Diffusion-Limited Reactions

Name: Diffusion-Limited Reactions
Brand: Elsevier
Price: 54.95 EUR
Availability: OnlineOnly

S. a. Rice(Author)

Stephen A. Rice(Editor)

Elsevier (Publisher)

Published on 1. March 1985

404 pages

E-Book

PDF with digital watermarking

System requirements

978-0-08-086819-6 (ISBN)

€54.95incl. 7% vat

System requirements

for PDF with digital watermarking

E-Book Single Licence

Available for download

Description

More details

Other editions

Content

Front Cover
Diffusion-limited Reactions, Volume 25
Copyright Page
Contents
Preface
Chapter 1. Introduction
Chapter 2. Diffusion-controlled reactions in solution
1. Introduction
2. Evidence that some reactions are diffusion-controlled
3. The smoluchowski theory
4. The incorporation of chemical reaction rates into the diffusion model
5. A comparison of Experimental results with the smoluchowski theory
6. Complications to the dimple diffusion model
Chapter 3. Reactions between Ions in solution
1. Theoretical considerations for Ionic reactions in solutions
2. Experimental studies of Ionic reactions in solution
Chapter 4. Long-range transfer effects and diffusion-controlled reactions
1. General theoretical considerations
2. The dipole-dipole interaction
3. The exchange effect
4. Electron tunnelling
5. Conclusions
Chapter 5. Rotational diffusion effects
1. Introduction
2. Theoretical aspects of rotational relaxation
3. Experimental studies of rotational relaxation
4. Simultaneous rotational and translational diffusion
Chapter 6. The escape probability of an isolated pair
1. Introduction
2. Geminate radical recombination. Theory
3. Experimental studies of radical and molecular recombination
4. The effect of a magnetic field on radical pair recombination
Chapter 7. Geminate ion-pair recombination
1. Introduction
2. Theory of recombination of ion-pairs
3. Experimental studies of geminate ion-pair recombination
4. Spurs produced by high-energy radiation
Chapter 8. A critique of the diffusion equation and molecular pair treatments
1. Introduction
2. Diffusion equation analysis
3. Molecular pair analysis
4. Conclusions, for future work
Chapter 9. Refinements to the diffusion equation analysis to include many-body effects
1. Introduction
2. The diffusion of an isolated pair
3. Hydrodynamic repulsion and the diffusion equation
4. The wilemski and fixman theory of fluorescence quenching
5. Competitive effects in reactions
6. The density and survival probability of radicals and ions in clusters
Chapter 10. The variational principle
1. Introduction
2. The lagrangian density
3. Rate coefficients from the variational principle
4. Diffusion on a cubic lattice of sinks
5. Further estimates of the rate coefficient
6. Conclusions
Chapter 11. Phenomenological brownian motion
1. Introduction
2. The velocity autocorrelation function
3 . From the Langevin equation to the diffusion equation
4. The generalised langevin equation and chemical reactions
5. Computer simulations
Chapter 12. The kinetic theory applied to chemical reactions in solutions
1. Introduction
2. The kinetic theory of fluids
3. The rate of a chemical reaction from the kinetic theory of fluids
4. Extensions to the Kinetic Theory
Appendix a second-order partial differential equations and Green's functions
1. Dirac delta functions
2. Inhomogeneous second-order (partial) differential equations
3. The green's theorem and function
4. The green's Function for the debye-smoluchowski equation
5. Green's theorem and the variation of parameters
6. Causality
7. Reciprocity
Appendix B. The relationship Between the Lifetime distribution and the diffusion equation
1. The lifetime distribution
2. The average scavenging probability
3. Averaging over the initial distribution
4. Towards the diffusion equation analysis
Appendix C. The molecular pair approach
Appendix D. The general equation of reaction kinetics
Acknowledgements
References
Index

System requirements

Save as PDF Copy link into clipboard

Schweitzer Fachinformationen

Diffusion-Limited Reactions

Description

More details

Other editions

Additional editions

Content

System requirements