
Photochemistry
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Content
- Photochemistry
- Contents
- Introduction and Review of the Year
- Part I Physical Aspects of Photochemistry
- Photophysical Processes in Condensed Phases
- 1 Introduction
- 2 General
- 3 Singlet State Processes
- 3.1 Electron and Proton Transfer Reactions and Exciplexes
- 3.2 Dyes
- 3.3 Photoisomerization and Related Proceses
- 3.4 Electronic Excitation Energy Transfer
- 3.5 Polymeric Systems
- 3.6 Colloidal and Heterogenous Systems
- 3.7 Biological Systems
- 4 Triplet State Processes
- 5 Other Processes
- 5.1 Chemiluminescence
- 5.2 Photochromism
- 5.3 Photochemical Reactions
- References
- Part II Organic Aspects of Photochemistry
- Chapter 1 Photolysis of Carbonyl Compounds
- 1 Norrish Type I Reactions
- 2 Norrish Type II Reactions
- 2.1 1 ,5-Hydrogen Transfer
- 2.2 Other Hydrogen Transfers
- 3 Oxetane Formation
- 4 Miscellaneous Reactions
- 4.1 SET Processes
- 4.2 Decarbonylation and Decarboxylation
- 4.3 Reactions of Miscellaneous Haloketones
- 4.4 Miscellaneous Fission Processes
- References
- Chapter 2 Enone Cycloadditions and Rearrangements
- Photoreactions of Dienones and Quinones
- 1 Cycloaddition Reactions
- 1.1 Intermolecular Cycloadditions
- 1.1.1 Open-chain Systems
- 1.1.2 Additions to Cyclopentenones and Related Systems
- 1.1.3 Additions to Cyclohexenones and Related Systems
- 1.2 Intramolecular Cyccloadditions
- 1.2.1 Additions to Cyclopentenones
- 1.2.2 Additions to Cyclohexenones and Related Systems
- 1.3 Miscellaneous Additions
- 2 Rearrangement Reactions
- 2.1 a,p-Unsaturated Systems
- 2.1.1 Isomerization
- 2.1.2 Cyclizations and Rearrangements
- 2.2 ß,?-Unsaturated Systems
- 2.2.1 Oxa-di-n-methane Reactions and Related Processes
- 2.2.2 Miscellaneous Processes
- 3 Photoreactions of Thymines and Related Compounds
- 3.1 Photoreactions of Pyridones
- 3.2 Photoreactions of Thymines etc.
- 4 Photochemistry of Dienones
- 4.1 Cross-conjugated Dienones
- 4.2 Linearly Conjugated Dienones
- 5 1,2-, 1,3- and 1,4-Diketones
- 5.1 Reactions of 1,2-Diketones
- 5.2 Reactions of 1,3-Diketones
- 5.3 Reactions of 1,4-Diketones
- 5.3.1 Phthalimides and Related Compounds
- 5.3.2 Fulgides and Fulgimides
- 5.3.3 Other 1,4-Dicarbonyl Compounds
- 6 Quinones
- 6.1 o-Quinones
- 6.2 p-Quinones
- References
- Chapter 3 Photochemistry of Alkenes, Alkynes, and Related Compounds
- 1 Reactions of Alkenes
- 1.1 cis,trans-Isomerization
- 1.1.1 Stilbenes and Related Compounds
- 1.2 Addition and Cyclization Reactions
- 1.2.1 SET Induced Reactions
- 1.2.2 Addition Reactions
- 1.2.3 Cyclizations
- 1.2.4 Ring Opening Reactions
- 1.2.5 Miscellaneous Reactions
- 2 Reactions involving Cyclopropane Rings
- 2.1 The Di-p-methane Rearrangement and Related Processes
- 2.1.1 Barrelene Derivatives
- 2.1.2 The Aza-di-p-methane Rearrangement and Related Processes
- 3 Reactions of Dienes, Trienes and Higher Polyenes
- 3.1 Reactions of Dienes and Trienes
- 3.1.1 Vitamin D Analogues
- 4 (2 + 2)-Intramolecular Additions
- 4.1 Cage Compounds
- 4.2 Cyclobutane Formation
- 5 Dimerization and Intermolecular Additions
- 5.1 Dimerization
- 5.2 (2 + 2)-Cycloaddition Reactions
- 6 Miscellaneous Reactions
- 6.1 Reactions involving Cations and Radicals
- 6.2 Miscellaneous Rearrangements and Bond Fission Processes
- References
- Chapter 4 Photo-reduction and -oxidation
- 1 Introduction
- 2 Reduction of the Carbonyl Group
- 3 Reduction of Nitrogen-containing Compounds
- 4 Miscellaneous Reductions
- 5 Singlet Oxygen
- 6 Oxidation of Aliphatic Compounds
- 7 Oxidation of Aromatic Compounds
- 8 Oxidation of Nitrogen-containing Compounds
- 9 Miscellaneous Oxidations
- References
- Chapter 5 Photoreactions of Compounds containing Heteroatoms other than Oxygen
- 1 Introduction
- 2 Nitrogen-containing Compounds
- 2.1 Rearrangements
- 2.2 Addition Reactions
- 2.3 Miscellaneous Processes
- 3 Sulfur-containing Compounds
- 4 Compounds Containing Other Heteroatoms
- References
- Chapter 6 Photoelimination
- 1 Elimination of Nitrogen from Azo-compounds
- 2 Elimination of Nitrogen from Diazo-compounds
- 3 Elimination of Nitrogen from Azides
- 4 Photoelimination of Carbon Dioxide
- 5 Photofragmentation of Organosulfur Compounds
- 6 Miscellaneous Decomposition and Elimination Reactions
- References
- Part III Polymer Photochemistry
- 1 Introduction
- 2 Photopolymerisation
- 2.1 Photoinitiated Addition Polymerisation
- 2.2 Photografting
- 2.3 Photocrosslinking
- 3 Polymer Luminescence
- 4 Photodegradation and Photooxidation of Polymers
- 4.1 Polyoelfins
- 4.2 Poly (vinyl halides)
- 4.3 Poly (acrylates) and (alkyl acrylates)
- 4.4 Polyamides and Polyimides
- 4.5 Polystyrenes and Copolymers
- 4.6 Polyesters
- 4.7 Silicone Polymers
- 4.8 Polycarbonate
- 4.9 Rubbers and Elastomers
- 4.10 Photoablation of Polymers
- 4.11 Wool
- 4.12 Cellulose
- 4.13 Miscellaneous Polymers
- 5 Photostabilisation of Polymers
- 6 Photochemistry of Dyed and Pigmented Polymers
- References
- Part IV Photochemical Aspects of Solar Energy Conversion
- 1 Introduction
- 2 Homogeneous Photosystems
- 3 Heterogeneous Photosystems
- 4 Photoelectrochemical Cells
- 5 Biological Systems
- References
- Author Index
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