
EPR Spectroscopy
Description
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Persons
Editors
Daniella Goldfarb is Professor in the Department of Chemical Physics at the Weizmann Institute of Science in Rehovot, Israel.
Stefan Stoll is Assistant Professor in the Department of Chemistry at the University of Washington in Seattle, Washington, USA.
Content
Contributors xi
Series Preface xv
Preface xvii
Part A: Fundamental Theory 1
1 Continuous-Wave EPR 3
Art van der Est
2 EPR Interactions - g-Anisotropy 17
Peter Gast and Edgar J.J. Groenen
3 EPR Interactions - Zero-field Splittings 29
Joshua Telser
4 EPR Interactions - Coupled Spins 63
Eric J.L. McInnes and David Collison
5 EPR Interactions - Hyperfine Couplings 81
Marina Bennati
6 EPR Interactions - Nuclear Quadrupole Couplings 95
Stefan Stoll and Daniella Goldfarb
7 Quantum Chemistry and EPR Parameters 115
Frank Neese
8 Spin Dynamics 143
Akiva Feintuch and Shimon Vega
9 Relaxation Mechanisms 175
Sandra S. Eaton and Gareth R. Eaton
Part B: Basic Techniques and Instrumentation 193
10 Transient EPR 195
Stefan Weber
11 Pulse EPR 215
Stefan Stoll
12 EPR Instrumentation 235
Edward Reijerse and Anton Savitsky
13 EPR Imaging 261
Boris Epel and Howard J. Halpern
14 EPR Spectroscopy of Nitroxide Spin Probes 277
Enrica Bordignon
Part C: High-Resolution Pulse Techniques 303
15 FT-EPR 305
Michael K. Bowman, Hanjiao Chen, and Alexander G. Maryasov
16 Hyperfine Spectroscopy - ENDOR 331
Jeffrey R. Harmer
17 Hyperfine Spectroscopy - ELDOR-detected NMR 359
Daniella Goldfarb
18 Hyperfine Spectroscopy - ESEEM 377
Sabine Van Doorslaer
19 Dipolar Spectroscopy - Double-resonance Methods 401
Gunnar Jeschke
20 Dipolar Spectroscopy - Single-resonance Methods 425
Peter P. Borbat and Jack H. Freed
21 Shaped Pulses in EPR 463
Philipp E. Spindler, Philipp Schöps, Alice M. Bowen, Burkhard Endeward, and Thomas F. Prisner
Part D: Special Techniques 483
22 Pulse Techniques for Quantum Information Processing 485
Gary Wolfowicz and John J.L. Morton
23 Rapid-scan EPR 503
Gareth R. Eaton and Sandra S. Eaton
24 EPR Microscopy 521
Aharon Blank
25 Optically Detected Magnetic Resonance (ODMR) 537
Etienne Goovaerts
26 Electrically Detected Magnetic Resonance (EDMR) Spectroscopy 559
Christoph Boehme and Hans Malissa
27 Very-high-frequency EPR 581
Alexander Schnegg
Index 603
Abbreviations and Acronyms
1D one-dimensional AA Aharonov-Anandan ADMR absorption-detected magnetic resonance ADP adenosine diphosphate AFC automatic frequency control AFM atomic force microscopy AFP adiabatic fast passage AILFT ab initio ligand-field theory AO atomic orbital AOM angular overlap model ARS Advanced Research Systems ATP adenosine triphosphate AWG arbitrary waveform generator BDPA a,ß-bisphenylene-ß-phenylallyl-benzolate BEBOP broadband excitation by optimized pulses BIR4 $B_1$ insensitive rotation BO Born-Oppenheimer BP Breit-Pauli BPP Bloembergen, Purcell, Pound BW bandwidth BWO backward-wave oscillator C-NOT controlled-NOT C-PHASE controlled-phase CAP constant adiabaticity pulse CASPT2 complete active space second-order perturbation theory CASSCF complete active space self-consistent field CC coupled cluster CESR conduction electron-spin resonance CFT crystal field theory CIDEP chemically induced dynamic electron polarization CIDME chirp-induced dipolar modulation enhancement CLR cross-loop resonator CP combination-peak CPMG Carr-Purcell-Meiboom-Gill CPT coherence pathway transfer CSR coherent synchrotron radiation CT clock transitions CT coherence transfer CW continuous wave DAC digital-to-analog converter DC direct current DD dynamical decoupling DDBSQ 2,5-dichloro-3,6-dihydroxy-1,4-benzosemiquinone DDS direct digital synthesizer DEER double electron-electron resonance DEER ESE deadtime-free ESEEM by nuclear coherence-transfer echoes DFDMR delayed fluorescence detection of magnetic resonance DFG Deutsche Forschungsgemeinschaft DFT density functional theory DKH Douglas-Kroll-Hess DNP dynamic nuclear polarization DONUT double nuclear coherence transfer DPPH 2,2-diphenyl-1-picrylhydrazyl DQ double-quantum DQC double-quantum coherence DQF DQ filtering DQM double-quantum modulation DSV diameter spherical volume EC electron coherence ED-EPR echo-detected EPR EDDEER electrically detected double electron-electron resonance EDMR electrically detected magnetic resonance EFG electric field gradient EIK extended interaction klystron EIO extended interaction oscillator ELDOR electron-electron double resonance ELDOR-detected NMR electon-nuclear double resonance EP electron polarization EPR electron paramagnetic resonance EPRI EPR imaging EPRM EPR microscopy ESE electron spin echo ESEEM electron spin echo envelope modulation ET electron transfer EZ electron Zeeman f.w.h.h. flavin adenine dinucleotide FBP filtered backprojection FD-EPR frequency-domain EPR FD-FT THz-EPR fluorescence detection of magnetic resonance FDMR frequency-domain magnetic resonance FEL free-electron laser FFT fast Fourier transformation FID free induction decay FJ field-jump FMR ferromagnetic resonance FPGA field-programmable gate array FR Faraday rotator FRET fluorescence resonance energy transfer FT Fourier transform FT Fourier transformation FWHM full width at half maximum GGA generalized gradient approximation GIAOs gauge-including atomic orbitals GM Gifford-McMahon HAS hindered amine stabilizers HF Hartree-Fock HF high magnetic field HF hyperfine HFCs hyperfine couplings HFEPR high-frequency and high-field EPR HFHF high-field high-frequency HFI hyperfine interaction HFML High Field Magnet Laboratory HOMO highest occupied molecular orbital HS high-spin HTA high-turning-angle HWHH half width at half height hwhm half-width at half maximum HYSCORE hyperfine sublevel correlation ID instantaneous diffusion IF intermediate frequency INS inelastic neutron scattering IQ in-phase quadrature IRESE inversion recovery electron spin-echo ISC intersystem crossing ISHE inverse spin Hall effect JB Jeener-Broekaert KS Kohn-Sham KSM Kaplan, Solomon, and Mott LAC level anticrossing LAN local area network LCP left circular polarization LDA ``local density'' approximation LF-DFT ligand-field density functional theory LFT ligand-field theory LGR loop-gap resonator LHS left-hand side LiPc lithium phthalocyanine LMO localized molecular orbital LNA low-noise amplifier LO local oscillator LP lone-pair LUMO lowest unoccupied molecular orbital LWHH linewidth at half height MCD magnetic circular...
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