
Microgels: Synthesis, Properties and Applications
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Content
- Intro
- Contents
- Preface
- References
- About the Editor
- Section I: An Overview of Microgel Research
- Chapter 1
- Microgels: What Are They?
- Abstract
- Introduction
- Synthesis of Microgels
- Precursors for Microgel Synthesis
- From Macrogels
- From Monomers
- From Polymers
- Processes of Microgel Formation
- Emulsification
- Emulsion Polymerization
- Inverse Emulsion Polymerization
- Complexation
- Homogeneous Nucleation
- Precipitation Polymerization
- Free Radical Polymerization
- Stage I - Initiation
- Stage II - Propagation
- Stage III - Termination
- Anionic Polymerization
- Properties of Microgels
- Swelling Behaviour of Microgels
- Effect of Monomers on Microgel Properties
- Phase Transition of Microgels
- Microgels and Their pH Sensitivity
- Rheological and Electrical Properties
- Characterization of Microgels
- Dynamic Light Scattering (DLS)
- Static Light Scattering (SLS)
- Nuclear Magnetic Resonance (NMR) Spectroscopy
- Small Angle Neutron Scattering (SANS)
- Turbidimetric Analysis
- Conclusion
- References
- Chapter 2
- Types and Properties of Microgels: An Overview
- Abstract
- Introduction
- Major Types of Polymer Constituents
- Categories of Hydrogels
- Chemical Hydrogels
- Physical Hydrogels
- Conclusion and Future Perspectives
- References
- Chapter 3
- Technologies for Polymer Characterization and Microgel Development
- Abstract
- Introduction
- Techniques for Structural Characterization
- Techniques for Morphological Characterization
- Techniques for Surface Characterization
- Other Techniques for Microgel Research
- Conclusion and Future Perspectives
- References
- Chapter 4
- Applications of Microgels: An Overview
- Abstract
- Introduction
- Microgels in Drug Delivery
- Microgels in Diagnosis and Biomedicine
- Microgels in Molecular Imprinting
- Microgels in Organic Coatings
- Microgels in Cosmetic Use
- Microgels in Oil Recovery
- Microgels in Other Applications
- Conclusion
- References
- Section II: Properties and Engineering of Microgels
- Chapter 5
- Stimuli-Responsive Microgels: Recent Advances and Future Prospects
- Abstract
- Introduction
- Characteristic Features of Polymers
- Physical Stimuli
- Temperature
- Light
- Electric Field
- Chemical Stimuli
- pH
- Ionic Strength
- Redox Potential
- Bio-Responsive Polymers
- Glucose-Responsive Polymers
- Enzyme-Responsive Polymers
- In ammation-Responsive Polymers
- Applications
- Drug Delivery
- Controlled Rate Microgels
- Mucoadhesive Microgels
- Metal-Containing Microgels
- Systemic Drug Delivery
- Glucose-Responsive Microgels
- Microreactors
- Temperature-Sensitive Microgels
- pH-Sensitive Microgels
- Ion-Sensitive Microgels
- Coatings and Rheology Modification
- Photonic Crystals
- Molecular Imprinting
- Sensing and Biosensing
- Cosmetics
- Food Industry
- Conclusion and Future Perspectives
- References
- Chapter 6
- Noncovalent Cross-Linking Microgels and Manipulation of Microgel Properties
- Abstract
- Introduction
- Microgel Generation via Self-Assembly
- Microgel Constituents
- Architecture
- Modes of Supramolecular Cross-Linking
- Ionic Interaction
- Hydrophobic Interactions
- Hydrogen Bonding
- Tuning Factors
- Solubility Characteristics
- Gelling Mechanism
- Electrical Properties
- Degradability
- Practical Factors
- Dissociation of Supramolecular Cross-Linking
- UV-Induced Dissociation
- Cyclodextrin-Induced Dissociation
- Conclusion and Future Perspectives
- Acknowledgments
- References
- Chapter 7
- Phenol Formaldehyde-Based Aerogels
- Abstract
- Introduction
- Methods of Preparation of Aerogels
- Sol-Gel Process
- Aging
- Drying
- Supercritical Drying (SCD)
- Ambient Pressure Drying (APD)
- Freeze Drying (FD)
- Microwave Drying and Vacuum Drying (VD)
- Carbonization
- Properties of Aerogels
- Types of Aerogels
- Polymer-Based Aerogels
- Phenol Formaldehyde-Based Aerogels
- Novolak Resin-Based Aerogels
- Phenol-Furfural Aerogels
- Phenol-Resorcinol-Formaldehyde Aerogels
- Phenol-Melamine-Formaldehyde Aerogels
- Melamine-m-Cresol-Formaldehyde-Resole-Based Aerogels
- Resorcinol Formaldehyde-Based Aerogels
- Polybenzoxazine-Based Aerogels
- Applications of Aerogels
- Conclusion and Future Perspectives
- References
- Chapter 8
- Fabrication of Microgel Particles with a Microfluidic Approach
- Abstract
- Introduction
- Fabrication of Capillary Microfluidic Devices
- Fabrication of Polydimethylsiloxane (PDMS) Microfluidic Devices
- 3D Printing
- Conclusion
- References
- Chapter 9
- Engineering the Microstructure of Microgels Using Electrospray
- Abstract
- Introduction
- Principles of Electrospray in Microgel Formation
- Fabrication of Microgels Using Electrospray
- Incorporating the Core-Shell Architecture into Microgels
- Generation of Multicompartment Microgels
- Conclusion and Future Perspectives
- References
- Section III: Practical Applications of Microgels
- Chapter 10
- Hydrogels and Metallo-Hydrogels: Characterization, and Their Environmental and Pharmaceutical Applications
- Abstract
- Introduction
- Characterization of Microgels
- Chemical Information of Microgels
- Acid-Base Equilibria for Basic Polyelectrolyte Hydrogels
- Acid-Base Equilibria for Basic Polyampholyte Hydrogels
- Structural Information of Microgels
- Nuclear Magnetic Resonance Characterization
- Strategies to Synthesize Hydrogels with Metal Ion Coordination Properties
- Environmental Applications of Copper and Cobalt Complexes
- H2O2 Activation by Copper and Cobalt Hydrogel Complexes
- Dye Removal from Aqueous Solutions
- Pharmaceutical Applications of Hydrogels
- Hydrogels for Drug Delivery
- Hydrogels as Biosensors
- Hydrogels as Contact Lenses
- Stimuli-Responsive Microgels: From Macro to Micro
- Conclusion and Perspectives
- Acknowledgments
- References
- Chapter 11
- Emerging Applications of Stimuli-Responsive Microgels in the Water Treatment Process
- Abstract
- Introduction
- Synthesis and Properties of Functionalized and Composite Microgels
- Synthesis and Properties of Microgels
- Composite Microgels
- Functionalized Microgels as Draw Agents for Forward Osmosis Desalination
- Forward Osmosis Desalination
- Recent Development of Draw Solute Materials
- Thermoresponsive Microgels as Forward Osmosis Draw Agents
- Microgels as Adsorbents for Water Treatment
- Incorporated Microgels for Responsive Membranes
- Conclusion and Research Outlook
- References
- Chapter 12
- Chemical Synthesis and Biomedical Applications of Micro/Nanogels
- Abstract
- Introduction
- Synthetic Methods of Micro/Nanogels
- Radical Polymerization
- Click Chemistry
- Copper-Catalyzed Azide-Alkyne Huisgen Cycloaddition (CuAAC)
- Copper-Free Click Chemistry
- Strain-Promoted Azide-Alkyne Cycloaddition (SPAAC)
- Thiol-Ene Click Reaction
- Michael Addition
- Schiff-Base Reaction
- Thiol-Disulfide Exchange Reaction
- Photo-Induced Cross-Linking
- Amide-Based Cross-Linking
- Boronic Acid-Diol Complexation
- Enzyme-Catalyzed Cross-Linking
- Siloxane Cross-Linking
- Radiation Cross-Linking
- Biomedical Applications of Micro/Nanogels
- Controlled Drug Release
- Tissue Engineering
- Gene Delivery
- Bio-Imaging
- Antifouling
- Conclusion and Future Perspectives
- References
- Chapter 13
- Application-Driven Microgel Engineering for Drug Delivery
- Abstract
- Introduction
- Polymer Constituents In Microgel Engineering
- Solubility/Hydrophilicity
- Biodegradability
- Methods of Drug Loading
- Physical Entrapment
- Chemical Crosslinking
- Changing the Properties of Microgels for Drug Delivery
- Swelling Capacity
- Size of Microgels
- Shape of Microgels
- Mechanical Strength
- Conclusion and Future Perspectives
- Acknowledgments
- References
- Index
- Blank Page
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