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Physical Chemistry: An Advanced Treatise: Liquid State, Volume VIIIB, deals with simple liquids because the theory is most developed for these liquids. The purpose of this treatise is to present a comprehensive treatment of physical chemistry for advanced students and investigators in a reasonably small number of volumes. An attempt has been made to include all important topics in physical chemistry together with borderline subjects which are of particular interest and importance. The book contains five chapters and begins with a discussion of various theories of mixtures, focusing on binary mixtures of simple, spherical molecules. This is followed by separate chapters on the properties of liquid helium; time-dependent correlation functions; theory of static critical phenomena; and progress in understanding the behavior of transport coefficients near the liquid-gas critical point.
Language
Place of publication
Publishing group
Elsevier Science & Techn.
ISBN-13
978-0-323-14799-6 (9780323147996)
Schweitzer Classification
List of Contributors Foreword Preface Contents of Previous and Future Volumes Chapter 7 / Liquid Mixtures I. Introduction II. Ideal Mixtures; Excess Thermodynamics Properties III. Intermolecular Potentials IV. Experimental Data V. Quasi-Lattice Theory VI. Distribution Function Approaches and the Percus-Yevick Theory VII. Perturbation Theories; Hard-Sphere Reference Fluid VIII. Other Perturbation Theories IX. "n-Fluid" Theories X. Solubility XI. Summary References Chapter 8 / Liquid Helium I. Introduction II. Experimental Data III. The Two-Fluid Model of 4He; Landau's Theory IV. The Fermi-Liquid Theory of 3He V. The Ideal Boson and Fermion Gases and the Hard-Sphere Boson Gas VI. Microscopic Theories for Helium II VII. Mixtures of 3He and 4He ReferencesChapter 9 / Time-Dependent Properties of Condensed Media I. Introduction II. Linear Response Theory III. Time Correlation Function and Memory Functions IV. Computer Experiments (Molecular Dynamics) V. Hydrodynamics and Generalized Hydrodynamics VI. Molecular Orientations in Gases and Liquids References Chapter 10 / Critical Phenomena: Static Aspects Introduction I. Nature of Phase Transitions II. Thermodynamics of Phase Transitions III. Critical Indices IV. Classical Theories V. Scaling-Law Equation of State VI. Lattice Gas Models VII. Pair Correlation Function and Critical Scattering Conclusion Appendix A References Chapter 11 / Dynamic Critical Phenomena in Fluid Systems I. Introduction II. Thermodynamic Functions and Transport Coefficients near the Liquid- Gas Critical Point III. Correlation Functions and Hydrodynamics IV. Relation between the Space- and Time-Dependent Correlation Functions and Scattering Experiments V. Measurements of the Structure Factor L(q, ¿) for Typical Fluids VI. Dynamic Scaling Laws VII. The Mode-Mode Coupling Approximation VIII. The Use of Mathematical Models to Study Time-Dependent Cooperative Behavior IX. Conclusion and Outlook Appendix. Linear Response Theory References Author Index Subject Index