
Process-Induced Phase Separation in Polymer Blends
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ISNI: 0000 0003 7053 0499
ISNI: 0000 0005 1640 5771
ISNI: 0000 0005 1640 5886
ISNI: 0000 0005 1640 5800
Content
- Intro
- Editorial Advisory Board
- The Authors
- Preface
- Contents
- 1 Introduction
- 1.1 Overview of the Polymer Blend Technology
- 1.1.1 Demixing in Polymer Blend Systems
- 1.2 Different Types of Miscible Polymer Blend Systems
- 1.2.1 PMMA/SAN Blend Systems
- 1.2.2 PS/PVME Blend Systems
- 1.2.3 PVDF/PMMA Blend Systems
- 1.3 Immiscible Polymer Blend Systems
- 1.3.1 Polypropylene (PP)-Based Blend Systems
- 1.3.2 PE-Based Polymer Blend Systems
- 1.3.3 PC-Based Polymer Blend Systems
- 1.4 Biobased Polymer Blend Systems
- 1.5 Industrial Significance and Commercial Applications of Different Polymer Blend Systems
- 1.6 Conclusions
- 2 Phase Separation, Heterogeneous Behavior and Prevention of Phase Separation
- 2.1 Basic Concept of Polymer Blends
- 2.2 Theories of Polymer Solutions
- 2.2.1 The Ideal Solutions of Small Molecules
- 2.2.2 Non-ideal Polymer Solutions
- 2.3 Mechanism of Phase Separation
- 2.4 Different Types of Morphologies
- 2.5 Influence of Compatibilizers on Morphology and the Phase Separation Behavior of Polymer Blends
- 2.5.1 Influence of Reactive Compatibilization
- 2.5.2 Particle-Induced Compatibilization
- 2.5.3 Role of Janus Hybrid Particles
- 2.6 Conclusions
- 3 Crystallization and Melting Kinetics of Phase Separated Polymer Blends
- 3.1 Introduction
- 3.2 Crystallization Kinetics from Melt
- 3.3 Theories of Nucleation and Growth
- 3.3.1 Homogeneous Nucleation
- 3.3.2 Heterogeneous Nucleation
- 3.3.3 Spherulite Growth and Fold Surface Free Energy
- 3.4 Crystallization Behavior (Isothermal and Non-isothermal) of Polymer Blends
- 3.5 Influence of Fillers on the Morphology and Crystalline Structure of Binary Polymer Blends
- 3.6 Impact of Compatibilizers on the Crystallization Morphology and Crystallization Rate of Polymer Blends
- 3.7 Conclusions
- 4 Theoretical Studies of Phase Separation in Polymer Blends
- 4.1 Introduction
- 4.2 Flory-Huggins Theory
- 4.3 Chad-Hilliard-Cook Theory
- 4.4 Landau-Ginzburg Theory
- 4.5 Conclusions
- 5 Processing of Phase-Separated Blends
- 5.1 Introduction
- 5.2 Processing Methods
- 5.2.1 Melt Compounding
- 5.2.2 Solution Blending
- 5.2.3 Latex Mixing
- 5.2.4 Interpenetrating Polymer Networks (IPNs)
- 5.2.5 Graft Copolymerization
- 5.2.6 In Situ Polymerization
- 5.2.7 Mill Mixing
- 5.3 Characterization of Phase-Separated Polymer Blends
- 5.4 Conclusions
- 6 Experimental Approaches for the Evaluation of Phase Separation Process in Polymer Blends
- 6.1 Introduction
- 6.2 Evaluation of Phase Separation Behavior in Polymer Blends by DSC
- 6.3 Evaluation of Phase Separation Behavior in Polymer Blends by DMA
- 6.4 Evaluation of Phase Separation Behavior in Polymer Blends by Rheology
- 6.5 Evaluation of Phase Separation Behavior in Polymer Blends by Broadband Dielectric Relaxation Spectroscopy
- 6.6 Evaluation of Phase Separation Behavior in Polymer Blends by Transmission Electron Microscope
- 6.7 Evaluation of Phase Separation Behavior in Polymer Blends by Scanning Electron Microscope
- 6.8 Evaluation of Phase Separation Behavior in Polymer Blends by Optical Microscope
- 6.9 Evaluation of Phase Separation Behavior in Polymer Blends by Atomic Force Microscope
- 6.10 Conclusions
- 7 Factors Influencing Phase Separation in Partially Miscible Polymer Blends
- 7.1 Introduction
- 7.2 Processing Techniques
- 7.2.1 Solution Mixing and Film Casting
- 7.2.2 Doctor Blade
- 7.2.3 Electrospinning
- 7.2.4 Spin Coating
- 7.2.5 Compression Molding
- 7.2.6 Incorporation of Nanoparticles
- 7.3 Conclusions
- 8 Interfacial Modification of Immiscible Polymer Blends
- 8.1 Introduction
- 8.2 Block Copolymers
- 8.3 Janus Nanoparticles
- 8.4 Compatibilization by Nanoparticles
- 8.4.1 Graphene Oxide
- 8.4.2 Carbon Nanotubes
- 8.5 Conclusions
- 9 Applications of Immiscible Polymer Blends
- 9.1 Introduction
- 9.2 Gas and Moisture Barrier Applications
- 9.3 Gas Sensing Applications
- 9.4 Membranes for Water Remediation
- 9.5 Electromagnetic Interference Shielding Materials
- 9.6 Conclusions
- Index
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