Modern Methods for the Separation of Rarer Metal Ions
Published on 22. October 2013
632 pages
978-1-4831-8631-3 (ISBN)
Description
Modern Methods for the Separation of Rarer Metal Ions describes several separation methods of more than 50 elements. This book is divided into 19 chapters that include separation methods involving the actinide elements, rare earths, and many rarer elements of the main and transition groups of the periodic table. The introductory chapter discusses the principles of the separation techniques presented in this book. The remaining chapters explore the application of specific separation methods, such as ion exchange, chromatography, liquid-liquid extraction, distillation, and coprecipitation. The approach of each chapter is a presentation of separation principle of an element first followed by numerous examples of applications to the solution of practical problems encountered in separation chemistry. Chapters 2 and 3 examine the separations involving the actinides and rare earth elements using ion exchange and liquid-liquid extraction These are followed by chapters dealing with separations of other rarer elements, which have been arranged according to their position in the periodic table. These elements are: Li, Rb, Cs, Fr, Be, Ra, Ga, In, Tl, Ge, Ag, Au, Ti, Zr, Hf, V, Nb, Ta, Mo, W, Tc, Re and the platinum metals. This book will be of great use to analytical chemists.
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Johann Korkisch
Modern Methods for the Separation of Rarer Metal Ions
Book
06/1969
Pergamon
€35.90
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Content
PrefaceAcknowledgments1. Separation Techniques 1.1. Ion Exchange 1.1.1. Ion Exchange Resins 1.1.2. Ion Exchange Selectivities 1.1.3. Ion Exchange Separations 1.1.4. Inorganic Ion Exchangers 1.2. Chromatography 1.2.1. Partition Chromatography 1.2.2. Paper Chromatography 1.2.3. Electrochromatography 1.2.4. Partition Chromatography on Thin Layers 1.2.5. Reversed-Phase Partition Chromatography 1.2.6. Gas Chromatography 1.3. Liquid-Liquid Extraction 1.3.1. The Extraction Process 1.3.2. Types of Solute 1.3.3. Applications 1.4. Distillation 1.5. Coprecipitation 1.6. Selected Bibliography2. Actinide Elements 2.1. Separation on Cation Exchangers 2.2. Separation on Anion Exchangers 2.2.1. Separation as Anionic Sulphate Complexes ("Sulphate Method") 2.2.2. Separation as Anionic Chloride Complexes ("Chloride Method") 2.2.3. Separation as Anionic Nitrate Complexes ("Nitrate Method") 2.2.4. Separation as Anionic Complexes with Various Other Complexing Agents 2.3. Other Chromatographic Methods 2.3.1. Separation on Cellulose Columns 2.3.2. Separation by Paper Chromatography, Paper Electrophoresis and on the Ring-Oven 2.3.3. Separation by Partition Chromatography on Silica Gel 2.3.4. Separation by Reversed-Phase Partition Chromatography 2.4. Extraction Methods 2.4.1. Extraction with Ethers 2.4.2. Extraction with Ketones 2.4.3. Extraction with Ethyl Acetate 2.4.4. Extraction with Organic Phosphorus Compounds 2.4.5. Extraction with Chelating Agents 2.5. Separation by Coprecipitation3. Rare Earth Elements 3.1. Separation on Cation Exchangers 3.1.1. Hydrochloric Acid Media 3.1.2. Sulphuric Acid Media 3.1.3. Nitric Acid Media 3.1.4. Other Media 3.1.5. Media Containing Organic Complexing Agents 3.2. Separation on Anion Exchangers 3.3. Other Chromatographic Methods 3.3.1. Separation by Partition Chromatography 3.3.2. Separation by Reversed-Phase Partition Chromatography 3.4. Extraction Methods 3.4.1. Extraction with Ethers, Ketones and Alcohols 3.4.2. Extraction with Organic Phosphorus Compounds 3.4.3. Extraction with Chelating Agents 3.5. Separation by Coprecipitation4. Lithium 4.1. Separation on Cation Exchangers 4.2. Separation on Anion Exchangers 4.3. Other Chromatographic Methods 4.4. Extraction Methods5. Rubidium, Caesium and Francium 5.1. Separation on Cation Exchangers 5.1.1. Separation on Cation Exchange Resins 5.1.2. Separation on Inorganic Cation Exchangers 5.2. Separation on Anion Exchangers 5.3. Other Chromatographic Methods 5.4. Extraction Methods 5.5. Separation by Coprecipitation6. Beryllium 6.1. Separation on Cation Exchangers 6.2. Separation on Anion Exchangers 6.3. Other Chromatographic Methods 6.4. Extraction Methods 6.5. Separation by Coprecipitation7. Radium 7.1. Separation on Ion Exchangers 7.2. Other Chromatographic Methods 7.3. Extraction Methods 7.4. Separation by Coprecipitation8. Gallium, Indium and Thallium 8.1. Separation on Cation Exchangers 8.2. Separation on Anion Exchangers 8.3. Other Chromatographic Methods 8.4. Extraction Methods 8.5. Separation by Coprecipitation9. Germanium 9.1. Separation on Cation Exchangers 9.2. Separation on Anion Exchangers 9.3. Other Chromatographic Methods 9.4. Extraction Methods 9.5. Distillation Methods 9.6. Separation by Coprecipitation10. Selenium, Tellurium and Polonium 10.1. Separation on Cation Exchangers 10.2. Separation on Anion Exchangers 10.3. Other Chromatographic Methods 10.4. Extraction Methods 10.5. Distillation Methods 10.6.
