
Physics Methods in Archaeometry
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Content
- Title Page
- Indice
- Preface
- Gruppo fotografico dei partecipanti al Corso
- Optical spectroscopy and colorimetry
- Introduction
- Causes of colour
- Transitions between delocalised molecular orbitals
- Ligand field transitions
- Charge transfer transitions
- Energy band transitions
- Colorimetry: some concepts
- Instrumentation
- Fibre Optics Reflectance Spectroscopy (FORS)
- Image Spectroscopy (IS)
- Non-invasive techniques: pros and cons
- Applications to actual cases
- Pigment identification
- Colour change measurements
- Distance and transformation in the multivariate analysis of archaeometric data
- Introduction
- Some data
- Notation and terminology
- Distances
- Transformation
- Principal component analysis (PCA)
- Basic ideas
- The mathematics of PCA
- Biplots
- PCA and correspondence analysis
- Examples
- Cluster analysis and Mahalanobis distance
- Basic ideas
- Cluster analysis and Mahalanobis distance
- Discriminant analysis
- Basic ideas
- DA, Mahalanobis distance and classification
- Literature
- Thermodynamics for cultural heritage
- Forward
- Part 1: Air and artefact temperature
- Kinetic theory of perfect gases
- Equipartition law
- Real gases and the energy of interaction between particles U
- Development of dynamic internal boundary layers
- The molecular and the continuum regimes
- Molecular regime
- Continuum regime
- Transition regime
- Thermophoresis
- Thermophoresis in the molecular regime
- Thermophoresis in the continuum regime
- Measuring air and artwork temperature
- Measuring artworks temperature
- Part 2: Parameters describing atmospheric humidity
- The equation of state for real gases
- PVT diagram showing the gas and the liquid phases and the phase transitions
- Which variable is representative of the interactions between moisture and materials?
- Relationship between temperature and saturation vapour pressure
- Dew point: the temperature of condensation
- The mixing ratio r of moist air
- The specific humidity q
- The absolute humidity d v
- The molar fraction of water vapour
- The relative humidity U w
- The two definitions of relative humidity
- Relative humidity: the 1947 definition
- Relative humidity: the 1966 definition
- The role of relative humidity
- Key data about the H2O vapour and the minimum volume available for each molecule
- Potential energy U(r) of mutual interaction of a molecule of water vapour as a function of the inter-molecular distance r: a possible interpretation
- The physical meaning of relative humidity: a possible interpretation
- Wet bulb temperature: the temperature of evaporation
- Relative humidity from psychrometric readings
- Appendix
- Formulae for the derivation of the hygrometric variables from psychrometers, hygrometers, dew point meters
- Part 3: the Kelvin law and the adsorption isotherms
- Droplets and pores: how a curved water meniscus changes the equilibrium vapour tension
- The Kelvin law for different types of meniscus
- Hysteresis for a different combination of pores
- Adsorption hysotherm for a relative humidity cycle
- Allowed microclimate variability (T and RH thresholds) for artworks
- Part 4: Impact of moisture on materials
- Nocturnal and morning condensation
- Role of moisture and condensation on weathering and decay of cultural heritage
- The equilibrium moisture content (EMC) and dimensional changes in wood species
- The microclimate and the conservation of paper
- The problem of church heating
- Leaching and corrosion
- Damage caused by water on stones
- Ion beam techniques for the analysis of archaeological metallic artefacts
- Ion beams for material analysis: an introduction
- Kinematics of RBS (Rutherford Backscattering Spectroscopy)
- The scattering cross-sections of RBS
- Rutherford cross-sections
- Non-Rutherford cross-sections
- Typical RBS spectra
- Basic principles of PIXE (Particle Induced X-ray Emission)
- Fundamentals of PIGE (Particle Induced gamma-ray Emission) and nuclear reactions
- Identification of signals for analytical purposes
- Experimental procedure for external beam PIXE
- Analysis of coins
- The soldering of gold artefacts
- Prehispanic gold artefacts of Mesoamerica
- Differential PIXE analysis for the study of depletion gilding
- Conclusions
- Information technologies applied to scientific examination of museum collections
- Introduction
- The scientific research at the C2RMF
- Scientific information indexing and retrieval
- The European Research Open System (EROS)
- The database architecture
- Digitising activities for cultural applications
- From photo-archive digitisation to direct digitisation of objects
- New technologies for direct capture of 2D and 3D objects
- The C2RMF panoramic views digitisation systems for objects consulting and 3D model construction
- The 3D laser detection of objects
- The 2D and 3D digitisation of paintings
- The Jumbolux linear beam lighting system
- A pigmented chart for colour correction of paintings
- The CRISATEL high-definition digital camera
- Varnish opacity, thickness and colour measurement
- 3D capture of paintings
- Conclusion
- Scientific techniques and methodologies for the provenance of white marbles
- Introduction
- The nature of marble
- Techniques used for provenance determination
- Neutron activation analysis
- Cathodoluminescence
- Petrographic thin-section analysis
- Stable isotope analysis
- Electron Paramagnetic Resonance spectroscopy (EPR)
- Ancient quarries and database
- Provenance determination procedure
- Sampling or not sampling?
- Sampling procedure
- The movement of marble in antiquity
- The physical basis of thermoluminescence dating and its applications
- Introduction
- Thermoluminescence
- Defects, traps and luminescence centres
- Instrumentation
- Applied thermoluminescence
- Radiation sources
- TL dating
- TL dating: a few examples of application
- TL dating in excavation archaeology
- TL dating of historical buildings
- TL dating of burnt flints
- TL dating of archaeological glasses
- TL dating of clay-cores
- Conclusions
- Quantitative XRF analysis in archaeometric applications
- Introduction
- Quantitative XRF analysis
- General
- Quantitative analysis with monochromatic excitation radiation
- Secondary excitation effects
- Detailed examination of the effects on relative intensity values dependent on the irregular shape
- Measurement of coin fineness
- Quantitative analysis of glass and ceramics
- The gilding of other metals since 3000 BC. "All that glisters is not gold
- Gilding with gold foil
- Gilding with gold leaf
- Diffusion bonding of gold leaf on to silver
- Gilding of copper alloys with gold leaf
- Leaf gilding on a bole ground
- Fire gilding
- Depletion gilding
- Pseudogilding
- The manufacture of wire since the Bronze Age: A technological investigation using the microscope
- Hammered wire
- Swaged wire
- Block-twisted wire
- Strip drawn wire
- Strip twisted wire
- Cast wire
- Folded wire
- Drawn wire
- Summary
- The scientific work on the Sutton Hoo ship burial
- The presence of a body
- Dating the burial
- The analysis of the jewellery
- The examination of the shield and helmet
- The examination of the sceptre and of the iron standard
- Bronzes in the Sutton Hoo grave
- Glass in the Sutton Hoo grave
- The Sutton Hoo drinking horns
- Summary
- Unmasking forged antiquities. How scientific techniques are used to expose fakes in museum collections
- Copies made from moulds of original objects
- Copies made in the style of original objects
- Genuine objects which have been altered to make them rarer and thus more valuable
- Damaged antiquities which have been carefully restored so that the damage is invisible
- Forgeries made in ancient times
- The scientific detection of forgeries
- Non-destructive examination
- The materials of manufacture
- The alteration products (such as metallic corrosion or weathering layers)
- The structure of the original material and the techniques of manufacture
- The age of the object
- Synchrotron radiation and neutrons in archaeological and cultural heritage science
- Introduction
- Pigments
- Painting pigments
- Micro-sampling of pigment powders
- Glazes
- Hispano-Moresque lustre ware
- Etruscan black gloss
- Use of hard X-rays and neutrons on metal objects
- Summary
- Archaeometallurgy: Examples of the application of scientific methods to the provenance of archaeological metal objects
- Introduction
- The behaviour of trace elements
- Trace elements and technology
- Trace elements and provenance
- Image spectroscopy for diagnostics and conservation of contemporary art
- Contemporary art: characters and problems
- Image spectroscopy
- Principles of the method
- Measurement
- Experimental apparatus
- Calibration
- Experimental results
- Treatment of spectral data
- Principal Component Analysis: mathematical definitions
- Applications
- Conclusions
- Archaeometry - an overview
- History of archaeometry in the UK
- Remote sensing
- Science-based dating
- Artefact studies
- Pottery production
- Copper alloys
- Copper trade in the Late Bronze Age Mediterranean
- Artefact use
- Man and his environment
- Stable isotope analysis of human bone
- DNA studies
- Conclusions
- Production technology of ancient pottery
- Reconstruction
- Raw materials
- Forming
- Surface treatment
- Firing procedures
- Discovery and adoption
- The beginnings of pottery production in the Near East
- Organic residue analysis
- Mode of production
- Technological choice and change
- Glass and related vitreous materials
- Glazed stone, faience and related materials
- Egyptian blue frit
- The beginnings of glass
- Glass production in Egypt
- Roman and Byzantine glass
- Roman cameo glass
- Islamic and Medieval glass
- Glazed pottery
- The first glazed earthenware
- Lead glazed pottery
- Tin-opacified glazes
- Stonepaste bodies
- Isnik ware
- Related European glazed ceramics
- Italian maiolica
- Medici porcelain
- Radionuclide dating in archaeology by accelerator mass spectrometry
- Introduction
- Accelerator mass spectrometry
- Chemical process
- Accelerator measurement
- Radiocarbon dating
- Principles of radiocarbon dating
- Performance of AMS 14 C dating
- Datable age
- Sample size
- Precision and accuracy
- Archaeology at the radiocarbon limit
- Datable age
- Accuracy
- Sample size
- Bomb pulse dating
- Dating with in situ cosmogenic radionuclides
- Dating of hominids with 10 Be/26 Al
- Conclusions
- Scientific methods and applications to archaeological provenance studies
- Introduction
- Analytical methods and instrumentation
- Spectroscopy and spectrometry
- Optical spectroscopy
- X-ray spectroscopy
- Gamma-ray spectroscopy
- Isotope spectrometry
- Standards and calibration
- Principles and prerequisites of provenance studies
- Sample selection and other considerations
- Trade and exchange
- Copper
- Marble
- Obsidian sourcing in the central Mediterranean: a case study
- Discussion and conclusion
- Stable isotopes and diet: You are what you eat
- Introduction
- Principles of stable isotope analysis
- Analytical methods
- Recent applications
- Patagonia (Argentina and Chile)
- Highland Ecuador and Peru
- Coastal Ecuador and Peru
- Belize and Guatemala
- Florida
- Europe
- China
- Microsampling of teeth
- Strontium isotope analysis
- Physics and archaeological time: Luminescence and particle track dating
- Nuclear clocks
- Luminescence dating
- TL dating of heated flint
- OSL dating of colluvium
- Spatially resolved luminescence
- Fission track dating
- Alpha recoil track dating
- Innovative systems for digital radiography and computed tomography: Applications to cultural heritage diagnostics
- Introduction: the computed tomography technique
- The micro-CT system
- Intensified 3D tomography large-area system I
- Intensified 3D tomography large-area system II
- Fan beam tomography with an intensified linear detector
- Conclusions
- Forensic science trace evidence approaches in archaeology
- Hafting in the Acheulean
- 17000BP Mycrobacerium tuberculosis
- Infanticide in ancient Ashkelon
- The Dead Sea Scrolls
- A 2000 year old burial shroud
- The "Warrior Family" burial from Massada
- Conclusions
- Thermographic testing on historic building
- Foreword
- Use of thermography for wall inspection
- Laboratory tests
- Mathematical models for the on-field application
- The case of "Santa Maria Incoronata" church
- Detection of damp surfaces by active and passive thermography
- Active approach
- Passive approach
- Lab test on building material
- On-field applications
- Final remarks on moisture detection
- Active tests
- Independence from the surface
- Sensibility to water content
- Environmental condition
- Conclusive remarks
- Elenco dei partecipanti
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