
Automotive Fuels Reference Book
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Content
- Intro
- Contents
- Preface to Third Edition
- Preface to Second Edition
- Preface to First Edition
- Chapter 1 Automotive Fuels and Their Specification
- References
- Chapter 2 A History of Gasoline and Diesel Fuel Development
- 2.1 Gasoline
- 2.1.1 The Evolution of the Gasoline Engine
- 2.1.2 Gasoline Development
- 2.2 Diesel Fuel
- 2.2.1 The Evolution of the Diesel Engine
- 2.2.2 Diesel Fuel Development
- References
- Further Reading
- Chapter 3 Manufacture of Gasoline and Diesel Fuel from Crude Oil
- 3.1 Introduction
- 3.2 Crude Oil
- 3.3 Influence of Product Demand Pattern on Processing
- 3.4 Distillation
- 3.5 Cracking Processes
- 3.5.1 Thermal Cracking
- 3.5.2 Visbreaking
- 3.5.3 Coking
- 3.5.4 Catalytic Cracking
- 3.5.5 Hydrocracking
- 3.5.5.1 Catalytic Distillate Dewaxing
- 3.5.6 Steam Cracking
- 3.6 Catalytic Reforming
- 3.7 Alkylation, Isomerization, and Polymerization
- 3.7.1 Alkylation
- 3.7.2 Isomerization
- 3.7.3 Polymerization
- 3.8 Finishing Processes
- 3.8.1 Caustic Washing
- 3.8.2 Merox Treating
- 3.8.3 Hydrodesulfurization
- 3.8.3.1 Sources of Hydrogen
- 3.9 Oxygenated Gasoline Components
- 3.9.1 Alcohols
- 3.9.2 Ethers
- 3.10 Gasoline Blending
- 3.10.1 Blending Operations
- 3.10.2 Blending Calculations
- 3.10.3 Octane Blending
- 3.10.4 Reid Vapor Pressure (RVP) Blending
- 3.10.5 ASTM Distillation Blending
- 3.11 Diesel Fuel Blending
- 3.11.1 Diesel Blending Operations
- 3.11.2 Diesel Blend Calculations
- References
- Further Reading
- Chapter 4 Manufacture of Gasoline and Diesel Fuel from Non-Crude Oil Fossil Sources
- 4.1 Introduction
- 4.2 Coal
- 4.2.1 Syn-Gas Production
- 4.2.2 F-T Synthesis
- 4.2.3 Product Upgrading
- 4.2.3.1 Hydrocracking
- 4.2.3.2 Oligomerization
- 4.2.3.3 Catalytic Reforming
- 4.2.3.4 Alcohol Dehydration
- 4.3 Gas to Liquids
- 4.4 Gaseous Fuels
- 4.4.1 Gaseous Fuel Supply
- 4.4.2 Gaseous Fuel Composition and Properties
- 4.4.2.1 Gaseous Fuel Components
- 4.4.2.2 Wobbe Index and Fuel Metering
- 4.4.2.3 Propensity to Knock: Octane and Methane Numbers
- 4.4.2.4 Effect of Gaseous Fuel Composition on Emissions
- 4.4.3 Gaseous Fuels Dispensing and Storage
- 4.4.3.1 Compressed Natural Gas (CNG)
- 4.4.3.2 Recommended Practice for CNG: SAE J1616
- 4.4.3.3 LNG Dispensing and Storage
- 4.4.3.4 LPG Dispensing and Storage
- 4.4.4 Gaseous-Fuel Engine Technology
- 4.4.4.1 Fuel Metering Systems
- 4.4.4.2 Spark-Ignition Engines
- 4.4.4.3 Dual-Fuel (Compression Ignition) Engines
- 4.5 Oil Sands Fuel
- 4.5.1 Oil Sands Extraction and Processing
- 4.5.1.1 Surface Mining
- 4.5.1.2 Subterranean Recovery
- 4.5.1.3 In Situ Processing
- 4.6 Oil Shale Fuel
- 4.6.1 Oil Shale Mining and Processing
- 4.6.2 In Situ Retorting
- References
- Further Reading
- Chapter 5 Manufacture of Gasoline and Diesel Fuel from Renewable Sources
- 5.1 Introduction
- 5.2 Minimally Processed Vegetable Oil
- 5.3 Bio-Ethanol
- 5.3.1 Ethanol from Sugar Crops
- 5.3.2 Ethanol from Grain Crops
- 5.3.3 Lignocellulosic Ethanol
- 5.4 Biodiesel Fuel
- 5.5 Hydrotreated Vegetable Oil
- References
- Further Reading
- Chapter 6 Storage, Distribution, and Handling of Gasoline and Diesel Fuel
- 6.1 Introduction
- 6.2 Safety Considerations for Storage and Handling
- 6.2.1 Flash Point
- 6.2.2 Electrical Conductivity
- 6.3 Health and Environmental Effects of Gasoline
- 6.3.1 Health Aspects
- 6.3.1.1 Inhalation
- 6.3.1.2 Ingestion
- 6.3.1.3 Aspiration
- 6.3.1.4 Skin Contact
- 6.3.1.5 Eye Contact
- 6.3.2 Exposure Limits
- 6.3.3 Ecotoxicity
- 6.3.4 Disposal
- 6.4 Health and Environmental Effects of Diesel Fuel
- 6.4.1 Health Aspects
- 6.4.1.1 Inhalation
- 6.4.1.2 Ingestion
- 6.4.1.3 Aspiration
- 6.4.1.4 Skin Contact
- 6.4.1.5 Eye Contact
- 6.4.2 Exposure Limits
- 6.4.3 Ecotoxicity
- 6.4.4 Disposal
- 6.5 Influences on Product Quality during Distribution
- 6.5.1 Sea Transport
- 6.5.2 Pipeline
- 6.5.3 Road and Rail
- 6.6 Influences on Product Quality during Storage
- 6.6.1 Water Contamination in Tankage
- 6.6.2 Microbiological Contamination
- 6.6.3 Sludge in Tankage
- 6.6.4 Evaporative Losses
- 6.6.5 Oxidation
- 6.7 Considerations with Oxygenated Blends
- 6.7.1 Environmental Aspects of Fuels Containing MTBE
- 6.7.2 Water Sensitivity of Alcohol Blends
- 6.7.3 Safety and Fire Protection for Alcohol Blends
- 6.7.4 Oxidation Stability of Biodiesel
- 6.7.5 Cold Stability of Biodiesel
- References
- Further Reading
- Chapter 7 Positive Ignition Engine Combustion Process
- 7.1 Normal Combustion
- 7.1.1 Mixture Requirements
- 7.1.2 The Combustion Process
- 7.2 Spark Knock
- 7.2.1 How Spark Knock Occurs
- 7.3 Measurement of Gasoline Antiknock Quality
- 7.3.1 Research and Motor Octane Number
- 7.3.2 Road Octane Number
- 7.3.3 Octane Index and Modern Engines
- 7.3.4 Influence of Chemical Structure on Octane Quality
- 7.4 Antiknock Additives
- 7.4.1 Lead Alkyls
- 7.4.2 MMT-Methylcyclopentadienyl Manganese Tricarbonyl
- 7.4.3 Other Metallic Antiknocks
- 7.4.4 Organic Antiknocks
- 7.4.5 Oxygenated Blending Components
- 7.5 Octane Blending
- 7.6 Octane Requirements of Vehicles and Engines
- 7.6.1 Vehicles with Knock Sensor Systems
- 7.6.2 Data Analysis
- 7.6.3 Octane Rating of Fuels Using Vehicles or Engines
- 7.6.4 Engine and Other Factors That Influence Octane Requirements
- 7.7 Octane Requirement Increase (ORI)
- 7.8 Other Abnormal Combustion Phenomena
- 7.8.1 Pre-Ignition
- 7.8.1.1 Fuel Quality Effects on Pre-Ignition
- 7.8.1.2 Deposits and Pre-Ignition
- 7.8.1.3 Inherent Fuel Resistance to Pre-Ignition
- 7.8.2 Misfire
- 7.8.3 Run-On
- References
- Further Reading
- Chapter 8 Gasoline Engine Design and Influence of Fuel Characteristics
- 8.1 Introduction
- 8.2 The Gasoline Engine
- 8.2.1 Otto Cycle
- 8.2.2 The Atkinson Cycle
- 8.2.3 The Miller Cycle
- 8.3 Vehicle Fuel Systems
- 8.3.1 The Fuel Metering System
- 8.3.1.1 Carburetors
- 8.3.1.2 Throttle Body Fuel Injection
- 8.3.1.3 Port Fuel Injection
- 8.3.1.4 Direct Fuel Injection
- 8.3.1.4.1 Direct Injection Strategies
- 8.3.1.4.2 Direct Injection Injector Technology
- 8.3.2 The Fuel Tank and Pump
- 8.4 Ignition Systems
- 8.5 Combustion and Exhaust Emission Control Systems
- 8.5.1 Combustion Chamber Configuration
- 8.5.1.1 Combustion Chamber Shape
- 8.5.1.2 Valve Layouts
- 8.5.2 The Effect of Air-to-Fuel Ratio
- 8.5.3 Exhaust Aftertreatment Systems
- 8.5.3.1 Oxidation Catalysts
- 8.5.3.2 Three-Way Catalysts
- 8.5.3.3 Lean NOX Traps
- 8.5.3.4 Particulate Filters
- References
- Further Reading
- Chapter 9 Gasoline Volatility
- 9.1 Measurement of Gasoline Volatility
- 9.1.1 Vapor Pressure
- 9.1.2 Reid Vapor Pressure
- 9.1.3 Dry Vapor Pressure and DVPE
- 9.1.4 Distillation by ASTM D86
- 9.1.5 Vapor-Liquid Ratio
- 9.1.6 Effect of Oxygenated Blending Components
- 9.2 Cold Starting
- 9.2.1 Different Fuel System Technologies
- 9.2.1.1 Carbureted Engines
- 9.2.1.2 Port Fuel Injected Engines
- 9.2.1.3 Direct Injection Engines
- 9.2.2 Relevant Specifications
- 9.3 Cold Weather Driveability
- 9.3.1 Cold Weather Driveability Test Procedures
- 9.3.1.1 U.S. Test Procedures
- 9.3.1.2 European Procedures
- 9.3.2 Relevant Fuel Parameters
- 9.3.2.1 U.S. Driveability Index
- 9.3.2.2 European and Japanese Indices
- 9.4 Hot Weather Driveability
- 9.4.1 Hot Weather Driveability Testing
- 9.4.2 Hot Weather Driveability Problems
- 9.4.2.1 Fuel Weathering
- 9.4.2.2 Vapor Lock
- 9.4.2.3 Carburetor Percolation
- 9.4.2.4 Carburetor Foaming
- 9.4.3 Hot Weather Fuel Parameter Specification
- 9.5 Evaporative Emissions from Vehicles
- 9.5.1 Measuring Evaporative Emissions
- 9.5.2 Reducing Evaporative Emissions
- 9.6 Influence of Fuel Volatility on Exhaust Emissions
- 9.7 Intake System Icing
- 9.7.1 Throttle Icing in Carbureted and Throttle Body Injected Engines
- 9.7.2 Throttle Icing in Multipoint Fuel Injected Engines
- 9.8 Oil Dilution and Combustion Chamber Deposits
- 9.9 Fuel Economy and Gasoline Volatility
- References
- Further Reading
- Chapter 10 Influence of Gasoline Composition on Stability, Gum Formation, and Engine Deposits
- 10.1 The Influence of Gasoline Composition on Stability
- 10.1.1 Measurement of Stability
- 10.1.1.1 Measurement of Oxidation Stability by Induction Period Method
- 10.1.1.2 Automated Measurement of Induction Period
- 10.1.1.3 Measurement of Gum Content by Jet Evaporation
- 10.1.1.4 Measurement of Oxidation Stability by Potential Residue Method
- 10.1.1.5 Measurement of Long-Term Stability
- 10.2 Deposit Formation in Engines Due to Gasoline Oxidation
- 10.2.1 Deposit Formation in the Fuel Tank and Fuel Lines
- 10.2.2 Deposit Formation in Fuel Injectors and Carburetors
- 10.2.2.1 Chrysler 2.2
- 10.2.2.2 Other Vehicle-Based Injector Deposit Test
- 10.2.2.3 CRC Injector Deposit Bench Test
- 10.2.3 Deposit Formation in the Inlet Manifold, Ports, and on Valves
- 10.2.3.1 Opel Kadett Test
- 10.2.3.2 Mercedes-Benz M102E Test
- 10.2.3.3 BMW 318i Test
- 10.2.3.4 Mercedes-Benz M111 Test
- 10.2.3.5 Ford 2.3 Test
- 10.2.3.6 Other Engine Tests
- 10.2.3.7 Bench Simulator Rigs
- 10.2.3.8 Valve Stick Test
- 10.2.4 Combustion Chamber Deposits
- 10.2.4.1 Deposit Formation in Direct Injection Gasoline Engines
- 10.2.4.1.1 Direct Injection Injector Deposits
- 10.2.4.1.2 Direct Injection Chamber Deposits
- 10.2.4.2 Combustion Chamber Deposit Interference
- References
- Chapter 11 Gasoline Additives
- 11.1 Additives to Improve Oxidation Stability
- 11.1.1 Antioxidants
- 11.1.2 Metal Deactivators
- 11.2 Additives Used in Gasoline Distribution
- 11.2.1 Dyes and Markers
- 11.2.2 Corrosion Inhibitors
- 11.2.3 Biocides
- 11.2.4 Anti-Static Additives
- 11.2.5 Drag Reducing Agents
- 11.2.6 Demulsifiers and Dehazers
- 11.3 Additives Used to Protect Engines and Fuel Systems
- 11.3.1 Corrosion Inhibitors
- 11.3.2 Anti-icing Additives
- 11.3.3 Deposit Control Additives (DCAs)
- 11.3.3.1 Carburetor Cleanliness Additives
- 11.3.3.2 Port Fuel Injector Anti-Fouling Additives
- 11.3.3.3 Additives to Control Inlet Manifold, Inlet Valve, and Port Deposits
- 11.3.3.4 Additives for Direct Injection Injector Cleanliness
- 11.3.3.5 Combustion Chamber Deposit Control
- 11.3.4 Factory Fill Additives
- 11.4 Additives That Influence Combustion
- 11.4.1 Antiknock Additives
- 11.4.2 Anti-ORI Additives
- 11.4.3 Anti-Pre-Ignition and Anti-Misfire Additives
- 11.4.4 Spark-Aider Additives
- 11.4.5 Additives for Improving Fuel Distribution between Cylinders
- 11.4.6 Anti-Valve-Seat Recession Additives
- 11.5 Additives That Improve Lubricant Performance
- 11.5.1 Upper Cylinder Lubricants
- 11.5.2 Anti-Wear Additives
- 11.5.3 Friction Modifiers
- 11.5.4 Anti-Sludge Additives
- 11.6 Multi-Functional Additive Packages
- References
- Chapter 12 Other Gasoline Specification and Non-Specification Properties
- 12.1 Density
- 12.2 Heat of Combustion
- 12.3 Composition
- 12.3.1 Hydrocarbon Composition
- 12.3.2 Elemental Composition
- 12.3.2.1 Lead
- 12.3.2.2 Manganese
- 12.3.2.3 Phosphorus
- 12.3.2.4 Sulfur
- 12.3.3 Oxygenates
- 12.3.4 Water
- 12.4 Flash Point
- 12.5 Surface Tension
- 12.6 Viscosity
- 12.7 Conductivity
- 12.8 Corrosivity
- 12.9 Freezing Point
- 12.10 Appearance
- References
- Chapter 13 Influence of Gasoline Characteristics on Emissions
- 13.1 Development of Emissions Legislation and Fuel Quality Regulations
- 13.1.1 Development in the United States
- 13.1.2 Development in Europe
- 13.1.3 Development in Japan
- 13.1.4 Development in the Rest of the World
- 13.2 The Introduction of Reformulated Gasolines
- 13.2.1 The Adoption of RFG in the United States
- 13.2.2 RFG Specifications
- 13.2.3 European Experience of RFGs
- 13.2.4 The Fuel and Emissions Relationship Going Forward
- 13.3 The Influence of Gasoline Sulfur Content on Emissions
- 13.3.1 The Effect of Sulfur on Tail-Pipe Emissions
- 13.3.2 The Effect of Sulfur on Durability of Aftertreatment Systems
- 13.3.3 The Effect of Sulfur on Onboard Diagnostics
- 13.4 The Influence of Gasoline Hydrocarbon Composition on Emissions
- 13.4.1 Aromatics
- 13.4.1.1 Aromatics and Regulated Exhaust Emissions
- 13.4.1.2 Aromatics and Air Toxins
- 13.4.2 Olefins
- 13.5 The Influence of Gasoline Distillation Characteristics on Emissions
- 13.5.1 Front-End Volatility
- 13.5.2 Mid-Range Volatility
- 13.5.3 Back-End Volatility
- References
- Further Reading
- Chapter 14 Racing Fuels
- 14.1 General Considerations
- 14.1.1 Safety
- 14.1.2 Volatility
- 14.1.3 Resistance to Detonation and Pre-Ignition
- 14.1.4 Flammability Limits
- 14.1.5 Flame Speed
- 14.1.6 Heat of Vaporization
- 14.1.7 Density
- 14.1.8 Heating Value
- 14.1.9 Stoichiometry
- 14.1.10 Specific Energy
- 14.2 Hydrocarbon Racing Fuels
- 14.2.1 Historical Perspective
- 14.2.2 Current Perspective
- 14.3 Alcohols as Racing Fuels
- 14.4 Antiknock Components
- 14.5 Nitro-Paraffins as Racing Fuels
- 14.6 Fuel Additives
- 14.6.1 Hydrazine
- 14.6.2 Antiknock Additives
- 14.6.3 Stabilizers
- 14.6.4 Deposit Control Additives
- 14.6.5 Dyes and Markers
- 14.6.6 Static Dissipaters
- 14.7 Nitrous Oxide as an Oxidant for Racing Fuels
- References
- Chapter 15 The Diesel Engine Combustion Process
- 15.1 The Diesel Combustion Process
- 15.1.1 Ignition Delay Period
- 15.1.2 Pre-Mixed Burning Period
- 15.1.3 Diffusion Burning Period
- 15.1.4 Tail-End Burning Period
- 15.2 Fuel Properties Influencing Combustion
- 15.2.1 Ignition Quality
- 15.2.1.1 Measurement of Cetane Number
- 15.2.1.2 Measurement of Derived Cetane Number
- 15.2.1.3 Measurement of Cetane Index
- 15.3 Emissions Characteristics of Diesel Combustion
- 15.3.1 Smoke and Particulates
- 15.3.2 Oxides of Nitrogen
- References
- Further Reading
- Chapter 16 Diesel Engine Design and Influence of Fuel Characteristics
- 16.1 Introduction
- 16.2 The Diesel Compression Ignition Engine
- 16.2.1 Direct Injection
- 16.2.2 Indirect Injection
- 16.2.3 Other Considerations
- 16.3 Diesel Vehicle Fuel Systems
- 16.3.1 Strainers, Filters, and Separators
- 16.3.2 Transfer or Lift Pumps
- 16.3.3 Injection Systems
- 16.3.3.1 Pump-Line-Nozzle Systems
- 16.3.3.1.1 In-Line Pumps
- 16.3.3.1.2 Rotary Distributor Pumps
- 16.3.3.1.3 Electronic Control
- 16.3.3.2 Unit Injector Systems
- 16.3.3.3 High-Pressure Common Rail Systems
- 16.4 Exhaust Aftertreatment
- 16.4.1 Diesel Oxidation Catalysts
- 16.4.2 Diesel Particulate Filters
- 16.4.2.1 Deep Bed Filters
- 16.4.2.2 Wall Flow Filters
- 16.4.2.3 Partial Filtration
- 16.4.2.4 DPF Regeneration
- 16.4.3 NOX Reduction Systems
- 16.4.3.1 Selective Catalytic Reduction
- 16.4.3.2 Hydrocarbon-Based NOX Reduction
- 16.4.4 Integrated Systems
- 16.5 Influence of Fuel Properties on Engine Systems Performance
- 16.5.1 Influence of Fuel Density
- 16.5.2 Influence of Diesel Fuel Volatility
- 16.5.3 Influence of Diesel Fuel Viscosity
- 16.5.4 Influence of Diesel Fuel Composition
- References
- Further Reading
- Chapter 17 Diesel Fuel Low-Temperature Characteristics
- 17.1 Diesel Fuel Low-Temperature Properties
- 17.1.1 Cloud Point
- 17.1.2 Wax Appearance Point
- 17.1.3 Pour Point
- 17.1.4 Significance of Cloud Point and Pour Point
- 17.1.5 Cold Filter Plugging Point
- 17.1.6 Low-Temperature Flow Test
- 17.1.7 Simulated Filter Plugging Point (SFPP)
- 17.1.8 Cold Soak Filtration Test
- 17.2 Additives to Improve Cold Weather Performance
- 17.2.1 Wax Crystal Modifiers (WCM)
- 17.2.2 Pour Point Depressants
- 17.2.3 Flow Improvers
- 17.2.4 Cloud Point Depressants
- 17.2.5 Wax Anti-Settling Additives (WASA)
- 17.2.6 Mechanism of Wax Crystal Modification
- 17.2.7 Factors Influencing Choice of Wax Modifier Additive
- 17.2.8 The Incorporation of Biodiesel
- 17.3 Measurement of Diesel Fuel Low-Temperature Performance
- 17.3.1 Selection of Field Test Site
- 17.3.2 Procedure for Low-Temperature Testing
- 17.3.2.1 Cold Startability
- 17.3.2.2 Cold Operability
- 17.3.3 Fuel Storage
- 17.3.4 Vehicle Instrumentation
- 17.3.5 Preparation of Test Vehicles
- 17.3.6 Operational Procedure
- 17.3.7 Climate Chamber Testing
- 17.3.8 Interpretation of Results
- 17.3.9 Low-Temperature Test Experience
- 17.3.10 Reducing Sensitivity to Waxing Problems by Vehicle Design
- 17.3.11 Experience with Modified Fuel Systems
- References
- Chapter 18 Influence of Diesel Fuel Composition on Stability and Engine Deposits
- 18.1 The Influence of Diesel Fuel Composition on Stability
- 18.1.1 Petroleum Fuel Composition Effects
- 18.1.2 Biodiesel Composition Effects
- 18.1.3 Measurement of Stability
- 18.1.3.1 Measurement of Storage Stability
- 18.1.3.2 Measurement of Thermal Stability
- 18.1.3.3 Measurement of Oxidation Stability
- 18.2 Engine Deposits
- 18.2.1 Deposit Formation in the Fuel Tank, Lines, and Filters
- 18.2.2 Internal Diesel Injector Deposits (IDID)
- 18.2.2.1 Carbonaceous Deposits
- 18.2.2.2 Metal Salts
- 18.2.2.3 Lacquer Deposits
- 18.2.2.4 IDID Test Methods
- 18.2.2.4.1 CRC Test Development
- 18.2.2.4.2 CEC Test Development
- 18.2.3 External Injectors Deposits
- 18.2.3.1 Peugeot XUD-9 Test Method
- 18.2.3.2 Cummins L10 Test Method
- 18.2.3.3 Peugeot XUD-9A Test Method
- 18.2.3.4 Peugeot DW10 Test Method
- References
- Chapter 19 Diesel Fuel Additives
- 19.1 Additives to Improve Fuel Stability
- 19.2 Additives Used to Aid Distribution and Handling of Diesel Fuel
- 19.2.1 Additives to Aid Cold Flow Performance
- 19.2.2 Corrosion Inhibitors
- 19.2.3 Static Dissipater Additives
- 19.2.4 Dehazers and Demulsifiers
- 19.2.5 Biocides
- 19.2.6 Anti-Foamants
- 19.2.7 Odor Masks and Odorants
- 19.2.8 Dyes and Markers
- 19.2.9 Drag Reducers
- 19.2.10 Anti-Icers
- 19.3 Additives Used to Protect Engines and Fuel Systems
- 19.3.1 Deposit Control Additives
- 19.3.2 Lubricity Additives
- 19.4 Additives That Influence Combustion
- 19.4.1 Ignition Improvers
- 19.4.2 Combustion Improvers
- 19.4.3 FBCs for DPF Regeneration
- 19.5 Multi-Functional Additive Packages
- References
- Chapter 20 Other Diesel Specification and Non-Specification Properties
- 20.1 Diesel Fuel Stability
- 20.2 Corrosivity
- 20.3 Ignition Quality
- 20.4 Lubricity
- 20.4.1 Evaluation of Different Test Methods
- 20.4.2 Ball on Three Seats Method (BOTS)
- 20.4.3 Ball-On-Cylinder Lubricity Evaluator (BOCLE)
- 20.4.4 High-Frequency Reciprocating Rig (HFRR)
- 20.5 Water and Sediment Content
- 20.6 Ash Content
- 20.7 Carbon Residue
- 20.8 Density
- 20.9 Heating Value
- 20.10 Flash Point
- 20.11 Electrical Conductivity
- 20.12 Appearance and Color
- References
- Chapter 21 Influence of Diesel Fuel Characteristics on Emissions
- 21.1 Development of Emissions Legislation and Fuel Quality Regulations
- 21.1.1 Development in the United States
- 21.1.1.1 California Risk Reduction Program for Diesel PM
- 21.1.2 Development in Europe
- 21.1.2.1 Measurement of PN
- 21.1.3 Development in Japan
- 21.1.4 Development in the Rest of the World
- 21.2 Diesel Fuel Cetane Number and Emissions
- 21.2.1 Effect of CN under Fully Warm Operating Conditions
- 21.2.1.1 Pre-1990 Studies
- 21.2.1.2 Studies During the 1990s
- 21.2.1.3 Studies in the 21st Century
- 21.2.2 Effect of CN under Cold Start Condition
- 21.2.3 Natural and Improved CN
- 21.3 The Influence of Diesel Fuel Physical Characteristics on Emissions
- 21.3.1 Diesel Fuel Density Effects
- 21.3.1.1 Density Emissions Correlations
- 21.3.1.2 The Influence of Fuel Density on Emission Control Systems
- 21.3.2 The Influence of Viscosity
- 21.3.3 Diesel Fuel Distillation Characteristics and Emissions
- 21.4 The Influence of Chemical Composition of Diesel Fuel on Emissions
- 21.4.1 Diesel Fuel Sulfur Effects on Emissions
- 21.4.1.1 The Effects of Fuel Sulfur on Tailpipe Emissions
- 21.4.1.2 Effect of Sulfur on Diesel Aftertreatment Systems
- 21.4.2 The Influence of Aromatic Content on Emissions
- 21.4.2.1 Effect of Total Aromatics Content on Emissions
- 21.4.2.2 Effect of Fuel Di-and Tri-Aromatic Content on Emissions
- 21.4.3 The Influence of Oxygenate Content on Emissions
- 21.4.3.1 The Influence of Biodiesel on Exhaust Aftertreatment Systems
- References
- Further Reading
- Chapter 22 The Kinetically Controlled Compression Ignition Engine and Combustion Process
- 22.1 Brief History of Kinetically Controlled Combustion
- 22.2 The Low-Temperature Combustion Process
- 22.3 Low-Temperature Combustion Engines
- 22.3.1 The CAI Gasoline Engine
- 22.3.2 The PCCI Diesel Engine
- 22.3.3 The RCCI Engine
- 22.4 Fuel Effects on Kinetically Controlled Compression Ignition
- 22.4.1 Fuel Effects on CAI Engine Performance
- 22.4.2 Fuel Effects on PCCI Engine Performance
- 22.4.3 Fuel Effects on RCCI Engine Performance
- References
- Further Reading
- Chapter 23 Future Trends and Alternative Fuels
- 23.1 Fossil Fuel Price and Security of Supply
- 23.1.1 Crude Oil
- 23.1.2 Other Oil Sources
- 23.1.3 Coal
- 23.1.4 Natural Gas
- 23.2 Renewable Fuel Price and Availability
- 23.2.1 Bio-Ethanol Feedstocks
- 23.2.2 Biodiesel Feedstocks
- 23.3 Environmental Considerations and Legislation
- 23.4 Vehicle Technology Advances
- 23.4.1 Gasoline Engine Development
- 23.4.2 Diesel Engine Development
- 23.4.3 Hybrid Electric Vehicles
- 23.4.4 Hydrogen-Powered Vehicles
- 23.4.4.1 Hydrogen as a Fuel for Spark Ignition Engines
- 23.4.4.2 Hydrogen Fuel Cell Vehicles
- 23.5 Alternative Fuels
- 23.5.1 Dimethyl Ether as a Fuel for Diesel Engines
- 23.5.2 Other Alternative Fuels
- References
- Further Reading
- Appendix 1 Introduction to Fuel Chemistry
- 1.1 Hydrocarbons
- 1.2 The Alkanes or Paraffins, CnH2n+2
- 1.3 The Cycloparaffins or Naphthenes, CnH2n
- 1.4 The Alkenes or Olefins, CnH2n
- 1.5 The Aromatic Hydrocarbons, CnH2n-6
- 1.6 Combustion of Hydrocarbons
- 1.7 Monohydric Alcohols, CnH2n+1OH
- 1.8 Alkyl Ethers, (CnH2n+1)2O
- 1.9 Combustion of Oxygenates
- Appendix 2 Physical Properties of Hydrocarbons
- Appendix 3 Worldwide Fuel Charter Recommendations
- Test methods for gasoline properties
- Gasoline specifications-recommended limits
- Test methods for diesel fuel properties
- Diesel fuel specifications-recommended limits
- Appendix 4 Composition of Biodiesel from Different Feedstocks
- Appendix 5 Material Safety Data Sheets
- Appendix 6 Abbreviations and Acronyms
- Appendix 7 Glossary of Terms
- Index
- About the Author
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