
General and Synthetic Methods
Description
Alles über E-Books | Antworten auf Fragen rund um E-Books, Kopierschutz und Dateiformate finden Sie in unserem Info- & Hilfebereich.
More details
Other editions
Additional editions

Persons
Content
- General and Synthetic Methods
- Contents
- Chapter 1 Saturated and Unsaturated Hydrocarbons
- 1 Saturated Hydrocarbons
- 2 Olefinic Hydrocarbons
- 3 Stereoselective, Simultaneous Formation of sp3 and sp2 Centres
- Claisen Rearrangements
- [2,3] Wittig Rearrangements
- 4 Conjugated Dienes
- 5 Non-conjugated Dienes
- 6 Polyenes
- 7 Allenes
- 8 Alkynes
- 9 Enynes
- References
- Chapter 2 Aldehydes and Ketones
- 1 Synthesis of Aldehydes and Ketones
- Oxidative Methods
- Reductive Methods
- Methods Involving Umpolung
- Other Methods
- Cyclic Ketones
- 2 Synthesis of Functionalised Aldehydes and Ketones
- Unsaturated Aldehydes and Ketones
- a-Substituted Aldehydes and Ketones
- Dicarbonyl Compounds
- 3 Protection and Deprotection of Aldehydes and Ketones
- 4 Reactions of Aldehydes and Ketones
- Reactions of Enolates
- Aldol Reactions
- Conjugate Addition Reactions
- References
- Chapter 3 Carboxylic Acids and Derivatives
- 1 Carboxylic Acids
- General Synthesis
- Diacids
- Hydroxy-acids
- Keto-acids
- Unsaturated Acids
- Aromatic Acids
- Halo-acids
- Carboxylic Acid Protection
- 2 Carboxylic Acid Esters
- Esterification
- General Synthesis
- Diesters
- Hydroxy-esters
- Keto-esters
- Unsaturated Esters
- Halo-esters
- Thioesters
- 3 Carboxylic Acid Amides
- General Synthesis
- Hydroxy-amides
- Keto-amides
- Unsaturated Amides
- Thioamides
- 4 Lactones
- General Synthesis
- Butyrolactones
- a-Methylene- and a-Alkylidenebutyrolactones
- ?-Alkylidinebutyrolactones
- Butenolides
- Tetronic Acids
- Phthalides
- Valerolactones
- Macrolides
- 5 Amino Acids
- a-Amino acids
- Dehydroamino acids
- Hydroxy a-amino acids
- ß-Amino acids
- Amino-acid Coupling
- Amino-acid Protection
- References
- Chapter 4 Alcohols, Halogeno Compounds, and Ethers
- 1 Alcohols
- Preparation
- By Addition to Olefins
- By Reduction of Carbonyl Compounds
- By Nucleophilic Alkylation
- Non Stereoselective Addition
- Selective Addition
- By Opening of Epoxides
- Miscellaneous Methods
- Protection and Deprotection
- Oxidation and Deoxygenation
- 2 Halogeno Compounds
- 3 Ethers and Thioethers
- References
- Chapter 5 Amines, Nitriles, and Other Nitrogen-containing Functional Groups
- 1 Amines
- Acyclic Amines
- Aromatic Amines
- Allylic Amines
- Cyclic Amines
- Protecting Groups
- Enamines
- Alkyldiamines
- 2 Amino-alcohols
- 1,2-Amino-alcohols
- 1,3-Amino-alcohols
- 1,2-Amino-thiols, 1,2-Aminoketones, and a-Aminophosphonic Acids
- Azo Compounds
- Nitriles
- Nitro Compounds
- Nitroxyl and Nitroso Compounds
- Alkyl Nitrates and Nitramines
- Hydroxylamines
- Imines
- Amidines
- Oximes and Hydrazones
- Thiodiimides
- Azides
- Thiocyanates, Isothiocyanates, and Isocyanides
- References
- Chapter 6 Organometallics in Synthesis
- Part I: The Transition Elements
- 1 Introduction
- 2 Reduction
- 3 Oxidation
- 4 Isomerisations and Rearrangements
- 5 Carbon-Carbon Bond-Forming Reactions
- Via Organometallic Electrophiles
- Via Organometallic Nucleophiles
- Via Coupling and Cycloaddition Reactions
- Via Carbonylation Reactions
- 6 Miscellaneous Reactions
- References
- Part II: Main Group Elements
- 1 Group I
- Lithium Amides
- Lithium Enolates
- Non-stabilized Organolithium Reagents
- Lithiated Aromatic and Heteroaromatic Rings
- Benzylic and Allylic Lithium Anions
- Alkenyl and Alkynyl Lithium Anions
- Di- and Trilithiated Anions
- Sodium and Potassium
- Anions Stabilised by Sulphur, Silicon, and Selenium
- 2 Group II
- Magnesium
- Zinc and Mercury
- 3 Group III
- Boron
- Aluminium and Thallium
- 4 Group IV
- Silicon and Germanium
- Allyl, Benzyl, and Alkenyl Silanes and their Derivatives
- Tin and Lead
- 5 Group V
- Phosphorus
- Arsenic, Antimony, and Bismuth
- 6 Group VI
- Sulphur
- Selenium and Tellurium
- References
- Chapter 7 Saturated Carbocyclic Ring Synthesis
- 1 Three-membered Rings
- 2 Four-membered Rings
- 3 Five-membered Rings
- Transition Metal Mediated Cyclisations
- Radical Cyclisations
- Other Routes to Five-membered Rings
- 4 Six-membered Rings
- Diels-Alder Reactions
- Other Routes to Six-membered Rings
- 5 Seven-membered, Medium, and Large Rings
- Seven and Eight-membered Rings
- Large Rings
- Ring Expansions
- References
- Chapter 8 Saturated Heterocyclic Ring Synthesis
- 1 Oxygen-containing Heterocycles
- Three-membered Rings
- Four-membered Rings
- Five-membered Rings
- Tetrahydrofurans
- Dihydrofurans and Benzofurans
- Five-membered Rings with More than One Oxygen
- Six-membered Rings
- Tetrahydropyrans
- Dihydropyrans
- Six-membered Rings with More than One Oxygen
- Medium- and Large-ring Ethers
- 2 Sulphur-containing Heterocycles
- 3 Heterocycles Containing More than One Heteroatom
- Nitrogen- and Oxygen-containing Rings
- Five-membered Rings
- Six- and Seven-membered Rings
- Nitrogen- and Sulphur, and Sulphur- and Oxygen- containing Rings
- 4 Nitrogen-containing Heterocycles
- Three- and Four-membered Rings
- Five-membered Rings
- Six-membered Rings Containing One Nitrogen
- Five- and Six-membered Rings with Two Nitrogen Atoms
- Seven-membered and Larger Rings
- ß-Lactam
- References
- Chapter 9 Highlights in the Total Synthesis of Natural Products
- 1 Terpenes
- 2 Alkaloids
- 3 Spiroacetals
- 4 Macrolides
- 5 Polyether Antibiotics
- 6 Tetronolides
- 7 Enediynes
- 8 Other Natural Products
- References
- Chapter 10 Reviews on General and Synthetic Methods
- 1 Saturated and Unsaturated Hydrocarbons
- 2 Halogeno Compounds
- 3 Sulphur Compounds
- 4 Carbonyl Compounds
- 5 Carboxylic Acids and Derivatives
- 6 Carbocyclic Ring Synthesis
- 7 Heterocyclic Ring Synthesis and Alkaloids
- 8 Organometallics
- 9 Asymmetric Synthesis and Stereoselective Processes
- 10 Natural Products Synthesis
- 11 Nucleosides
- 12 Radicals in Synthesis
- 13 Carbohydrates
- 14 Cycloaddition Reactions
- 15 Pressure Reactions
- 16 Photochemistry and Electrochemistry
- 17 General
- Author Index
System requirements
File format: PDF
Copy protection: Watermark-DRM (Digital Rights Management)
System requirements:
- Computer (Windows; MacOS X; Linux): Use the free software Adobe Reader, Adobe Digital Editions, or any other PDF viewer of your choice (see eBook Help).
- Tablet/Smartphone (Android; iOS): Install the free app Adobe Digital Editions or another reading app for eBooks, e.g., PocketBook (see eBook Help).
- E-reader: Bookeen, Kobo, Pocketbook, Sony, Tolino and many more (only limited: Kindle).
The file format PDF always displays a book page identically on any hardware. This makes PDF suitable for complex layouts such as those used in textbooks and reference books (images, tables, columns, footnotes). Unfortunately, on the small screens of e-readers or smartphones, PDFs are rather annoying, requiring too much scrolling.
This eBook uses Watermark-DRM, a „soft” copy protection. This means that there are no technical restrictions to prevent illegal distribution. However, there is a personalised watermark embedded in the eBook that can be used to identify the purchaser of the eBook in the event of misuse and to provide evidence for legal purposes.
For more information, see our eBook Help page.