
Colloid Science
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Content
- Colloid Science
- Contents
- Chapter 1 Adsorption on Heterogeneous Surfaces
- 1 Introduction
- The Development and Early Solutions of the Integral Equation of Adsorption
- Extensions of the Adsorption Model to Include Adsorbate Lateral Interactions
- Terminology
- Unisorptic Surface
- Homotattic Surface
- Intrinsic Heterogeneity
- Patch
- Residual Heterogeneity
- 2 Solutions of Fredhohn Equations of the First Kind
- Introduction
- General Numerical Methods of Solution
- The Matrix Regularization Approach
- Approximation of the Kernel
- Optimization Methods Involving a Generalized Form of f(y)
- Numerical Iterative Methods of Solution
- General Analytical Methods of Solution
- Method of Stieltjes Transform
- Method of Laplace Transform
- 3 Adsorption on Unisorptic and Homotattic Surfaces
- Adsorption Isotherms on Homogenous Surfaces
- Intrinsic Heterogeneity
- Interrelation Between the Adsorbate Partition Function and the Adsorption Energy
- Local Isotherm Equations
- The Langmuir Equation
- The Jovanovic Equation
- The Fowler-Guggenheim Equation
- The Hill-de Boer Equation
- The Virial Equation for an Imperfect Two-dimensional Gas
- Associated Adsorbate Model
- 4 Applications of the Integral Equation of Adsorption
- Introduction
- Generation of Total Isotherms by using a Generalized Distribution Function and Assuming a Local Isotherm Equation
- Determination of Distribution Function for Generalized Total Isotherm Equations
- Applications of Hobson's Method
- Results of the Numerical Iterative Method
- Applications of the Adamson and Ling Method
- The HILDA Algorithm
- The CAEDMON Algorithm
- Results from Specific Adsorption Systems
- Argon Adsorbed on Titanium Dioxide (Rutile)
- Adsorption on Silica
- 5 The Random Heterogeneous Model of Adsorption
- 6 The Role of Surface Heterogeneity in MultilayerAdsorption
- 7 Heterogeneity Effects in Adsorption from Solution
- Comparisons with Adsorption from Binary Gas Mixtures
- Adsorption from Binary Liquid Mixtures
- Chapter 2 The Dubinin-Radushkevich (DR) Equation: History of a Problem and Perspectives for a Theory
- 1 Introduction
- 2 The Proposal of Dubinin and Radushkevich
- 3 Surface Heterogenity
- 4 The Onset of the Henry Law
- 5 Equilibrium Surfaces
- 6 Adsorption on Equilibrium Surfaces
- Weak Heterogeneity
- Strong Heterogeneity
- 7 An Extension: Desorption Kinetics
- Weakly Heterogeneous Surfaces
- Strongly Heterogeneous Surfaces
- 8 Perspectives
- Films
- Proteins
- Topography
- 9 Conclusions
- Acknowledgments
- Chapter 3 Adsorption from Solution
- 1 Introduction
- 2 Thermodynamics
- General Considerations
- Surface Activity Coefficients
- Thermodynamic Data
- 3 Dilute Solutions
- General
- Two-component Aqueous Systems
- Adsorption of Weak Electrolytes
- Multisolute Adsorption from Dilute Aqueous Solutions
- 4 Experimental Techniques
- 5 Surface Area Determination
- 6 Spectroscopic Studies
- 7 Studies of Specific Systems
- Carbon
- Oxides
- Clays
- Zeolites
- Miscellaneous Adsorbents
- 8 Conclusions
- Chapter 4 Statistical Mechanics of Colloidal Suspensions
- 1 Introduction
- 2 Formalism and Methodology
- Liquid-state Background
- Distribution and Correlation Functions
- Computer Simulation
- 3 Order-Disorder Phase Transitions
- Numerical Results and Approximate Theories
- Wigner Lattice Model
- The Onsanger Transition
- 4 Structure from Light Scattering
- Time-averaged Light Scattering
- Light-scattering Studies of Floc Structure
- Photon Correlation Spectroscopy
- 5 Osmotic Equation of State
- 6 Polydispersity
- Thermodynamics of Polydisperse Systems
- Light Scattering from Polydisperse Systems
- 7 Time-dependent Behaviour
- Neglect of Hydrodynamic Interactions
- Effect of Hydrodynamic Forces between Particles
- Chapter 5 Micellar Structure and Catalysis
- 1 Introduction
- 2 Micellar Structure and Solubilization
- Computational Aspects
- Critical Micelle Concentrations
- Properties of Micelles
- Scattering Techniques
- Solubilization
- 3 Magnetic Resonance
- Electron Spin Resonance
- Proton Magnetic Resonance
- Carbon Magnetic Resonance
- Magnetic Resonance of Other Nuclei
- 4 Dynamics of Micelle Formation and Breakdown
- Theory
- Experiment
- 5 Reactions in Micelles
- Micellar Effects on Chemical Equilibria
- Reactions Catalysed by Simple Cationic Micelles
- Other Catalysed Reactions in Cationic Micelles
- Oxidation and Reduction
- Reactions Catalysed by Anionic Micelles
- Micellar Effects on Inorganic Reactions
- 6 Organic Reactions in Functional Micelles
- 7 Bicatenate Surfactants
- Structure and Catalysis
- Kinetics of Catalysed Reactions
- Excited-state Phenomena
- 8 Excited-state Chemistry in Micelles
- Radiolysis and Related Techniques
- Quenching of Excited States
- Photoionization and Electron Transfer from Excited States
- Organic Photoreactions in Micelles
- Chapter 6 A Bibliography of Gas-Liquid Surface Tensions for Binary Fluid Mixtures
- 1 Introduction
- 2 Compilation of Data on Binary Liquid Mixtures
- 3 References
- 4 Compound Index
- Author Index
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