
Wide Bandgap Semiconductor-Based Electronics
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Advances in wide bandgap semiconductor materials are enabling the development of a new generation of power semiconductor devices that far exceed the performance of silicon-based devices. These technologies offer potential breakthrough performance for a wide range of applications, including high-power and RF electronics, deep-UV optoelectronics, quantum information and extreme-environment applications.
This reference text provides comprehensive coverage of the challenges and latest research in wide and ultra-wide bandgap semiconductors. Leading researchers from around the world provide reviews on the latest development of materials and devices in these systems, including gallium nitride and silicon carbide electronics, gallium oxide, boron nitride, aluminium gallium nitride, zinc oxide, diamond-based electronics and UV emitters.
The book is an essential reference for researchers and practitioners in the field of wide bandgap semiconductors and power electronics, and valuable supplementary reading for advanced courses in these areas.
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Persons
Fan Ren is a distinguished professor in the Department of Chemical Engineering at the University of Florida. He is a fellow of the American Physical Society, Electrochemical Society, Materials Research Society, Society of Photographic Instrumentation Engineers and American Vacuum Society. He won a Teacher and Scholar Award from the University of Florida in 2014 and the Gordon E Moore Medal for Outstanding Achievement in Solid State Science and Technology from the Electrochemical Society in 2013.
Stephen J Pearton is a distinguished professor in the Department of Materials Science and Engineering at the University of Florida. Pearton is a fellow of the International Society for Optics and Photonics, American Physical Society, Materials Research Society, American Vacuum Society, IEEE, Electrochemical Society and TMS. He has won awards from the Electrochemical Society, American Vacuum Society, American Physical Society, IEEE and TMS.
Content
- Intro
- Preface
- References
- Acknowledgements
- Editor biography
- Fan Ren
- S J Pearton
- Contributor list
- Chapter 1 Low-dimensional ß-Ga2O3 semiconductor devices
- 1.1 Introduction
- 1.1.1 Preparation of low-dimensional Ga2O3 nanostructures
- 1.1.2 Contact properties of ß-Ga2O3 nanodevices
- 1.1.3 The ohmic contacts of ß-Ga2O3 nanobelt devices
- 1.1.4 ß-Ga2O3 nanobelt Schottky contacts
- 1.2 ß-Ga2O3-based nanoelectronic devices
- 1.2.1 Single ß-Ga2O3 nanobelt-based field-effect transistors
- 1.2.2 ß-Ga2O3 nanobelt-based heterostructured transistors
- 1.2.3 ß-Ga2O3 nanobelt-based Schottky barrier diode
- 1.3 Conclusion
- References
- Chapter 2 ß-Ga2O3 power field-effect transistors
- 2.1 Introduction
- 2.2 Key parameters of a ß-Ga2O3 power field-effect transistor
- 2.3 Planar depletion-mode transistors
- 2.4 Planar enhancement-mode transistors
- 2.5 Vertical depletion-mode transistors
- 2.6 Vertical enhancement-mode transistors
- 2.7 Homojunction HEMT
- 2.8 Heterojunction HEMT
- 2.9 Nanomembrane transistors
- 2.10 Conclusion
- References
- Chapter 3 Beta gallium oxide (ß-Ga2O3) nanomechanical transducers: fundamentals, devices, and applications
- 3.1 Introduction
- 3.2 ß-Ga2O3 circular drumhead resonators
- 3.3 Resonant solar-blind ultraviolet (SBUV) transducers
- 3.3.1 Resonator
- 3.3.2 Oscillator
- 3.3.3 Dual-modality transducer
- 3.4 Conclusions and future perspectives
- References
- Chapter 4 Epitaxial growth of monoclinic gallium oxide using molecular beam epitaxy
- 4.1 The properties of Ga2O3
- 4.1.1 Polymorphs
- 4.1.2 Crystal structure, electronics, and thermal properties of ß-Ga2O3
- 4.1.3 Optical properties of MBE-grown ß-Ga2O3
- 4.2 Molecular beam epitaxy
- 4.3 Growth modes
- 4.4 Epitaxial growth of ß-Ga2O3 thin films by MBE
- 4.4.1 Growth of ß-Ga2O3 from an elemental Ga source using PAMBE
- 4.4.2 Growth of ß-Ga2O3 using a Ga2O3 compound source
- 4.4.3 Growth of ß-Ga2O3 using ozone-MBE
- 4.5 Investigation of deep level defects and traps in MBE-grown ß-Ga2O3
- 4.6 The status of dopants in MBE-grown ß-Ga2O3
- 4.7 ß-(AlxGa1-x)2O3/Ga2O3 heterostructures and superlattices
- 4.8 Summary
- References
- Chapter 5 Defects and carrier lifetimes in Ga2O3
- 5.1 Introduction
- 5.1.1 Summary of the results of theoretical and experimental defect and impurity studies in ß-Ga2O3
- 5.1.2 Centers active in recombination
- 5.2 Conclusions
- Acknowledgments
- References
- Chapter 6 Breakdown in Ga2O3 rectifiers-the role of edge termination and impact ionization
- 6.1 Introduction
- 6.2 The evolution of rectifier design and performance
- 6.3 Degradation mechanisms in rectifiers
- 6.3.1 Reverse bias
- 6.3.2 Forward bias
- 6.3.3 Carrier multiplication mechanisms
- 6.4 Measurement of impact ionization coefficients and their temperature dependence
- 6.5 Edge termination methods
- 6.6 The choice of dielectric material for a field plate
- 6.7 Summary and conclusions
- Acknowledgments
- References
- Chapter 7 Radiation damage in Ga2O3 materials and devices
- 7.1 Introduction
- 7.2 Basic radiation damage measurement quantities
- 7.2.1 The importance of radiation damage in electronics
- 7.2.2 Radiation damage in wide bandgap semiconductors
- 7.2.3 Summary of radiation damage studies in Ga2O3
- 7.2.4 Dominant defects induced by proton irradiation
- 7.3 Conclusions
- Acknowledgments
- References
- Chapter 8 Optical properties of Ga2O3 nanostructures
- 8.1 Introduction
- 8.2 Optical parameters of Ga2O3
- 8.2.1 Optical processes in semiconductors and insulators
- 8.2.2 Gallium oxide as an optical material
- 8.2.3 Ga2O3 nano- and microstructures
- 8.3 Luminescence of doped Ga2O3
- 8.3.1 Transition metal ion doping (Cr, Ni, Mn, and Zn)
- 8.3.2 Rare-earth ion doping (Er, Eu, Gd, Tb, Dy, and Nd)
- 8.3.3 Sn and Si doping
- 8.3.4 Al and In doping and alloying-ternary oxides
- 8.3.5 Other dopants
- 8.4 Optical confinement in Ga2O3 microstructures
- 8.4.1 Waveguiding in Ga2O3
- 8.4.2 Fabry-Pérot resonant cavities
- 8.4.3 Distributed Bragg reflector based microcavities
- 8.5 Summary, outlook, and prospective work
- References
- Chapter 9 Band alignment of various dielectrics on Ga2O3, (AlxGa1-x)2O3, and (InxGa1-x)2O3
- 9.1 Introduction
- 9.1.1 (AlxGa1-x)2O3
- 9.1.2 (InxGa1-x)2O3
- 9.2 Band alignment principles
- 9.3 Measuring band offset
- 9.4 Bandgap determination
- 9.4.1 Onset of inelastic losses using XPS
- 9.4.2 Reflection electron energy loss spectroscopy
- 9.4.3 Ultraviolet-visible spectroscopy
- 9.5 Choice of dielectric
- 9.6 Reported band offsets
- 9.6.1 Gate dielectrics on Ga2O3, (AlxGa1-x)2O3, and (InxGa1-x)2O3
- 9.6.2 Al2O3
- 9.6.3 SiO2 and HfSiO4
- 9.6.4 Indium tin oxide and aluminum zinc oxide
- 9.6.5 InN
- 9.6.6 CuI
- 9.7 Conclusion
- References
- Chapter 10 The effect of growth parameters on the residual carbon concentration in GaN high electron mobility transistors: theory, modeling, and experiments
- 10.1 Introduction
- 10.1.1 Opportunities and challenges for GaN based devices
- 10.1.2 Carbon impurity and related defects in GaN
- 10.2 Correlation between carbon concentration and growth conditions
- 10.2.1 The effects of MOCVD growth parameters
- 10.3 Theory and modeling of carbon incorporation
- 10.3.1 The surface reconstruction of GaN
- 10.3.2 The effects of carrier gas
- 10.3.3 The thermodynamic model of impurity incorporation
- 10.3.4 The effects of the Ga precursor
- 10.4 Conclusions
- References
- Chapter 11 High Al-content AlGaN-based HEMTs
- 11.1 Introduction
- 11.2 Figures-of-merit suggest performance advantages for AlGaN-channel HEMTs
- 11.2.1 Power switching figures-of-merit
- 11.2.2 RF figures-of-merit
- 11.3 Ohmic contacts for high Al-content AlGaN
- 11.4 AlGaN-channel HEMTs
- 11.4.1 Early work in AlGaN-channel HEMTs
- 11.4.2 Recent work in high Al-content HEMTs
- 11.4.3 Enhancement-mode HEMTs
- 11.4.4 Toward high current density in AlGaN-channel HEMTs
- 11.4.5 RF performance of high Al-content HEMTs
- 11.5 Breakdown properties of high Al-content transistors
- 11.6 Other nascent AlGaN HEMT research
- 11.6.1 Pulsed I-V
- 11.6.2 Reliability
- 11.6.3 Extreme temperature operation
- 11.6.4 Radiation performance
- 11.7 Summary
- Acknowledgement
- References
- Chapter 12 Understanding interfaces for homoepitaxial GaN growth
- 12.1 Introduction
- 12.2 Surface interface structure
- 12.2.1 Offcut
- 12.2.2 Wafer bow
- 12.2.3 Surface polish and morphology
- 12.3 Chemical interfaces
- 12.4 Effects on device performance
- 12.4.1 Surface morphology effects
- 12.4.2 Chemical interface effects
- 12.5 Conclusion
- Acknowledgements
- References
- Chapter 13 Gas sensors based on wide bandgap semiconductors
- 13.1 Introduction
- 13.2 An AlGaN/GaN HEMT-based ethanol sensor
- 13.3 AlGaN/GaN HEMT-based ammonia sensor
- 13.4 The AlGaN/GaN HEMT-based carbon dioxide sensor
- 13.5 The AlGaN/GaN HEMT-based hydrogen sensor with a water blocking layer
- 13.6 Conclusion
- Acknowledgments
- References
- Chapter 14 Modeling of AlGaN/GaN pH sensors
- 14.1 Introduction
- 14.2 Background
- 14.2.1 Experimental review
- 14.2.2 Simulation review
- 14.3 Simulation methodology: an open-gate high electron mobility transistor as pH sensor
- 14.3.1 Device structure
- 14.3.2 Two-dimensional electron gas
- 14.3.3 Electrolyte
- 14.3.4 Semiconductor
- 14.3.5 Inner and outer Helmholtz regions
- 14.3.6 Interface regions
- 14.3.7 Boundary conditions
- 14.4 Results: a pH GaN-based HEMT sensor with EDL and specific adsorption finite-element modeling
- 14.4.1 Understanding the 2DEG as a sensor response
- 14.4.2 Equilibrium reaction rate
- 14.4.3 Passivation charge
- 14.4.4 Linear 2DEG sensor response
- 14.4.5 Drain bias
- 14.5 Comparing simulation work with experimental results
- 14.6 Future work
- References
- Chapter 15 The potential and challenges of in situ microscopy of electronic devices and materials
- 15.1 Introduction
- 15.2 Materials and characterization techniques
- 15.2.1 The material properties and working principle of AlGaN/GaN HEMTs
- 15.2.2 Material and device characterization using the in situ TEM technique
- 15.3 AlGaN/GaN HEMT reliability study
- 15.3.1 Degradation in the GaN HEMT
- 15.3.2 AlGaN/GaN HEMT characterization techniques
- 15.3.3 GaN HEMT reliability study using an in situ TEM study
- 15.4 Future directions
- Acknowledgement
- References
- Chapter 16 Vertical GaN-on-GaN power devices
- 16.1 Introduction
- 16.2 Vertical GaN p-n diodes
- 16.2.1 Ion implantation
- 16.2.2 Beveled field plate
- 16.2.3 Mesa termination
- 16.2.4 Plasma-based edge termination
- 16.2.5 Leakage mechanism
- 16.3 Vertical GaN Schottky barrier diodes
- 16.3.1 Carbon doping in the drift layer
- 16.3.2 Double drift layer
- 16.3.3 Effect of buffer layer thickness
- 16.3.4 Edge termination
- 16.3.5 Leakage mechanism
- 16.4 Vertical GaN advanced power rectifiers
- 16.4.1 Vertical GaN MPS rectifiers
- 16.4.2 Vertical GaN JBS rectifiers
- 16.4.3 Vertical GaN TMBS rectifiers
- 16.5 Normally-off vertical GaN power transistors
- 16.5.1 Vertical GaN CAVETs
- 16.5.2 Vertical GaN trench MOSFETs
- 16.5.3 Vertical GaN JFETs
- 16.5.4 Vertical GaN FinFETs
- 16.6 Selective area doping
- 16.7 Conclusion
- References
- Chapter 17 Electric-double-layer-modulated AlGaN/GaN high electron mobility transistors (HEMTs) for biomedical detection
- 17.1 Introduction
- 17.2 Fabrication of sensors
- 17.2.1 Fabrication of HEMT sensors
- 17.2.2 Antibody and DNA aptamer immobilization
- 17.3 Principles and characteristics of EDL AlGaN/GaN HEMT sensors
- 17.4 Beyond the Debye length for protein detection in physiological samples
- 17.4.1 Protein detection in 1X PBS and human serum
- 17.4.2 Tunable and amplified sensitivity
- 17.4.3 Portable devices for personal healthcare
- 17.5 Summary
- References
- Chapter 18 Irradiation effects on high aluminum content AlGaN channel devices
- 18.1 Introduction
- 18.2 SRIM modeling
- 18.3 Device fabrication overview
- 18.4 Proton irradiation
- 18.5 Alpha irradiation
- 18.6 Summary and conclusion
- References
- Chapter 19 BeMgZnO wide bandgap quaternary alloy semiconductor
- 19.1 Introduction
- 19.2 Theoretical studies
- 19.3 Material growth
- 19.3.1 MBE of BeMgZnO
- 19.3.2 Other growth methods
- 19.4 Compositional and optical characterizations of BeMgZnO
- 19.5 Applications of BeMgZnO
- 19.5.1 BeMgZnO/ZnO HFETs
- 19.5.2 Other applications
- 19.6 Summary
- References
- Chapter 20 Growth and properties of hexagonal boron nitride (h-BN) based alloys and quantum wells
- 20.1 Introduction and unique properties of h-BN
- 20.2 Prospects of h-BN-based alloys and heterostructures
- 20.3 Epitaxy growth and properties of h-BGaN alloys and QWs
- 20.3.1 Epitaxial growth of h-GaxB1-xN alloys
- 20.3.2 Growth of h-BGaN QWs and photoluminescence emission properties
- 20.3.3 Probing the critical thickness and phase separation effects in h-GaBN/BN heterostructures
- 20.4 Epitaxy growth and properties of h-(BN)C semiconductor alloys
- 20.4.1 BN-rich h-(BN)1-x(C2)x alloys
- 20.4.2 C-rich h-(BN)1-x(C2)x alloys
- 20.5 Concluding remarks
- Acknowledgement
- References
- Chapter 21 Recent advances in SiC/diamond composite devices
- 21.1 Introduction
- 21.2 Silicon carbide
- 21.2.1 SiC power devices
- 21.2.2 Technological challenges
- 21.3 Diamond
- 21.3.1 Doped diamond
- 21.3.2 Diamond based devices
- 21.3.3 Technical challenges
- 21.4 Diamond/SiC composite devices
- 21.4.1 Thermal management
- 21.4.2 Device passivation
- 21.4.3 Diamond/SiC heterojunctions
- 21.5 PCD/SiC heterojunctions
- 21.5.1 Experimental details
- 21.5.2 Morphological characterization of the BDD films
- 21.5.3 Electrical characteristics of the BDD films
- 21.6 Conclusions
- References
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