
Surface Processing and Laser Assisted Chemistry
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Content
- Front Cover
- Surface Processing and Laser Assisted Chemistry
- Copyright Page
- Table of Contents
- Preface
- Conference organisation
- Supporting organisations and sponsors
- PART I: PRECURSORS FOR SURFACE PROCESSING
- Chapter 1. New metallo-organic precursors for surface processing
- 1. Introduction
- 2. Metal films
- 3. Metal oxide films
- 4. Metal nitride films
- 5. Metal fluoride films
- 6. Compound semiconductors
- 7. Conclusions
- References
- Chapter 2. Design and synthesis of CVD precursors to thin film ceramic materials
- 1. Introduction
- 2. Experimental section
- 3. Results and discussion
- Acknowledgments
- References
- Chapter 3. The photolytic laser chemical vapor deposition rate of platinum, its dependence on wavelength, precursor vapor pressure, light intensity, and laser beam diameter
- 1. Introduction
- 2. Experimental
- 3. Results and discussion
- 4. Conclusions
- Acknowledgements
- References
- Chapter 4. Photoprocesses in organometallics
- 1. Introduction
- 2. Metal alkyls
- References
- Chapter 5. Preferential (111) orientation of ZnSe on (100) GaAs deposited by laser-induced MOCVD
- 1. Introduction
- 2. Experimental
- 3. Results
- 4. Discussion
- 5. Conclusions
- References
- Chapter 6. The adsorption of triethylgallium on GaAs(100) at 300 K: adsorption kinetics from optical second harmonic generation transients
- 1. Introduction
- 2. Theory
- 3. Results and discussion
- 4. Conclusions
- Acknowledgements
- References
- Chapter 7. Photoreactions of adsorbed CH3Br on Pt(111)
- 1. Introduction
- 2. Experimental
- 4. Summary and conclusions
- Acknowledgements
- References
- Chapter 8. Second harmonic generation of C02-laser radiation and FTIR spectroscopy for resonant desorption in the adsorbate CO-NaCl(100)
- 1. Introduction
- 2. SHG of C02 laser radiation for resonant desorption
- 3. Experimental
- 4. CO on NaCl(100) - a model adsorbate for studying laser energy transfer
- 5. Results and discussion
- 6. Summary and conclusions
- Acknowledgements
- References
- PART II: DEPOSITION
- SECTION II-l: SUPERCONDUCTORS
- Chapter 9. High- Tc YBa2 Cu3 O7-8 prepared by chemical vapour deposition
- 1. Introduction
- 2. Experiments
- 3. Results
- 4. Conclusion
- Acknowledgements
- References
- Chapter 10. Deposition, characterization, and laser ablation patterning of YBCO thin films
- 1. Introduction
- 2. Experimental set-up
- 3. Film preparation
- 4. Film characteristics
- 5. Laser ablation lithography
- 6. Summary
- References
- Chapter 11. Computer-controlled ion beam deposition systems for high Tc superconductor and other multi-component oxide thin films and layered structures
- 1. Introduction
- 2. Description of the SBMT deposition system
- 3. Results
- 4. Conclusion
- Acknowledgement
- References
- Chapter 12. High quality YBa2Cu3Ox ultra-thin films and Y/Pr/Y multilayers made by a modified RF-magnetron sputtering technique
- 1. Introduction
- 2. Experimental
- 3. Results and discussions
- 4. Conclusions
- References
- Chapter 13. Characterization of the KrF laser-induced plasma plume created above an YBaCuO superconducting target and preparation of superconducting thin films
- 1. Introduction
- 2. Experimental set-up
- 3. Results and discussion
- 4. Conclusion
- Acknowledgment
- References
- Chapter 14. Laser-ablation deposition of uniform thin films of Bi2Sr2CaCu20x
- 1. Introduction
- 2. Mathematical analysis
- 3. Experimental studies
- 4. Conclusion
- Acknowledgements
- References
- Chapter 15. An investigation of laser ablation and deposition of Y-Ba-Cu-O in an oxygen environment
- 1. Introduction
- 2. Experimental
- 3. Results
- 4. Plume dynamics - analysis
- 5. Plume range
- 6. Deposition experiments
- 7. Conclusions
- Acknowledgements
- References
- SECTION I-2: METALS
- Chapter 16. Simulation of laser CVD
- 1. Introduction
- 2. Basic equations
- 3. Calculations, comparison with analytical expressions
- Acknowledgement
- References
- Chapter 17. Gas-phase transport and kinetics in pulsed-laser CVD
- 1. Introduction
- 2. Model
- 3. Discussion
- Acknowledgements
- References
- Chapter 18. High performance contact formation in LSI circuit restructuring using visible pulse laser induced ablation and CVD
- 1. Introduction
- 2. Experiment
- 3. Results
- 4. Summary
- References
- Chapter 19. Laser-assisted deposition for electronic packaging applications
- 1. Introduction
- 2. Factors influencing the LAD process
- 3. Effect of laser parameters
- 4. Prenucleation with palladium
- 5. Concentration of the precursor
- 6. Influence of the substrate material
- 7. Surface pretreatment
- 8. Applications
- References
- Chapter 20. Multichip packaging for very-high-speed digital systems
- Acknowledgment
- References
- Chapter 21. Optimization of the laser-induced deposition technique for its application in X-ray mask repair
- 1. Introduction
- 2. Experimental
- 3. Deposition processes
- 4. Experimental results
- 5. Repair results
- 6. Comparison with electron- and ion-induced deposition
- 7. Conclusion
- Acknowledgements
- References
- Chapter 22. HF formation in laser-induced CVD of tungsten
- 1. Introduction
- 2. Experimental
- 3. Results
- 4. Discussion
- 5. Conclusions
- Acknowledgements
- References
- Chapter 23. Laser direct writing of copper on various thin-film substrate materials
- 1. Introduction
- 2. Experimental
- 3. Results
- 4. Conclusion
- References
- Chapter 24. Direct writing of conducting traces by chemical modification of sohd coatings with laser radiation
- 1. Introduction
- 2. Experimental set-up
- 3. Results
- 4. Conclusions
- References
- Chapter 25. VUV synchrotron radiation processing of thin palladium acetate spin-on films for metallic surface patterning
- 1. Introduction
- 2. Experiment
- 3. Spectrometric study of chemical changes
- 4. Discussion
- 5. Conclusion
- Acknowledgments
- References
- Chapter 26. Investigation of the mechanism of the UV-induced palladium deposition process from thin solid palladium acetate films
- 1. Introduction
- 2. Experimental
- 3. Results and discussion
- 4. Conclusions
- References
- Chapter 27. Laser evaporation of metal sandwich layers for improved IC metallization
- 1. Introduction
- 2. Experimental set-up
- 3. Experimental results
- 4. Conclusion
- Acknowledgements
- References
- SECTION II-3: INSULATORS AND REFRACTORY MATERIALS
- Chapter 28. Filling of Si oxide into a deep trench using digital CVD method
- 1. Introduction
- 2. TMS/02 and TES /02 reaction systems
- 3. TES/H2 - O2 reaction system
- 4. Conclusion
- Acknowledgement
- References
- Chapter 29. Photo-assisted deposition of thin films on III-V semiconductors with UV and IR lamps
- 1. Introduction
- 2. Build-up of semiconductor/insulator interfaces in CVD and UVCVD
- 3. High-sensitivity infrared spectroscopy for the study of the InP/Si02 interface
- 4. Silicon nitride deposition by "flash" CVD
- 5. Deposition of semiconductors and metals
- 6. Conclusions
- Acknowledgments
- References
- Chapter 30. Si02 deposition by direct photolysis at 185 nm of N2O and SiH4
- 1. Introduction
- 2. Experimental
- 3. Results
- 4. Modelling of the deposition mechanism
- Appendix A
- References
- Chapter 31. Deposition of Si02 by reactive excimer laser ablation from a SiO target
- 1. Introduction
- 2. Experimental
- 3. Results and discussion
- 4. Conclusion
- References
- Chapter 32. Sol-gel low-temperature preparation of silica films: RBS, TEM and MOS C- V characterization
- 1. Introduction
- 2. Experimental procedure
- 3. High-resolution transmission electron microscopy
- 4. RBS analysis
- 5. MOS C-V analysis
- Acknowledgements
- References
- Chapter 33. Gas mixture dependence of the LCVD of Si02 films using an ArF laser
- 1. Introduction
- 2. Experimental
- 3. Results
- 4. Conclusions
- Acknowledgements
- References
- Chapter 34. Excimer laser deposition of silica films: a comparison between two methods
- 1. Introduction
- 2. Experimental
- 3. Results
- 4. Sample properties
- 5. Conclusions
- Acknowledgements
- References
- Chapter 35. Photochemical vapor deposition of titaniumdiboride
- 1. Introduction
- 2. Experimental
- 3. Results and discussion
- 4. Conclusion
- Acknowledgment
- References
- Chapter 36. In situ formation of ionic carbide clusters by laser ablation
- 1. Introduction
- 2. Experimental
- 3. Results and discussion
- References
- Chapter 37. Synthesis of ultrafine Ti02 powders by a CW C02 laser
- 1. Introduction
- 2. Experimental
- 3. Results and discussion
- 4. Conclusions
- References
- SECTION II-4: SEMICONDUCTORS
- Chapter 38. On the role of the substrate position in the C02 laser CVD of amorphous hydrogenated silicon
- 1. Introduction
- 2. Experimental part
- 3. Results and discussion
- Acknowledgements
- References
- Chapter 39. Laser CVD of a-Si:H from SiH4 and Si2H6: relations between chemistry, growth rate and film properties
- 1. Introduction
- 2. Experimental
- 3. Results
- 4. Discussion
- Acknowledgements
- References
- Chapter 40. Picosecond YAG laser photoablation of amorphous silicon
- 1. Introduction
- 2. Experimental details
- 3. Results and discussion
- 4. Summary
- References
- Chapter 41. The influence of deposition parameters on the growth of a-SiGe:H alloys in a plasma CVD system
- 1. Introduction
- 2. Experimental
- 3. Results
- 4. Discussion and conclusions
- References
- Chapter 42. Good-quality Ge films grown by excimer laser deposition
- 1. Introduction
- 2. Experimental
- 3. Results and discussion
- 4. Conclusions
- Acknowledgments
- References
- PART III: DESORPTION, ABLATION, ETCHING AND PATTERNING
- Chapter 43. Industrial laser applications
- 1. Introduction
- 2. Preconditions for the use of novel production processes: reflections from the developer's standpoint
- 3. Some examples of laser application in production lines
- 4. The first application of KrF excimer lasers in a production line for high-density-multilayer printed circuit boards
- 5. Use of excimer lasers in production
- 6. Conclusion
- References
- Chapter 44. Surface modifications of Kapton and cured polyimide films by ArF excimer laser: applications to imagewise wetting and metallization
- 1. Introduction
- 2. Experimental
- 3. Results
- 4. Discussion
- References
- Chapter 45. Excimer laser ablation of polyimide
- 1. Introduction
- 2. Experimental
- 3. Results and discussions
- 4. Conclusions
- Acknowledgements
- References
- Chapter 46. Photochemically assisted laser ablation of doped polymethyl-methacrylate
- 1. Introduction
- 2. Experimental
- 3. Results
- 4. Discussion
- References
- Chapter 47. Picosecond time-resolved laser desorption
- 1. Introduction
- 2. Experimental
- 3. Results
- 4. Discussion
- 5. Summary
- Acknowledgement
- References
- Chapter 48. Mechanisms of photon-stimulated desorption and chemisorption of atomic particles on the surfaces of semiconductors and metals
- 1. Introduction
- 2. Cross-section of single-photon bound-free transition
- 3. Electrical field effect on the cross-section
- References
- Chapter 49. Surface temperature measurements using pyrometry during excimer laser pulsed etching of silicon in a Cl2 environment
- 1. Introduction
- 2. Experimental
- 3. Results
- 4. Calculations
- 5. Discussion
- 6. Conclusions
- References
- Chapter 50. Reactive ion beam etching of Si/Si02 systems using SF6/02 chemistry
- 1. Introduction
- 2. Experimental set-up
- 3. Results and discussion
- 4. Conclusion
- Acknowledgments
- References
- Chapter 51. On the two- and three-dimensional simulation of ion-milled structures
- 1. Introduction
- 2. Structure profile /topography algorithm
- 4. Application of algorithm
- 5. Conclusions
- Ackowledgement
- References
- Chapter 52. Spectroscopic study of the plasma created by interaction between a TEA C02 laser beam and a Ti target in a cell containing helium gas
- 1. Introduction
- 2. Experimental set-up
- 3. Diagnostics
- 4. Results
- 5. Modelling
- 6. Conclusion
- Acknowledgement
- References
- Chapter 53. Luminescence and ESCA analysis of laser-ablated materials
- 1. Introduction
- 2. Experimental
- 3. Results and discussion
- Acknowledgements
- References
- PART IV. PHOTON AND ION SURFACE MODIFICATIONS
- Chapter 54. Controlled structuring of polymer surfaces by UV-laser irradiation
- 1. Introduction
- 2. Experimental
- 3. Emperical observations
- 4. The model
- References
- Chapter 55. Ion-beam-assisted formation of interconnections into high temperature polymers
- 1. Introduction
- 2. Ion-beam-induced conductivity in polymers
- 3. Field of application
- 4. Role of the ion beam parameters
- 5. Conclusions
- References
- Chapter 56. Laser-induced photochemical adherence enhancement
- 1. Introduction
- 2. Experimental
- 3. Results and discussion
- 4. Conclusion
- Acknowledgement
- References
- Chapter 57. Application of doping and dedoping of Teflon AF films in microfabrication using KrF and ArF excimer lasers
- 1. Introduction
- 2. Experimental
- 3. Results and discussion
- Acknowledgment
- References
- Chapter 58. Ultra-flat p-n junctions formed by solid source laser doping
- 1. Introduction
- 2. Experimental procedure
- 3. Theoretical background
- 4. Experimental results
- 5. Conclusion
- Acknowledgements
- References
- Chapter 59. Low temperature VUV enhanced growth of thin silicon dioxide films
- 1. Introduction
- 2. Experimental system and procedures
- 3. Results and discussion
- 4. Influence of VUV photons on the electrical properties
- 5. Conclusions
- Acknowledgements
- References
- Chapter 60. Chemical reactions at solid-solid interfaces induced by pulsed laser annealing
- 1. Introduction
- 2. Experimental details
- 3. Experimental results
- 4. Discussion
- 5. Conclusions
- Acknowledgements
- References
- Chapter 61. Nitridation of titanium by multipulse excimer laser irradiation
- 1. Introduction
- 2. Experimental apparatus
- 3. Experimental results
- 4. Discussion
- 5. Conclusions
- Acknowledgements
- References
- Chapter 62. Annealing kinetics during rapid thermal processing of excimer laser-induced defects in virgin silicon
- 1. Introduction
- 2. Experiments
- 3. Results and discussion
- 4. Conclusion
- References
- Chapter 63. Influence of the substrate on the temperature induced by pulsed laser irradiation of thin films
- 1. Introduction
- 2. Numerical simulation
- 3. Results and discussion
- 4. Conclusions
- References
- Chapter 64. Pulsed excimer and Nd:YAG laser crystallization of a-Si:H The specific role of hydrogen
- 1. Introduction
- 2. Experimental
- 3. Results and discussions
- 4. Conclusion
- References
- Chapter 65. The influence of the substrate on the transformations induced in Si by nanosecond laser irradiation: a time-resolved study
- 1. Introduction
- 2. Experimental procedure
- 3. Results
- 4. Discussion
- 5. Conclusions
- Acknowledgements
- References
- Chapter 66. Investigation of laser recrystallization of thin Si films using numerical simulation
- 1. Introduction
- 2. Modelling
- 3. Beam shaping
- 4. Integrated absorber
- 5. Micro-absorber
- Acknowledgements
- References
- Chapter 67. Time-resolved TEM of laser-induced structural changes in GeTe films
- 1. Introduction
- 2. Experimental procedure
- 3. Experimental results
- 4. Discussion/conclusion
- Acknowledgement
- References
- Chapter 68. Thermal evolution of W/Si and W/C multilayers under pulsed laser heating and classical annealing
- 1. Introduction
- 2. Experimental conditions
- 3. Results
- 4. Discussion
- Acknowledgments
- References
- Chapter 69. Diffusion and microstructures induced by excimer laser irradiation in Ge-Sb thin film bilayers
- 1. Introduction
- 2. Experimental method
- 3. Results
- 4. Discussion
- Acknowledgements
- References
- Chapter 70. Morphological improvement of zinc electrodeposits by laser assistance
- 1. Introduction
- 2. Materials and experimental procedure
- 3. Electrochemical and metallurgical aspects of the classical electrodeposition of zinc
- 4. Influence of laser assistance on the electrochemical aspect
- 5. Influence of laser assistance on the metallurgical aspect
- 6. Conclusion
- Acknowledgements
- References
- Chapter 71. CW laser-induced transformation of thin Sb, Se and Sb2Se3 films in air
- 1. Introduction
- 2. Experimental
- 3. Results
- 4. Discussion
- 5. Conclusions
- Acknowledgements
- References
- Chapter 72. Instability and structural transformation of amorphous ultra-thin W-Si multilayer structures during heavy ion irradiation
- 1. Experiments
- 2. Results and discussion
- 3. Conclusions
- Acknowledgments
- References
- Chapter 73. Crystallization of Fe-Zr metallic glasses during ion irradiation
- 1. Introduction
- 2. Experimental details
- 3. Results and discussion
- References
- Chapter 74. Glass surface treatment with excimer and C02 lasers
- 1. Introduction
- 2. Experimental set-up
- 3. Interaction of laser beams with glasses
- 4. Surface treatment with C02 laser
- 5. Excimer laser ablation of glasses
- 5. Conclusion
- References
- PART V: ADVANCED TECHNIQUES OF CHARACTERISATION
- Chapter 75. Hydrogen plasma treatment of silicon surfaces studied by in-situ spectroscopic ellipsometry
- 1. Introduction
- 2. Experimental
- 3. Results and discussion
- References
- Chapter 76. Scanning tunneling microscopy and technical applications
- 1. Introduction
- 2. Applications in magnetic storage device manufacturing
- 3. Instrumental
- 4. STM applications on substrates of magnetic recording disks
- 5. Advanced techniques
- 6. Conclusion
- References
- Chapter 77. Femtosecond transient reflectivity measurements as a probe for process-induced defects in silicon
- 1. Introduction
- 2. Experimental
- 3. Physics, measurements and applications
- 4. Conclusion
- Acknowledgements
- References
- Chapter 78. In situ silicon solid state regrowth kinetics measurement in a rapid thermal processor
- 1. Introduction
- 2. Experimental methods
- 3. Results and discussion
- 4. Conclusion
- References
- Author index
- Subject index
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