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Advanced and Emerging Polybenzoxazine Science and Technology introduces advanced topics of benzoxazine resins and polybenzoxazines as presented through the collaboration of leading experts in the benzoxazine community, representing the authoritative introduction to the subjects. Broad topics covered include the recent development and improved understanding of the subjects, including low temperature cure, aerogels and carbon aerogels, smart chemistry in fire retarding materials and coatings, metal containing benzoxazines, rational design of advanced properties, and materials from natural renew.
In the past twenty years, the number of papers on polybenzoxazine has continuously increased at an exponential rate. During the past three years, the number of papers published is more than the previous 17 years combined. The material is now part of only a few successfully commercialized polymers in the past 35 years. Therefore, interest in this material in both academia and industry is very strong.
- Includes the latest advancements in benzoxazine chemistry
- Describes advanced materials, such as aerogels, carbons, smart coatings, nanofibers, and shape memory materials
- Includes additional characterization data and techniques, such as FT-IR, Raman, NMR, DSC, and TGA analyses
Language
Place of publication
Publishing group
Elsevier Science & Techn.
ISBN-13
978-0-12-804185-7 (9780128041857)
Schweitzer Classification
Part I: Synthesis and Properties of Benzoxazine Resins1. Various Synthetic Methods of Benzoxazine Monomers2. Catalytic Accelerated Polymerization of Benzoxazines and Their Mechanistic Considerations3. Molecular Designs of Benzoxazines With Enhanced Reactivity Based on Utilization of Neighboring-Group Participation and Introduction of Thioether Moiety4. Development of New Generation Benzoxazine Thermosets Based on Smart Ortho-Benzoxazine Chemistry5. Tailoring Polybenzoxazine Chemical Structure: Synthetic Approaches to Flexible Systems6. 3,4-Dihydro-1,3-2H-Benzoxazines: Uses Other Than Making Polybenzoxazines7. Symmetric Versus Asymmetric di-Bz Monomer Design: Structure-to-Properties Relationship
Part II: Physical and Chemical Properties of Cross-linked Polybenzoxazines8. Modern Developments Using Molecular Simulation to Predict the Physical and Mechanical Properties of Polybenzoxazines9. Predictive Methodology and Properties of Polybenzoxazines10. Properties Enhancement Obtained in Anhydride-Modified Polybenzoxazines: Effects of Ester Functional Group on Polybenzoxazine Network11. Thermal Degradation Mechanism of Polybenzoxazines12. Mediated Surface Properties of Polybenzoxazines
Part III: Application of Advanced Organic Synthesis for Benzoxazine Resins13. Thiol-Benzoxazine Chemistry for Macromolecular Modifications14. Boron-Containing Benzoxazine Resin15. Structures of Metal-Complex Polybenzoxazines and Effect of Metal Ions on the Polymerization, Degradation, and Catalysis16. Development of Phosphorus-Containing Polybenzoxazines
Part IV: Polybenzoxazine Blends and Alloys17. Benzoxazine/Cyanate Ester Alloys18. Polybenzoxazine/Bismaleimide Alloys19. Arylacetylene-Derived Resins and Functional Benzoxazines20. Polybenzoxazines Derived from Nitrile- and Phthalonitrile-Functional Benzoxazines and Copolymers from Benzoxazine/Phthalonitrile Resin Mixtures21. Fluorene-Based High Molecular Weight Benzoxazine Blends22. Polybenzoxazine/Organosiloxane
Part V: Biobased Polybenzoxazine Materials23. Polybenzoxazine Materials From Renewable Diphenolic Acid24. Cardanol-Based Benzoxazines and Their Applications25. Lignin-Based Phenols: Potential Feedstock for Renewable Benzoxazines26. Chitin- and Shell-Based Benzoxazines27. Eugenol-Based Polybenzoxazines28. Furan-Based Benzoxazines
Part VI: Morphological Control of Polybenzoxazines29. Reaction-Induced Phase Separation of Benzoxazine Blends30. Precision Thermoset-Spherical Nano- and Microparticles Formation in Nanoconfinement: A Model Case From Benzoxazine Polymerization in the Blend System With Aromatic Containing Thermoplastic Resin31. Polybenzoxazine for Hierarchical Nanoporous Materials32. Nanostructured Carbons and Related Materials Derived From Polybenzoxazine-Based Polymers33. Polybenzoxazine-Based Nanofibers by Electrospinning34. HCl-Catalyzed Polymerization of Benzoxazine and Chemical Transformations Along Pyrolysis to Microporous Carbons
Part VII: Polybenzoxazine Composites, Hybrid Materials, and Nanocomposites35. Hard Armor Composites From Ballistic Fiber-Reinforced Polybenzoxazine Alloys36. Polybenzoxazine/Carbon Nanotube Composites37. Recent Progress in Polybenzoxazine/POSS Hybrid Materials38. Polybenzoxazine Nanocomposites: Case Study of Carbon Nanotubes39. Polybenzoxazine-Based Organic-Inorganic Nanohybrid Materials for High Performance Engineering Applications40. Polybenzoxazine-Clay Nanocomposites41. Ceramic-Based Polybenzoxazine Micro- and Nanocomposites42. Preparation of Mechanically Flexible Composites Composed of Polybenzoxazine-Linear Low-Density Polyethylene-Fumed Silica and Study of Their Properties
Part VIII: Polybenzoxazine Applications and Potential Applications43. Benzoxazines in Proton Exchange Membrane Fuel Cells44. Polybenzoxazine-Based Self-Lubricating and Friction Materials45. Hybrid Polybenzoxazine Nanocomposites for Low-k Dielectrics46. Polybenzoxazine-Based Coatings for Corrosion Protection47. Polybenzoxazines as Self-Healing Materials48.