
General and Synthetic Methods
Description
Alles über E-Books | Antworten auf Fragen rund um E-Books, Kopierschutz und Dateiformate finden Sie in unserem Info- & Hilfebereich.
More details
Other editions
Additional editions

Person
Content
- General And Synthetic Methods
- Contents
- Chapter 1 Saturated and Unsaturated Hydrocarbons
- 1 Saturated Hydrocarbons
- 2 Olefinic Hydrocarbons
- 3 Stereoselective Simultaneous Formation of Sp3 and Sp2 Centres
- Claisen Rearrangement
- [2,3] Wittig Rearrangements
- 4 Conjugated Dienes
- 5 Non-conjugated Dienes
- 6 Polyenes
- 7 Allenes
- 8 Alkynes
- 9 Diynes and Polynes
- 10 Enynes
- References
- Chapter 2 Aldehydes and Ketones
- 1 Synthesis of Aldehydes and Ketones
- Oxidative Methods
- Reductive Methods
- Methods Involving Umpolung
- Other Methods
- Cyclic Ketones
- 2 Synthesis of Functionalized Aldehydes and Ketones
- Unsaturated Aldehydes and Ketones
- a-Substituted Aldehydes and Ketones
- Dicarbonyl Compounds
- 3 Protection and Deprotection of Aldehydes and Ketones
- 4 Reactions of Aldehydes and Ketones
- Reactions of Enolates
- Aldol Reactions
- Conjugate Addition Reactions
- References
- Chapter 3 Carboxylic Acids and Derivatives
- 1 Carboxylic Acids
- General Synthesis
- Anhydrides
- Diacids
- Hydroxy-acids
- Keto-acids
- Unsaturated Acids
- Aromatic Acids
- Carboxylic Acid Protection
- 2 Carboxylic Acid Esters
- Esterification
- General Synthesis
- Diesters
- Hydroxy-esters
- Keto-esters
- Unsaturated Esters
- Thioesters
- 3 Lactones
- Butyrolactones
- a-Methylene- and a-Alkylidenebutyrolactones
- Butenolides
- Tetronic Acids
- Phthalides
- Valerolactones
- Macrolides
- 4 Carboxylic Acid Amides
- General Synthesis
- Hydroxy-amides
- Keto-amides
- Unsaturated Amides
- Thioamides
- 5 Amino-acids
- a-Amino-acids
- a-and ß-Dehydroarnino-acids
- ß-Amino-acids
- ?-Amino-acids
- Amino-acid Protection
- References
- Chapter 4 Alcohols, Halogeno-compounds, and Ethers
- 1 Alcohols
- Preparation
- By Addition to Alkenes
- By Reduction of Carbonyl Compounds
- By Nucleophilic Alkylation
- By Opening of Epoxides
- Miscellaneous Methods
- Protection and Deprotection
- Oxidation
- Deoxygenation
- 2 Halogeno Compounds
- Preparation and Reactions
- 3 Ethers
- Preparation
- 4 Thiols and Thioethers
- References
- Chapter 5 Amines, Nitriles, and Other Nitrogen-containing Functional Groups
- 1 Amines
- Acyclic Amines
- Aromatic Amines
- Allylic Amines
- Cyclic Amines
- Protecting Groups
- 2 Enamines
- 3 Amino Alcohols and Amino Ketones
- 4 Azo Compounds
- 5 Nitriles and Isocyanides
- 6 Nitro- and Nitroso-compounds and Nitramines
- 7 Hydrazines and Hydrazides
- 8 Hydroxylamines
- 9 Imines
- 10 Amidines
- 11 Oximes and Hydrazones
- 12 Carbodiimides
- 13 Azides
- 14 Isocyanates and Thiocyanates
- 15 Nitrones
- References
- Chapter 6 Organometallics in Synthesis
- Part I: The Transition Elements
- 1 Introduction
- 2 Reduction
- 3 Oxidation
- 4 Isomerisations and Rearrangements
- 5 Carbon-Carbon Bond Forming Reactions
- Via Organometallic Electrophiles
- Via Organometallic Nucleophiles
- Via Coupling and Cycloaddition Reactions
- Via Carbonylation Reactions
- 6 Miscellaneous Reactions
- References
- Part II: Main Group Elements
- 1 Group 1
- General Aspects
- Selective Lithiations
- Di- and tri-Anions, Alkenyl and Alkynyl Anions
- Sodium, Potassium and Caesium
- Sulphur and Selenium Stabilised Anions
- 2 Group II
- Magnesium
- Zinc and Mercury
- 3 Group III
- Boron
- Aluminium
- 4 Group IV
- Silicon
- Allyl and Vinyl Silanes
- Other Silicon-containing Reagents
- Germanium, Tin and Lead
- 5 Group V
- Phosphorus
- Arsenic, Antimony and Bismuth
- 6 Group VI
- Sulphur
- Selenium and Tellurium
- References
- Chapter 7 Saturated Carbocyclic Ring Synthesis
- 1 Three-membered Rings
- 2 Four-membered Rings
- 3 Five-membered Rings
- Transition Metal Mediated Cyclisations
- Radical Cyclisations
- Other Routes to Five-membered Rings
- 4 Six-membered Rings
- Diels-Alder Reactions
- Other Routes to Six-membered Rings
- 5 Seven-membered Medium and Large Rings
- Seven and Eight-membered Rings
- Sigmatropic Rearrangements
- Other Routes to Medium and Large Rings
- 6 Ring Expansion and Spiro-ring Compounds
- References
- Chapter 8 Saturated Heterocyclic Ring Synthesis
- 1 Oxygen-containing Heterocycles
- Three-membered Rings
- Four-membered Rings
- Five-membered Rings
- Tetrahydrofurans
- Dihydrofurans and Benzofurans
- Five-membered Rings with More than One Oxygen
- Six-membered Rings
- Tetrahydropyrans
- Dihydropyrans
- Six-membered Rings with more than One Oxygen
- Medium- and Large-ring Ethers
- 2 Sulphur-containing Heterocycles
- 3 Heterocycles Containing More than One Heteroatom, Nitrogen- and Oxygen-containing Rings
- Five-membered Rings
- Six-membered Rings
- Nitrogen- and Sulphur, and Sulphurand- Oxygen-containing Rings
- 4 Nitrogen-containing Heterocycles
- Three- and Four-membered Rings
- Five-membered Rings
- Six-membered Rings Containing One Nitrogen
- Six-membered Rings with Two Nitrogens
- Seven, Eight and Nine-membered Rings
- ß-Lactams
- References
- Chapter 9 Highlights in Total Synthesis of Natural products
- 1 Terpenes
- 2 Alkaloids
- 3 Spiroacetals
- 4 Macrolides and Ionophores
- 5 Other Natural Products
- References
- Reviews on General and Synthetic Methods
- 1 Olefinic Compounds
- 2 Fluoro-organic Compounds
- 3 Azides and Sulphur Chemistry
- 4 Amino Acids and Peptides
- 5 Carbocyclic Rings
- 6 Organometallics
- General
- Main Group Elements
- Transition Elements
- 7 Cycloaddition Reactions
- 8 Heterocycles
- 9 Natural Products
- 10 Asymmetric Syntheses
- 11 Rearrangement Reactions
- 12 Carbonylation Reactions
- 13 Catalysts in Synthesis
- 14 Radical Reactions in Synthesis
- 15 Strategy in Synthesis
- 16 General
- 17 Miscellaneous
- Author Index
System requirements
File format: PDF
Copy protection: Watermark-DRM (Digital Rights Management)
System requirements:
- Computer (Windows; MacOS X; Linux): Use the free software Adobe Reader, Adobe Digital Editions, or any other PDF viewer of your choice (see eBook Help).
- Tablet/Smartphone (Android; iOS): Install the free app Adobe Digital Editions or another reading app for eBooks, e.g., PocketBook (see eBook Help).
- E-reader: Bookeen, Kobo, Pocketbook, Sony, Tolino and many more (only limited: Kindle).
The file format PDF always displays a book page identically on any hardware. This makes PDF suitable for complex layouts such as those used in textbooks and reference books (images, tables, columns, footnotes). Unfortunately, on the small screens of e-readers or smartphones, PDFs are rather annoying, requiring too much scrolling.
This eBook uses Watermark-DRM, a „soft” copy protection. This means that there are no technical restrictions to prevent illegal distribution. However, there is a personalised watermark embedded in the eBook that can be used to identify the purchaser of the eBook in the event of misuse and to provide evidence for legal purposes.
For more information, see our eBook Help page.