Applied Complexometry
Pergamon Series in Analytical Chemistry
Published on 22. October 2013
456 pages
978-1-4831-6111-2 (ISBN)
Description
Applied Complexometry tackles complexometry from a practical perspective. The book discusses more applications, and theories are reduced to the most important ones. Comprised of 22 chapters, this book deals first with volumetric reagents in complexometry, and then tackles detection of the titration end-point. Chapter 3 covers masking (screening) reagents. Chapter 4 discusses separation methods, and Chapter 5 covers apparatus and solutions. Chapter 6 talks about the classification of EDTA complexes, while Chapter 7 discusses the complexometry anions. Chapter 8 discusses the analytical applications; Chapters 9 to 21 explain the analysis of several materials and solutions, such as alloys, silicates and rocks, cement, ores and concentrates, semiconductors, pigments, and electroplating solutions. The last chapter discusses further applications of complexometry. This book will be of great interest to researchers, especially for chemists whose work involves various chemical techniques such as complexometry.
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Rudolf Pribil
Applied Complexometry
Book
11/1982
Pergamon
€91.76
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Content
Chapter 1 Volumetric Reagents in Complexometry 1.1 The Properties of EDTA 1.2 The Stability of EDTA Complexes 1.3 EDTA as a Volumetric reagentChapter 2 Detection of the Titration End-point 2.1 Complexometric Indicators 2.1.1 Introduction 2.1.2 Metallochromic Indicators 2.1.3 The Properties of Metallochromic Indicators 2.1.4 The Sensitivity of the Indicator and Accuracy of the Titration 2.1.5 A Brief Survey of Metallochromic Indicators 2.1.6 Metallofluorescent Indicators 2.1.7 Redox Indicators 2.1.8 Chemiluminescent Indicators 2.1.9 Blocking of Indicators 2.2 Instrumental Methods in ComplexometryChapter 3 Masking (Screening) Reagents 3.1 Classification of Masking Agents 3.2 Masking Agents for Alkaline Media 3.2.1 Potassium Cyanide 3.2.2 Triethanolamine (TEA) 3.2.3 Thioglycollic Acid (TGA) 3.2.4 3-Mercaptopropionic Acid (MPA) 3.2.5 2,3-Dimercaptopropan-1-o1 (BAL) 3.2.6 Unithiol 3.2.7 Dimercaptosuccinic Acid 3.2.8 Ammonium Fluoride 3.2.9 Hydrogen Peroxide 3.2.10 Sodium or Potassium Hydroxide 3.3 Masking Reagents for Acid Solutions 3.3.1 Sodium or Ammonium Sulphate 3.3.2 Potassium Iodide 3.3.3 Sodium Thiosulphate 3.3.4 Thiourea 3.3.5 Thiosemicarbazide 3.3.6 1,10-Phenanthroline (Phen) 3.3.7 Derivatives of Salicylic Acid 3.3.8 Acetylacetone 3.3.9 Hydrogen Peroxide 3.4 Masking by Precipitation 3.5 ConclusionsChapter 4 Separation Methods 4.1 Separation during Dissolution 4.2 Separation by Precipitation 4.3 Separation by Electrolysis 4.4 Separation on Ion-Exchangers 4.5 Separation by Liquid-Liquid ExtractionChapter 5 Apparatus and Solutions 5.1 Glass and Plastic Ware 5.2 Reagents 5.2.1 Ethylenediaminetetra-Acetic Acid - EDTA 5.2.2 The Stability of Standard EDTA Solutions 5.2.3 Standardization of EDTA Solutions 5.2.4 Preparation of Other Standard Solutions 5.2.5 Preparation of Indicators 5.2.6 BuffersChapter 6 Classification of EDTA Complexes 6.1 Complexometry of Group I Cations 6.1.1 Zirconium 6.1.2 Hafnium 6.1.3 Thorium 6.1.4 Scandium 6.1.5 Bismuth 6.1.6 Iron 6.1.7 Uranium 6.1.8 Indium 6.1.9 Gallium 6.1.10 Thallium 6.1.11 Chromium 6.1.12 Titanium 6.1.13 Tin 6.1.14 Mercury 6.2 Complexometry of Group II Cations 6.2.1 Copper 6.2.2 Lead 6.2.3 Nickel 6.2.4 Cobalt 6.2.5 Zinc 6.2.6 Cadmium 6.2.7 Aluminum 6.2.8 Manganese 6.2.9 Molybdenum 6.2.10 Vanadium 6.2.11 The Rare-Earth Lanthanides (RE) - The Lanthanides 6.3 Complexometry of Group III Cations 6.3.1 Calcium and Magnesium 6.3.2 Strontium 6.3.3 Barium 6.3.4 Beryllium 6.3.5 Silver 6.3.6 Alkali Metals 6.3.7 Gold and the Platinum MetalsChapter 7 The Complexometry of Anions 7.1 Fluoride 7.1.1 Determination of Fluoride as CaF2 7.1.2 Determination of Fluoride as PbClF 7.1.3 Determination of Fluoride as PbBrF 7.1.4 Determination of Fluoride as CeFo 7.1.5 Determination of Fluoride as LaF3(H2O)3 7.1.6 Direct Determination of Fluoride by Titration with Thorium Nitrate 7.1.7 Direct Determination of Fluoride with U(SO4)2 Solution 7.2 Determination of Sulphate 7.2.1 Determination of Sulphate as BaSO4 7.2.2 Determination of Sulphate as PbSO4 7·3 Determination of Phosphate 7.3.1 Determination of Phosphate as MgNH4PO4.6H2O 7.3.2 Determination of Phosphate as ZnNH4PO4.6H2O 233 7.3.
