
Corrosion Policy Decision Making
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Explore the science, management, economy, ecology, and engineering of corrosion management and prevention
In Corrosion Policy Decision Making, distinguished consultant and corrosion expert Dr. Reza Javaherdashti delivers an insightful overview of the fundamental principles of corrosion with a strong focus on the applicability of corrosion theory to industrial practice. The authors demonstrate various aspects of smart corrosion management and persuasively make the case that there is a real difference between corrosion management and corrosion knowledge management.
The book contains seven chapters that each focuses on one important aspect of corrosion and corrosion management.
Corrosion management is an issue that is not just corrosion science or corrosion engineering but rather a combination of both elements. To cover this paradoxical aspect of corrosion management, chapter 2 deals with some basic, introductory concepts and principles of corrosion and coating/painting (an important corrosion protection method) while chapter 3 explains the elements of smart corrosion management in detail. Another important principle of smart corrosion management is to be able to study the cost of corrosion, chapter 4 introduces important points in the economics involved in a smart corrosion management. As indicated earlier, corrosion engineering is also an integral part of corrosion management and thus chapter 5 looks at the engineering side of corrosion by detailing the example of Process Additives (EMPA). Chapter 6 for the first time looks at the possibility of using TRIZ (algorithm of invention) in corrosion management. Finally, chapter 7 presents the necessary elements for building a model that would explore the mutual interaction between corrosion and environment mainly by exploring the difference between environmental impact and environmental effect. Chapter 7 is also very important because the four models so far applied to estimate the cost of corrosion (Uhlig Method, Hoar Method, I/O method and LCC method) are not capable of suggesting any clear model or a sensible way of exploring the elements necessary to explain the impact of indirect costs of corrosion the most important of which being environmental damages imposed by corrosion.
This book is ideal for engineers, students, and managers working or studying corrosion, Corrosion Policy Decision Making is also an indispensable resource for professionals in the fields of upstream and downstream, on-shore/off-shore oil and gas, transportation, mining, power generation as well as major sectors of other strategic industries.
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Reza Javaherdashti, PhD, is a consultant in the field of corrosion assessment and management. He has extensive experience teaching corrosion, corrosion management, and microbial corrosion to industry professionals around the world, and is the author of six books on the subject.
Content
Preface xiii
Authors and Contributors xv
1 Introduction 1
Reza Javaherdashti
References 5
2 A Short Review of Some Important Aspects of the Science of Corrosion 7
Reza Javaherdashti and Ali Ghanbarzadeh
2.1 Introduction 7
2.1.1 Essentials of Electrochemical Corrosion 9
2.1.2 Prediction of Corrosion 12
2.1.2.1 Standard Hydrogen Electrode/Electrochemical Series 12
2.1.2.2 Galvanic Series 13
2.1.2.3 Pourbaix Diagrams 15
2.2 Important Technical Treatment Strategies for Corrosion Treatment 16
2.2.1 Design Modification-change/Materials Selection 17
2.2.2 Chemical Treatment 21
2.2.3 Electrical Treatment 22
2.2.4 Mechanical Treatment 23
2.2.5 Physical Treatment 23
2.2.5.1 Paints, Coating Systems, and Premature Destruction in Industrial Facilities 23
2.2.5.2 Features of Substrate 24
2.2.5.3 Characteristics of the Environment and Local Features 26
2.2.5.4 Paints Quality Control 34
2.2.5.5 Paint Warehousing and Storage 35
2.2.5.6 Role of Executors and Contractors 36
2.2.5.7 Surface Preparation 36
2.2.5.8 Technical Painting Operations 39
2.2.5.9 Inspection and Management 41
2.3 Conclusion 43
References 44
3 Smart Corrosion Management Elements 47
Reza Javaherdashti and Faranak Javaherdashti
3.1 Introduction 47
3.1.1 Risk, Importance, and How They Are Interrelated? 48
3.1.2 Corrosion Management: What It Is and What It Is Not 56
3.1.3 Management of Corrosion 58
3.1.3.1 Corrosion Reactions Geometry 59
3.1.3.2 Failure 60
3.1.3.3 Corrosion Prevention and Corrosion Control 67
3.1.3.4 cm Model 69
3.1.4 Phase 1: Definition 70
3.1.5 Phase 2: Application 73
3.1.6 Phase 3: Monitoring 74
3.1.7 Phase 4: Feedback 75
3.1.7.1 Corrosion Cost Estimation Model 76
3.1.7.2 Corrosion Knowledge Management (CKM) 79
3.2 Management of Corrosion and COVID 19 90
3.3 Environment 93
3.4 Application of Management of Corrosion Scheme to Underground Fire Water Ring 96
3.5 Damage Management 99
3.6 Algorithm 100
3.7 Final Remarks 104
References 107
4 Economics and Corrosion 111
Mahsa Mostashar-Nezami
4.1 Introduction 111
4.2 Economics 112
4.2.1 What Is Economics 112
4.2.2 Gross Domestic Product 114
4.2.2.1 The Expenditure Approach 115
4.2.2.2 The Income Approach 117
4.2.2.3 The Value-Added Approach 117
4.2.2.4 Income, Consumption, Saving, and Investment 117
4.2.2.5 Gross National Product 123
4.2.3 Introduction to National Account 123
4.2.3.1 Production Account, the Intermediate Consumption, and the Consumption of Fixed Capital 124
4.2.4 Net Present Value (NPV) and Net Future Value (NFV) 128
4.2.5 Input-Output Model in Economics 129
4.2.5.1 Technical Coefficients 130
4.2.5.2 Price and the Input-output Table 135
4.2.5.3 Dynamic Input-output Analysis 137
4.2.6 Depreciation, Consumption of Fixed Capital, or Corrosion 137
4.3 Corrosion Economics 138
4.3.1 Input-output Model in Corrosion 138
4.3.1.1 Matrix of Technical Coefficients 139
4.3.1.2 Matrix of Capital Coefficients 140
4.3.1.3 Input-output Model 142
4.3.1.4 Final Demand 143
4.3.1.5 World I, World Ii, World III 144
4.3.1.6 Estimating Corrosion Cost by Battelle 144
4.3.2 Life Cycle Cost (LCC) 149
4.3.2.1 Life-Cycle Cost Model 149
4.4 Corrosion and Sustainability 152
4.5 Conclusion 154
4.6 Summary 155
References 155
5 Effective Management of Process Additives (EMPA) 159
Mohamedreza Hamedghafarian
5.1 Introduction 159
5.2 A Gas Plant 160
5.3 Utilities 161
5.4 Process Additives (Chemicals) 165
5.5 Effective Management of Process Additives (EMPA) 175
5.5.1 Production Costs 175
5.5.2 Quality Control 175
5.5.3 Corrosion 176
5.5.4 Energy 177
5.5.5 Environment 178
5.5.6 Process Issues 180
5.5.6.1 Production Reduction 180
5.5.6.2 Off-spec Products 181
5.5.6.3 Operation History 1 202
5.5.6.4 Operation History 2 203
5.5.6.5 Operation History 3 214
5.5.6.6 Operation History 4 214
5.6 Misleading Trends with Corrosion Conclusions 215
5.6.1 Phosphate Solution Preparation (Boiler Internal Treatment) 215
5.6.2 Putting A Kettle-type Reboiler into Service that Has Been Under Maintenance 219
5.6.3 Problems in Sampling from Deaerator and Oxygen Scavenger Analyzation 220
5.6.4 Problems in Sampling and Analyzing Specific Conductivity from Demineralized Water 222
5.6.5 An Improper Sample Point and Mistake in Determining Free Residual Chlorine 223
5.7 Chemicals, Their Corrosion, and Impacts of Their Corrosions on the Environment 225
5.7.1 Operation History 5 226
5.8 Configuring EMPA 226
5.9 Setting up an EMPA 229
5.9.1 Description of Activities 230
5.9.1.1 Selection 230
5.9.1.2 Operation History 6 230
5.9.1.3 Operation History 7 232
5.9.1.4 Operation History 8 233
5.9.1.5 Operation History 9 234
5.9.1.6 Procurement 236
5.9.1.7 Operation History 10 236
5.9.1.8 Operation History 11 237
5.9.1.9 Delivery 237
5.9.1.10 Operation History 12 238
5.9.1.11 Operation History 13 239
5.9.2 Storage 240
5.9.2.1 Operation History 14 241
5.9.2.2 Operation History 15 242
5.9.2.3 Operation History 16 242
5.9.2.4 Operation History 17 243
5.9.2.5 Operation History 18 244
5.10 Consumption 245
5.10.1 Operation History 19 246
5.10.2 Operation History 20 246
5.10.3 Operation History 21 247
5.10.4 Operation History 22 248
5.10.5 Operation History 23 249
5.10.6 Operation History 24 249
5.10.7 Operation History 25 256
5.10.8 Operation History 26 257
5.10.9 Operation History 27 257
5.10.10 Operation History 28 259
5.11 Reporting 259
5.12 Documentation 260
5.13 Summary 263
Abbreviations 263
References 265
6 Application of TRIZ for Corrosion Management 269
Reza Javaherdashti and Mehdi Basirzadeh
6.1 Introduction 269
6.2 Basic Structure of TRIZ 271
6.2.1 The Essence of TRIZ in 50 Words 273
6.3 Level of Invention 274
6.4 History of TRIZ 275
6.5 About the Founder of TRIZ 276
6.5.1 Genrich Saulovich Altshuller 276
6.6 Contradiction as a Means to Formulate an Inventive Problem 278
6.7 Procedure of Inventive Design 280
6.8 Concept Development Using TRIZ 281
6.9 Contradiction Matrix (39 × 39) 283
6.9.1 List of the 39 Features 284
6.9.2 List of the 40 Principles 285
6.10 Using the TRIZ Matrix 286
6.10.1 TRIZ Problem Solving Methodology 286
6.10.2 Reality of the "Four-Box Scheme" Theory 288
6.11 Physical Contradiction Resolution 289
6.12 Ideality and the Ideal Final Result (IFR) 294
6.13 TRIZ Crossover QMS 299
6.14 The Evolutionary S-Curve 299
6.15 Nine Windows 301
6.16 Trends of Engineering System Evolution 302
6.17 Geometric Evolution of Linear Constructions 305
6.18 Trimming 306
6.18.1 Making Things Better and Less Expensive 306
6.19 Input-Output-Trimming Operator (I-O-T) 308
6.20 Resource Analysis 310
6.21 Function Analysis 311
6.22 Substance-Field Analysis 312
6.23 Tool-Object-Product (TOP) Function Analysis 312
6.24 Generic Model of a Function 314
6.24.1 Precise Description of a Function 315
6.24.2 Link between Functions 315
6.24.3 Increasing Effectiveness of Function Analysis 315
6.25 TRIZ Offers Five Basic Function Models 315
6.26 Psychological Inertia 315
6.27 Size-Time-Cost Operator 317
6.28 Applying the 40 Inventive Principles in Corrosion Management 318
6.29 Conclusion 334
6.30 Glossary of TRIZ Terms 334
6.a TRIZ Contradiction Table 339
References 345
7 Environmental Impacts of Corrosion and Assessment Strategies 349
Reza Javaherdashti
7.1 Introduction 349
7.1.1 Characterization of the Disaster 350
7.1.2 Why Environment? 352
7.1.3 Corrosion Impact and Corrosion Effect 355
7.1.4 Modeling Environmental Impacts 356
7.1.4.1 Necessary Elements for Construction of Corrosion Impact Modeling 358
7.2 Some Uses of Rule 365 363
7.2.1 Application of Rule 365 to Assess Corrosion Effects 364
7.3 Conclusions 365
References 365
Index 369
1
Introduction
Reza Javaherdashti
General Manager, Eninco Engineering B.V., The Netherlands
This book is a first-hand answer to two questions:
- What corrosion management (CM) really means;
- What to expect from CM.
Let us be more specific in describing what we mean by the above. For those of you who have been too engaged with your integrity management tasks that cannot find time to watch movies and particularly horror movies, I do recommend to watch the movie "Final Destination; Part 5," and watch it with the eyes of a corrosion/integrity management specialist. In this movie (and its previous parts) what is shown is that something of little importance goes wrong, and in a series of unpredictable, sad events, one (or sometimes more) of the actors are killed in a very dramatic, graphic way. As said, the main lesson learned from this movie is that one problem can lead to another and in the end, a catastrophic result occurs. The same is also true with neglecting corrosion in an integrity management plan; something that one would think is not that important will lead to another, and if it is in its "pseudo-FFS1" (Fit-For-Service State) stage, the result at its best could be arriving at a "Zugzwang effect" [1] stage, or simply said, failure.
In classical academic literature related to Management and its principles, perhaps one of the best definitions have been given by Henry Fayol as "To manage is to forecast and to plan, to organize, to command, to co-ordinate and to control [1]." On the other hand, corrosion has also a clear definition that can be simplified as the chemical reaction between an electron donor (anode) and electron receiver (cathode) via a medium that allows exchange of ions and a metallic path that allows electron transfer.2 However, what is CM? In fact, when it comes to corrosion science, we know that we are talking about laboratories, white-collar researchers, academic environments, and the search for understanding fundamentals and mechanisms of corrosion processes. In this context, innovation and how innovative research must be carried out is of fundamental significance. When we talk about corrosion engineering, it is the way the accumulated science and knowledge about corrosion and corrosion processes will become applicable in the field. For instance, the use of cathodic protection to let structures survive longer, or use of corrosion inhibitors and biocides to chemically control corrosion. Figure 1.1 can serve to show the essential elements of corrosion engineering and how corrosion engineering and other engineering disciplines are interconnected with each other. We see that when talking about corrosion engineering, we are actually talking about a multidimensional topic that in its wholeness is more complex than other engineering disciplines not in based on the subject of focus, but on the methodologies that apply to address corrosion and its various aspects such as monitoring and treatment:
Figure 1.1 Corrosion engineering and its relation to other engineering disciplines (right), essential features and components of corrosion engineering (left) (Used by permission from Eng. Riky Bernardo - Qatar).
All of these applications have their own codes and standards. When we talk about corrosion treatment, we know that we are talking about five strategies to deal with corrosion (physical measures, chemical measures, electrical measures, mechanical measures, and design/material selection measures). Corrosion monitoring is to address methods and technologies by which severity of corrosion within its course of action is studied by codes and measures pertaining to corrosion monitoring. All of the above bring to mind certain codes, working environments and specialties, and expertise. However, what is CM? It obviously has a part dealing with corrosion and a part dealing with management. The confusion arises from here; how can management which is seeming a non-technical issue, be matched with corrosion which is a highly technical issue?
All the materials written to date on the management of corrosion are just looking at the science/engineering, and to some extent economy of corrosion, without detailing with the actual requirements (for example, about the economic nomenclature that is needed to understand cost of corrosion). Some of the publications about CM do suffer from the defects mentioned above. Some examples of CM literature are:
A. Morshed, "An Introduction to Corrosion Management in Industry," NACE, USA, 2017.
A. Morshed, "An Introduction to Asset Corrosion Management in the Oil and Gas Industry, 2nd edition," NACE, USA, 2016.
A.S. Groysman, "Corrosion Problems and Solutions in Oil Refining and Petrochemical Industry," Springer, 2017.
"My Manual: Practical Corrosion Management," a manual published by IDC Technologies, 2009, Perth, Australia.
Even IMPACT report by ex-NACE (now AMPP) that was published in 2016 had some sections on management and economy without any focus on engineering and science aspect of corrosion.
No economist, environmental sciences specialist, or a non-technical manager is likely to read those books (and similar ones) or attend CM seminars and webinars. The reason is simple; corrosion has not been defined for these non-corrosionist professionals. Perhaps, the importance of corrosion has sometimes been flagged by some politicians,3 as well as passing bills to allow the establishment of certain corrosion related entities, say, within the army, but apart from those individual sparks, no overall, systematic understanding about corrosion and its various aspects exists yet.
Our iconoclast approach toward CM is what we call "Smart Management of Corrosion" in the sense that (i) it is smart because this system can adapt itself with any industry and, contrary to the existing assumption that CM is to be discussed within the context of a certain industry (oil and gas), smart management of corrosion is not industry-specific; and (ii) it focuses of the management side rather+ than the corrosion side. Our understanding is that current CM systems mainly deali with the risk of corrosion, however it is essential to also deal with the cost of corrosion, whether economic cost or ecological cost. Management of corrosion is a term that acts as an umbrella to both CM (risk of corrosion) and corrosion knowledge management (CKM) (cost of corrosion) simultaneously and being as such, Management of Corrosion is a more general term than CM alone.
There are three very important features about corrosion:
- Corrosion and Failure: Corrosion is inevitable and manageable; failure is inevitable and non-manageable. Being non-manageable does not mean that it cannot be prevented, it simply means that when failure happens, it happens! This distinguishment between these two terms if of vital importance; the prejudice of many who deal with corrosion issues is that they are entitled to find a way to prevent or control corrosion.4 Corrosion occurs anyway due to the thermodynamic nature of it, it is our duty, though, to prevent failures. It is through failures and leaks that not only economic costs are imposed (from shut down costs to maintenance and replacement), but also environmental effects also occur. Study of corrosion processes ending in leak and failure is the task of a corrosion specialist, post-mortem forensic investigation of the failure is what a forensic investigator does to help build a root cause analysis report, but who is to measure the seriousness of the environmental effects thus produced? Who is going to estimate the economic loss (direct cost and indirect cost)?
- Risk and Likelihood: If the likelihood of getting a certain type of corrosion-related failure is low, it does not necessarily mean that is risk is also low and vice versa. The confusion between risk and likelihood is with no doubt one of the most important sources of problems that can even reach to the level of disasters. It is the mindset that can be observed in industry quite frequently and it has the potential of being lethal.
- Corrosion and Aging: Aging implies that a structure has been in service for quite a long time, whereas corrosion can actually occur in structures right after being put into service. Therefore, corrosion-related failures could happen in structures after a relatively short period of service (sometimes months).
In our professional judgment, management of corrosion needs to address all aspects of corrosion as we have tried to do in this book; corrosion and the algorithm of innovation (TRIZ; the Theory of Inventive Problem Solving) have been covered to the required extent in Chapters 2 and 6. In Chapter 2, some important aspects of corrosion science is re-defined, that is, as much as needed. The engineers looking after corrosion issues may not themselves have attended pre-employment corrosion courses, and thus during their employment years they attend courses or conferences with specific titles, or even learn from each other and/or their colleagues verbally. There is a very small minority who, with a pre-employment background in corrosion, still keep their knowledge up to date. This author during his more than two decades of consulting, as well as education training courses, has seen these issues very...
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