Buffer.
- A solution containing both a weak acid and its conjugate weak base, which is employed to stabilize the pH value in a solution, and anything that acts to diminish and/or regulate changes in a system or process.
- Bulk sample.
- A small portion of material that is collected and sent to a laboratory for analysis.
- Bulk density.
- The mass per unit volume of a solid in a mixture such as a packed bed or soil mass; unlike the real solid particle density, the pore space is included in the volume for this calculation.
- Burning.
- The chemical combination of oxygen and a fuel such as carbon, hydrogen, hydrocarbon, or other substances that combine with oxygen.
- Butterfly damper.
- A plate or blade installed in a duct, flue, breeching, or stack that rotates on an axis to regulate the flow of gases.
- Butterfly valve.
- A flow control valve containing a disk supported by a shaft on which it rotates.
- Bypass.
- The avoiding...
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