
Colloid Science
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Content
- Colloid Science
- Contents
- Chapter 1 Adsorption at the Gas/Solid Interface
- 1 General Aspects of Physisorption
- The Potential Energy of Adsorption
- Structure of Adsorbed Monolayers
- Specific Adsorbate-Adsorbent Interactions
- Determination of Surface Area
- 2 Adsorption in Micropores
- Concept of Microporosity and Interpretation of Type I Isotherms
- The Dubinin Theory of Micropore Filling
- Potential Energy for Adsorption in Micropores
- Statistical Mechanical Treatments for Adsorption in Micropores
- Conclusions
- 3 Adsorption and Surface Effects in Flow and Diffusion
- Introduction
- Regimes of Flow
- Influence of Pore Structure
- Surface Flow
- Intra-crystalline Diffusion in Zeolites
- Chapter 2 Adsorption at the Solid/Liquid Interface: Non-electrolyte Systems
- 1 Introduction
- 2 Thermodynamic Considerations
- 3 Determination of Surface Areas by Adsorption from Solution
- 4 Relationship between Gas Adsorption and Adsorption from Solution
- 5 Adsorption from Dilute Solutions
- 6 Adsorption from Multicomponent Solutions
- 7 Liquid Chromatography
- 8 Spectroscopic Methods
- 9 Studies of Specific Systems
- Silica
- Carbons
- Non-porous Carbons
- Activated Carbons
- Miscellaneous Adsorbents
- Oxide Adsorbents
- Clay Minerals
- Chapter 3 Insoluble Monolayers - Dynamic Aspects
- 1 Introduction
- 2 Rheological Properties
- Surface Shear Viscosity
- Dilational Visco-elasticity
- Relaxation Processes
- Summary
- 3 Movement across the Interface
- Spreading Solvents
- Spreading from Crystals
- Spreading Across a Liquid Surface
- Surface Diffusion
- 4 Mass Transport through Monolayers
- General Principles
- Evaporation through Monolayers
- Evaporation of Water Droplets
- Transport of Gases
- Transport through Liquid/Liquid Interfaces
- 5 Penetration of Monolayers
- Kinetics of Penetration
- Equilibrium Penetration
- Theoretical Treatment of Penetration
- Summary
- 6 Reactions in Monolayers
- 7 Concluding Remarks
- Chapter 4 Emulsions
- 1 Introduction
- 2 Non-spontaneous Emulsitication
- 3 Spontaneous Emulsification
- 4 Emulsion Stability
- 5 Emulsion Properties
- Chapter 5 Micellization in Aqueous Solution
- 1 Introduction
- 2 Phase Behaviour of Surface Active Agents in Water
- 3 Properties of Micellar Solutions
- Molecular Motion
- Micellar Shape
- 4 Thermodynamics of Micellization
- Thermodynamic Model
- Monomeric Surfactant Concentration
- Aggregation Numbers
- Free Energy and Enthalpy of Micellization
- 5 Theories of Micelle Formation
- 6 General Conclusions
- Chapter 6 Structure and Reactivity in Micellar Aggregates
- 1 Introduction
- 2 The Structure of Micelles
- Inverse Micelles
- 3 Dynamic Aspects of Micelle Formation and Breakdown
- 4 Ground- and Excited-state Reactions and Equilibria in Micelles
- Transient Intermediates
- 5 Micellar Catalysis
- Hydrolysis of Acyl Derivatives
- Ester Hydrolysis by Functional and Mixed Micelles
- Hydrolysis of Phosphate Esters
- Carbonium Ion Reactions in Micelles
- Aromatic Nucleophilic Substitution
- Proton Transfer in Micelles
- Other Micelle-promoted Reactions
- Catalysis by Inverse Micelles
- Catalysis of Inorganic Reactions
- 6 Other Aspects of Hydrophobic Catalysis
- Catalysis in Association Complexes
- Catalysis by Functional Polymers
- Chapter 7 Spectroscopic Measurements at the Gas/Solid Interface
- 1 Introduction
- 2 Infrared Studies
- Infrared Spectra
- Zeolite Surfaces
- Silica Surfaces
- Alumina Surfaces
- Other Oxide Surfaces
- Halide Surfaces
- Metal Surfaces
- Supported Metal Surfaces
- New Techniques
- 3 Nuclear Magnetic Resonance
- Zeolites
- Silicas and Aluminas
- Other Oxides
- Carbon Surfaces
- Metal Surfaces
- Glass Surfaces
- 4 Electron Spin Resonance
- Oxygen Radical Anions
- Sulphur Anions
- Small Molecules
- Paramagnetic Probes
- New Technique: Adiabatic Rapid Passage
- 5 Electron Spectroscopy
- Zeolites
- Single Crystals
- Polycrystalline Surfaces
- 6 Neutron Scattering
- Structural Determination
- Dynamic Studies
- 7 Laser Raman Spectroscopy
- 8 Dielectric Studies
- 9 Other Techniques
- Mössbauer Spectra
- Nuclear Reactions
- U.V. and Visible
- Inelastic Electron Tunnelling
- Microwave Spectroscopy
- Author Index
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