
Photochemistry
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Content
- Photochemistry
- Contents
- Introduction and Review of the Year
- Part I Physical Aspects of Photochemistry
- Photophysical Processes in Condensed Phases
- 1 Introduction
- 2 General Aspects of Photophysical Processes
- 3 Theoretical and Kinetic Considerations
- 4 Photophysical Processes in Liquid or Solid Media
- 4.1 Detection of Single Molecules
- 4.2 Radiative and Non-radiative Decay Processes
- 4.3 Amplitude or Torsional Motion
- 4.4 Light-induced Proton-transfer Reactions
- 4.5 Quenching of Excited States
- 4.5.1 Energy-transfer Reactions
- 4.5.2 Electron-transfer Reactions
- 4.6 Photophysics of Fullerenes
- 5 Applications of Photophysics
- 6 Advances in Instrument Design and Utilisation
- 6.1 Data Analysis
- 6.2 Instrumentation
- 7 References
- Part II Organic Aspects of Photochemistry
- 1 Photolysis of Carbonyl Compounds
- 1 Norrish Type I Reactions
- 2 Norrish Type II Reactions
- 2.1 1,5-Hydrogen Transfer
- 2.2 Other Hydrogen Transfers
- 3 Oxetane Formation
- 4 Miscellaneous Reactions
- 4.1 Decarbonylation and Decarboxylation
- 4.2 Reactions of Miscellaneous Haloketones and Acid Chlorides
- 4.3 Other Processes
- 5 References
- 2 Enone Cycloadditions and Rearrangements: Photoreactions of Dienones and Quinones
- 1 Cycloaddition Reactions
- 1.1 Intermolecular Cycloaddition
- 1.1.1 Open-chain Systems
- 1.1.2 Additions to Cyclopentenones and Related Systems
- 1.1.3 Additions to Cyclohexenones and Related Systems
- 1.2 Intramolecular Additions
- 1.2.1 Intramolecular Additions to Cyclopentenones
- 1.2.2 Additions to Cyclohexenones and Related Systems
- 2 Rearrangement Reactions
- 2.1 a,ß-Unsaturated Systems
- 2.1.1 Isomerisation
- 2.1.2 Hydrogen Abstraction Reactions
- 2.1.3 Rearrangement Reactions
- 2.2 ß,?-Unsaturated Systems
- 2.2.1 The Oxa Di-p-methane Reaction and Related Processes
- 2.2.2 Other Rearrangements
- 3 Photoreactions of Thymines and Related Compounds
- 3.1 Photoreactions of Pyridones
- 3.2 Photoreactions of Thymines etc.
- 3.3 Miscellaneous Processes
- 4 Photochemistry of Dienones
- 4.1 Cross-conjugated Dienones
- 4.2 Linearly Conjugated Dienones
- 5 1,2-, 1,3- and 1,4-Diketones
- 5.1 Reactions of 1,2-Diketones and Other 1,2-Dicarbonyl Compounds
- 5.2 Reactions of 1,3-Diketones
- 5.3 Reactions of 1,4-Diketones
- 5.3.1 Phthalimides and Related Compounds
- 5.3.2 Fulgides and Fulgimides
- 6 Quinones
- 6.1 o-Quinones
- 6.2 p-Quinones
- 7 References
- 3 Photochemistry of Alkenes, Alkynes and Related Compounds
- 1 Reactions of Alkenes
- 1.1 cis,trans-Isomerisation
- 1.1.1 Stilbenes and Related Compounds
- 1.1.2 The Dithienylethene System and Related Compounds
- 1.2 Miscellaneous Reactions
- 1.2.1 Addition Reactions
- 1.2.2 Electron-transfer Processes
- 1.2.3 Other Processes
- 2 Reactions Involving Cyclopropane Rings
- 2.1 The Di-p-methane Rearrangement and Related Processes
- 2.1.1 The Aza-di-p-methane Rearrangement and Related Processes
- 2.2 Miscellaneous Reactions Involving Three-membered Ring Compounds
- 3 Reactions of Dienes and Trienes
- 3.1 Vitamin D Analogues
- 4 (2p+2p)-Intramolecular Additions
- 5 Dimerisation and Intermolecular Additions
- 5.1 Dimerisation
- 6 Miscellaneous Reactions
- 6.1 Reactions Involving Cations and Radicals
- 6.2 Miscellaneous Rearrangements and Bond Fission Processes
- 7 References
- 4 Photochemistry of Aromatic Compounds
- 1 Introduction
- 2 Isomerisation Reactions
- 3 Addition Reactions
- 4 Substitution Reactions
- 5 Cyclisation Reactions
- 6 Dimerisation Processes
- 7 Lateral Nuclear Shifts
- 8 Miscellaneous Photochemistry of Aromatic Systems
- 9 References
- 5 Photo-reduction and -oxidation
- 1 Introduction
- 2 Reduction of the Carbonyl Group
- 3 Reduction of Nitrogen-containing Compounds
- 4 Miscellaneous Reductions
- 5 Singlet Oxygen
- 6 Oxidation of Aliphatic Compounds
- 7 Oxidation of Aromatic Compounds
- 8 Oxidation of Nitrogen-containing Compounds
- 9 Miscellaneous Oxidations
- 10 References
- 6 Photoreactions of Compounds Containing Heteroatoms Other than Oxygen
- 1 Introduction
- 2 Nitrogen-containing Compounds
- 2.1 E,Z Isomerisations
- 2.2 Photocyclisations
- 2.3 Photoadditions
- 2.4 Other Processes
- 3 Sulfur-containing Compounds
- 4 Compounds Containing Other Heteroatoms
- 4.1 Silicon and Germanium
- 4.2 Phosphorus
- 4.3 Other Elements
- 5 References
- 7 Photoelimination
- 1 Introduction
- 2 Elimination of Nitrogen from Azo Compounds and Analogues
- 3 Elimination of Nitrogen from Diazo Compounds and Diazirines
- 3.1 Generation of Alkyl, Alicyclic and Heterocyclic Carbenes
- 3.2 Generation of Aryl and Heteroaryl Carbenes
- 3.3 Photolysis of Diazo Carbonyl Compounds and Sulfur Analogues
- 4 Elimination of Nitrogen from Azides
- 5 Photoelimination of Carbon Monoxide and Carbon Dioxide
- 5.1 Photoelimination of CO from Organometallic Compounds
- 6 Photoelimination of NO and NO2
- 7 Miscellaneous Photoeliminations and Photofragmentations
- 7.1 Photoelimination from Hydrocarbons
- 7.2 Photoelimination from Organohalogen Compounds
- 7.3 Photofragmentations of Organosilicon and Organogermanium Compounds
- 7.4 Photofragmentations of Organosulfur, Organoselenium and Organotellurium Compounds
- 7.5 Photolysis of o-Nitrobenzyl Derivatives and Related Compounds
- 7.6 Other Photofragmentations
- 8 References
- Part III Polymer Photochemistry
- 1 Introduction
- 2 Photopolymerization
- 2.1 Photoinitiated Addition Polymerization
- 2.2 Photocrosslinking
- 2.3 Photografting
- 3 Luminescence and Optical Properties
- 4 Photodegradation and Photooxidation Processes in Polymers
- 4.1 Polyolefins
- 4.2 Polystyrenes
- 4.3 Poly(acrylates) and Poly(alkyl acrylates)
- 4.4 Polyesters
- 4.5 Polyamides and Polyimides
- 4.6 Poly(alkyl and aromatic ethers)
- 4.7 Silicone Polymers
- 4.8 Polyurethanes and Rubbers
- 4.9 Poly(vinyl halides)
- 4.10 Photoablation of Polymers
- 4.11 Natural Polymers
- 4.12 Miscellaneous Polymers
- 5 Photostabilization of Polymers
- 6 Photochemistry of Dyed and Pigmented Polymers
- 7 References
- Part IV Photochemical Aspects of Solar Energy Conversion
- 1 Introduction
- 2 Homogeneous Photosystems
- 3 Heterogeneous Photosystems
- 4 Photoelectrochemical Cells
- 5 Biological Systems
- References
- Author Index
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